File name: Pandora85s1_NewOrleansLA-XULA_20240629_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182529.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240629_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240629T130352.2Z 8946.544355 254 1 11.90 2 66.30 75.93 24.93 201.64 0.00 1 0.00 1 0 17 2.300e-02 1.199e-02 6.429e-03 2.252e-03 3.031513e-01 1.136472e-03 3.358688e-03 -6.000000e+00 1.317649e-02 230.60 -2.00 3.24 -2.00 316.99 0.00e+00 1.143463e-03 1.568258e-04 5.239599e-04 -6.000000e+00 6.045554e-04 293.41 -2.00 20.00 -2.00 316.05 0.00e+00 2.469 0.000 302.00 328.00 3 3.3716e+00 3.0029e-03 2.8565e-02 -6.0000e+00 3.2832e-02 1.3766e-02 3.3838e-03 1.4467e-02 -6.0000e+00 3.5580e-02 8.8623e-03 1.9809e-03 6.9560e-03 -6.0000e+00 2.1298e-02 -1.4107e-02 9.5234e-04 1.8881e-03 -6.0000e+00 8.9745e-03 1.0693e-03 1.1143e-04 6.3618e-05 2.1067e-05 -6.0000e+00 6.2025e-04 -4.4875e-03 12 9 9 12 1 1 44.13 27.45 0.37 -0.00449 -0.00365 10 6 1 5 0 1081.080 34.50 20.00 27.45 36.45 15.2 1016.89 4122 -1116 4700 -3018 -7548 -1889 -5845 -9754 -2634 -6478 -1688 -5336 -6583 2386 -2092 4845 -462 -2223 2971 1184 1602 -681 2875 716 -36 1297 1313 146 -4420 -2822 -1902 128 -83 -346 -5775 -5141 -5659 -3267 500 414 991 338 1059 741 649 923 1089 1357 -359 -751 910 1607 991 1551 1200 2007 1687 595 -896 74 315 2232 1635 3327 1924 688 -848 -1427 -1160 432 1636 1664 976 281 522 -891 -1837 -3581 -3276 -2828 -2248 -1796 -1965 -2359 -1361 -442 -145 836 1292 1217 1007 233 -1053 -2143 -1102 -1527 -449 766 629 168 -326 -1487 -2011 -1286 -778 -1239 -512 -429 227 1158 1808 2278 1778 1430 -42 -484 -459 127 73 784 314 669 912 663 336 133 -1003 -308 -307 58 -171 -427 -939 -750 -353 -230 -4 770 564 480 447 -243 -758 -895 425 -139 586 -400 -941 -206 -680 -1305 -370 -1028 -260 -856 -1183 457 -447 1102 -120 -614 820 320 447 -194 797 214 -11 427 444 48 -1430 -868 -608 44 -29 -130 -2241 -1867 -2164 -1390 228 212 539 197 639 460 405 576 677 825 -219 -459 568 1015 674 1054 860 1462 1261 454 -684 55 237 1739 1328 2755 1689 587 -711 -1152 -948 369 1482 1613 932 265 486 -804 -1576 -2894 -2630 -2371 -2035 -1735 -1996 -2537 -1471 -510 -171 981 1541 1435 1165 260 -1132 -2181 -1124 -1706 -512 928 809 223 -419 -1862 -2420 -1493 -957 -1592 -660 -580 309 1608 2673 3396 2652 2108 -58 -645 -608 171 100 1109 468 999 1332 942 472 185 -1340 -409 -408 81 -245 -625 -1415 -1159 -553 -372 -7 1276 956 810 751 -396 -1234 -1447 SS 20240629T131534.0Z 8946.552477 260 1 53.95 2 63.83 77.12 25.92 207.87 0.00 1 0.00 1 0 17 1.779e-02 1.168e-02 1.507e-03 6.286e-04 2.774746e-01 3.183429e-04 3.084958e-03 -6.000000e+00 1.019379e-02 230.60 -2.00 3.24 -2.00 316.67 0.00e+00 1.063766e-03 4.064168e-05 4.581597e-04 -6.000000e+00 4.676569e-04 293.41 -2.00 20.00 -2.00 315.76 0.00e+00 2.254 0.000 302.00 328.00 3 2.6775e+00 8.3563e-04 2.6074e-02 -6.0000e+00 2.5400e-02 3.4450e-03 9.3899e-04 1.3169e-02 -6.0000e+00 2.7525e-02 6.3150e-03 5.4313e-04 6.3254e-03 -6.0000e+00 1.6476e-02 -1.1385e-02 2.5595e-04 1.7155e-03 -6.0000e+00 6.9439e-03 2.7575e-03 9.2701e-05 1.7718e-05 1.9842e-05 -6.0000e+00 4.7980e-04 -5.5250e-03 12 8 8 10 0 0 99.96 27.51 0.43 -0.00552 -0.00483 228 25 1 5 0 236.620 34.75 20.00 27.51 37.34 15.3 1016.89 1882 -773 