File name: Pandora85s1_NewOrleansLA-XULA_20240628_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182454.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240628_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240628T140937.8Z 8945.590021 293 1 53.49 2 52.25 82.56 46.06 236.36 0.00 1 0.00 1 0 17 2.154e-02 1.305e-02 3.347e-03 1.696e-03 2.172240e-01 8.609151e-04 2.447843e-03 -6.000000e+00 1.234058e-02 230.62 -2.00 3.24 -2.00 316.03 0.00e+00 8.711098e-04 9.525618e-05 2.688882e-04 -6.000000e+00 5.660486e-04 293.35 -2.00 20.00 -2.00 315.17 0.00e+00 1.629 0.000 302.00 328.00 3 5.2043e+00 2.2432e-03 1.9327e-02 -6.0000e+00 3.0752e-02 3.0366e-02 2.5095e-03 1.0363e-02 -6.0000e+00 3.3326e-02 9.0379e-03 1.4400e-03 5.0077e-03 -6.0000e+00 1.9948e-02 -1.4219e-02 6.5944e-04 1.3664e-03 -6.0000e+00 8.4040e-03 4.4078e-04 9.6086e-05 4.8019e-05 1.6873e-05 -6.0000e+00 5.8086e-04 -4.1685e-03 12 8 8 10 0 0 99.99 27.34 0.95 -0.00417 -0.00345 46 5 1 5 0 1162.600 34.50 20.01 27.34 35.54 15.2 1011.70 7415 -2191 5035 -1867 -5748 5001 -3628 -6101 -274 -3231 -1612 -5830 -3093 2974 -1543 4792 1688 -1110 2888 1944 1828 -787 1715 1478 -536 911 2013 1618 -4301 -1542 -1193 208 -239 -2180 -7244 -5489 -4943 -4691 -198 -109 612 572 1474 413 1059 320 1772 965 -590 -301 -743 2527 805 781 1897 1292 990 64 -506 -912 -375 2067 1628 2024 1805 409 -1497 -129 -1406 696 1531 1671 957 535 505 -1139 -1766 -3245 -3143 -1936 -2595 -1588 -1658 -2199 -1366 170 104 745 1717 558 1449 367 -647 -2149 -528 -2155 -255 825 853 89 -148 -933 -1822 -1732 -862 -1672 -465 -62 14 1775 1621 2557 2300 1792 -226 -763 -1012 -504 -702 282 602 346 1247 266 25 -187 -1412 -415 -1036 108 -96 -222 -707 -263 -512 99 -165 726 557 624 601 -542 -788 -409 1304 -475 1060 -409 -1163 914 -668 -1261 -60 -782 -385 -1429 -793 813 -501 1628 573 -398 1031 724 701 -309 655 589 -229 398 887 688 -1789 -592 -467 85 -106 -1043 -3517 -2449 -2284 -2448 -108 -66 410 406 1069 309 785 238 1288 686 -413 -206 -523 1833 629 598 1497 1044 815 54 -420 -748 -310 1754 1406 1872 1725 376 -1360 -109 -1205 645 1479 1723 956 527 503 -1054 -1569 -2676 -2538 -1674 -2384 -1604 -1714 -2399 -1559 195 126 943 2082 675 1729 428 -693 -2294 -554 -2328 -298 1000 1070 115 -184 -1149 -2093 -2058 -1026 -2165 -590 -82 20 2530 2327 3766 3350 2478 -309 -961 -1291 -652 -910 391 834 485 1795 376 34 -239 -1831 -511 -1320 145 -130 -312 -1019 -385 -746 152 -252 1129 888 990 926 -817 -1209 -621 SS 20240628T152831.3Z 8945.644807 352 1 40.08 2 35.21 91.57 60.88 251.87 0.00 1 0.00 1 0 17 1.982e-02 1.375e-02 3.118e-03 2.082e-03 1.657454e-01 1.067811e-03 1.886221e-03 -6.000000e+00 1.135996e-02 230.62 -2.00 3.24 -2.00 315.03 0.00e+00 8.152702e-04 9.612664e-05 1.415639e-04 -6.000000e+00 5.209334e-04 293.36 -2.00 20.00 -2.00 314.28 0.00e+00 1.223 0.000 302.00 328.00 3 5.7746e+00 2.7494e-03 1.4585e-02 -6.0000e+00 2.8308e-02 3.7319e-02 3.0580e-03 7.9343e-03 -6.0000e+00 3.0674e-02 7.4326e-03 1.7479e-03 3.8212e-03 -6.0000e+00 1.8361e-02 -1.3490e-02 7.6641e-04 1.0528e-03 -6.0000e+00 7.7389e-03 4.0963e-04 -2.0909e-05 5.8645e-05 1.4592e-05 -6.0000e+00 5.3457e-04 -6.8908e-03 12 9 9 12 1 1 100.00 27.71 0.79 -0.00689 -0.00705 27 4 1 5 0 1431.330 34.75 20.01 27.71 37.68 15.3 1011.59 6577 -494 4494 -2639 -5586 3370 -2578 -4712 996 -1018 -477 -4092 -7432 2365 -1176 4287 -780 -286 1860 1455 1247 35 2029 2169 -106 2085 1491 1592 -3933 -1950 -1692 -300 256 -1737 -2492 -5069 -4797 -4609 -878 88 909 608 1269 374 433 -14 1792 1088 -1055 -567 -924 2190 432 1494 2001 1368 999 419 94 -900 28 2047 1746 1620 1625 -329 -1340 -239 -1504 798 1926 1487 627 562 1068 -1489 -1587 -2972 -3091 -1792 -3061 -2583 -1227 -2404 -918 294 49 306 1955 264 2086 -115 -620 -2783 -420 -2333 -260 617 765 365 -142 -895 -1546 -1499 -1108 -1638 -434 -146 142 2061 1516 2433 2464 1650 20 -503 -1439 -582 -1309 -25 751 458 1385 315 28 111 -1409 -57 -684 279 417 -402 -752 -333 -249 45 -42 603 239 465 766 -637 -1075 -419 1920 -157 1535 -856 -1800 899 -735 -1493 331 -371 -172 -1488 -2704 869 -501 1904 -380 -141 921 744 605 17 1044 1064 -56 1102 805 824 -2136 -974 -848 -155 139 -938 -1304 -2742 -2678 -2670 -577 63 674 476 1015 307 354 -11 1415 833 -851 -441 -731 1774 349 1250 1727 1204 895 380 85 -803 25 1881 1622 1609 1656 -322 -1276 -210 -1327 754 1892 1567 643 603 1087 -1425 -1447 -2497 -2696 -1544 -2988 -2599 -1318 -2575 -1020 348 59 381 2448 332 2432 -133 -690 -2896 -422 -2548 -288 746 950 465 -175 -1093 -1764 -1673 -1317 -1999 -547 -192 193 2728 2123 3477 3458 2196 26 -605 -1762 -717 -1620 -33 1046 616 1919 428 36 136 -1760 -67 -826 355 525 -529 -1007 -450 -351 63 -62 906 350 679 1144 -936 -1539 -590 SS 20240628T154315.8Z 8945.655044 364 1 5.28 2 32.02 93.63 63.82 254.21 0.00 1 0.00 1 0 17 1.304e-02 1.116e-02 1.569e-03 1.232e-03 1.545356e-01 6.366923e-04 1.745258e-03 -6.000000e+00 7.473564e-03 230.62 -2.00 3.24 -2.00 314.17 0.00e+00 8.098500e-04 4.901280e-05 8.188724e-05 -6.000000e+00 3.427458e-04 293.36 -2.00 20.00 -2.00 313.52 0.00e+00 1.179 0.000 302.00 328.00 3 2.9601e+00 1.6270e-03 1.3902e-02 -6.0000e+00 1.8624e-02 1.7632e-02 1.8020e-03 7.4060e-03 -6.0000e+00 2.0181e-02 5.1853e-03 1.0355e-03 3.5360e-03 -6.0000e+00 1.2080e-02 -1.0477e-02 4.4269e-04 9.8167e-04 -6.0000e+00 5.0907e-03 7.3725e-03 1.6758e-06 3.4411e-05 1.4155e-05 -6.0000e+00 3.5172e-04 -5.9610e-03 12 9 9 12 1 1 61.30 27.77 0.53 -0.00596 -0.00595 15 18 1 5 0 329.960 34.75 20.00 27.77 38.02 15.3 1011.45 1034 570 918 -1269 -3285 -2277 -2165 -897 373 193 -2082 -3110 -1345 -698 776 1365 121 984 1210 1461 2251 499 1266 1804 836 1202 948 -404 -1028 -508 104 225 1204 -270 -3250 -4006 -3701 -3165 -945 153 100 -28 274 215 389 926 276 157 -200 -576 12 811 969 1072 1003 759 952 319 174 282 490 1295 1942 2775 1913 118 -478 -2008 -978 543 593 972 616 958 458 -346 -1477 -2680 -2861 -2050 -2113 -1795 -2195 -2507 -1397 -575 156 557 1261 1266 847 327 -839 -1470 -1069 -1026 -455 511 936 188 -36 -1100 -1938 -1568 -814 -1070 -575 -422 16 1099 1616 2084 1809 1386 304 -311 -79 -82 198 787 689 529 689 548 224 394 -744 -356 -282 -203 -52 -468 -768 -722 -128 85 -52 723 477 255 149 -181 -935 -919 437 253 420 -571 -1401 -919 -879 -370 169 89 -978 -1429 -639 -349 407 747 70 570 717 849 1331 298 746 1091 531 755 605 -250 -612 -295 60 136 727 -174 -2069 -2493 -2279 -2095 -667 118 83 -24 238 189 342 804 238 134 -165 -478 9 685 830 958 901 692 877 298 160 256 449 1198 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