2550 -2632 -5273 -3542 -4149 -4829 -1696 -2771 -4111 -5074 -3403 -662 -21 2127 84 626 1923 2035 1700 378 1717 1231 778 1062 1047 -454 -2451 -1513 -815 -456 426 -395 -4393 -5410 -4828 -3483 -729 305 241 231 834 587 788 1029 1097 447 -440 -545 79 1087 1042 1727 1594 1407 1371 407 123 54 459 1597 2157 3162 2174 469 -748 -1680 -1087 552 1003 1315 1044 1014 371 -793 -1848 -3430 -3370 -2406 -2327 -1688 -1969 -2411 -1373 -370 206 864 1455 1135 860 118 -1204 -1991 -1307 -1386 -416 505 827 233 -340 -1283 -2139 -1657 -761 -1117 -548 -170 188 1245 1764 2180 1915 1455 210 -513 -416 -51 183 711 581 652 909 647 205 183 -1043 -614 -306 -193 -281 -678 -911 -795 -303 -11 10 750 661 445 227 -217 -732 -702 256 -123 416 -443 -817 -496 -599 -773 -296 -531 -808 -1005 -666 -146 -5 597 24 184 584 643 557 125 564 426 266 378 382 -163 -898 -527 -293 -165 166 -167 -1876 -2194 -2034 -1536 -372 173 145 140 523 378 507 662 702 282 -275 -338 50 737 714 1244 1205 1091 1032 313 93 40 346 1256 1748 2752 1901 418 -620 -1406 -915 483 939 1257 1024 976 357 -704 -1557 -2844 -2768 -2042 -2138 -1649 -2020 -2619 -1497 -414 244 1024 1752 1355 1009 133 -1309 -2034 -1394 -1541 -489 609 1052 306 -433 -1588 -2558 -1919 -931 -1427 -703 -228 255 1768 2574 3201 2802 2102 294 -691 -536 -67 253 1017 845 954 1304 904 283 250 -1368 -801 -397 -270 -404 -993 -1371 -1184 -472 -18 16 1233 1111 747 369 -353 -1156 -1098 SS 20240629T132014.6Z 8946.555724 263 1 53.97 2 62.85 77.59 26.39 210.24 0.00 1 0.00 1 0 17 1.629e-02 1.095e-02 6.627e-04 3.195e-04 2.678640e-01 1.620321e-04 2.953896e-03 -6.000000e+00 9.333729e-03 230.60 -2.00 3.24 -2.00 316.32 0.00e+00 9.990070e-04 1.894040e-05 3.265476e-04 -6.000000e+00 4.282448e-04 293.41 -2.00 20.00 -2.00 315.43 0.00e+00 2.179 0.000 302.00 328.00 3 1.4595e+00 4.2348e-04 2.5182e-02 -6.0000e+00 2.3257e-02 -3.6666e-03 4.7528e-04 1.2676e-02 -6.0000e+00 2.5203e-02 5.4201e-03 2.7230e-04 6.0959e-03 -6.0000e+00 1.5087e-02 -1.0445e-02 1.2546e-04 1.6583e-03 -6.0000e+00 6.3572e-03 1.0222e-02 -3.6789e-05 8.9934e-06 1.9477e-05 -6.0000e+00 4.3936e-04 -4.5074e-03 12 8 8 10 0 0 95.98 27.53 0.38 -0.00451 -0.00478 590 66 1 5 0 91.460 34.50 20.01 27.53 37.64 15.3 1016.91 -157 -272 1160 -2079 -5160 -4617 -4538 -2822 -1088 -2049 -4128 -5009 -3143 -1364 248 1419 479 1009 1601 2050 2001 799 1611 1469 887 1066 704 -658 -2021 -1430 -544 180 1048 -13 -3632 -4751 -4187 -3096 -621 439 250 341 621 537 820 1171 735 217 -138 -549 350 1020 1001 1449 1076 1032 1149 484 339 178 613 1422 2210 2935 1999 88 -608 -1728 -980 524 739 1065 851 854 254 -606 -1585 -3095 -2967 -2294 -2094 -1679 -2094 -2411 -1532 -591 117 686 1300 1257 840 381 -861 -1504 -1144 -1117 -440 605 754 147 -424 -1290 -2109 -1539 -712 -1159 -564 -250 43 1091 1627 2013 1715 1271 176 -369 -226 61 399 793 605 604 785 581 295 222 -884 -450 -163 -205 -144 -570 -787 -758 -246 15 27 719 606 344 145 -314 -805 -711 -27 -53 237 -429 -984 -805 -809 -544 -232 -441 -917 -1119 -753 -370 71 453 154 336 554 734 740 299 600 538 345 433 294 -269 -778 -560 -205 73 457 -6 -1627 -2021 -1850 -1537 -320 254 156 226 407 361 551 785 491 143 -93 -369 230 716 716 1091 816 801 910 390 270 139 484 1129 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