File name: Pandora85s1_NewOrleansLA-XULA_20240630_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182504.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240630_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240630T113501.3Z 8947.482654 189 1 55.25 2 84.57 66.40 28.82 121.91 0.00 1 0.00 1 0 41 7.180e-01 9.999e-02 2.630e-01 1.647e-02 1.066702e+00 1.087551e-02 2.509443e-02 -6.000000e+00 4.551421e-01 230.57 -2.00 3.24 -2.00 322.24 0.00e+00 -8.237839e-02 6.610127e-03 5.271152e-02 -6.000000e+00 4.608452e-02 293.46 -2.00 20.00 -2.00 321.66 0.00e+00 9.198 0.009 302.00 328.00 3 5.5941e-01 4.6390e-02 2.8387e-01 -6.0000e+00 1.1256e+00 1.8319e+00 5.7460e-02 3.1321e-01 -6.0000e+00 1.2346e+00 -2.2697e+00 3.7663e-02 1.0805e-01 -6.0000e+00 7.3505e-01 8.7838e-01 1.8929e-02 1.0295e-02 -6.0000e+00 3.2893e-01 1.0156e-05 -6.5740e-03 4.8739e-04 1.1308e-03 -6.0000e+00 2.2719e-02 -3.6418e-04 12 8 8 10 0 0 -14.82 27.30 1.51 -0.00036 -0.04976 19 2 1 5 0 2907.610 34.50 20.01 27.30 34.52 15.2 1019.28 900000 900000 900000 900000 83224 900000 146106 -5467 900000 900000 900000 900000 900000 900000 171721 900000 900000 110221 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 88785 900000 164230 900000 130427 70954 -68347 168057 288512 113819 900000 900000 900000 900000 900000 900000 131829 -6679 900000 900000 31622 900000 -15705 900000 900000 70981 900000 900000 138141 154399 114635 15297 10728 900000 140761 -35194 44032 900000 -40832 900000 -6339 158425 188095 900000 25633 4336 127057 -45305 38662 19948 73548 900000 -410 4956 39591 7814 47607 97723 8601 -7168 69624 -32739 54149 -3228 42904 -17250 81033 -30807 6041 -19809 10100 -8472 16281 11382 14122 2221 7878 -78 8176 13362 -6629 23293 -8623 18334 16441 14193 -1780 4962 -13980 1275 -19916 -9124 5558 15 22889 -1309 -4364 2978 -15311 10056 -12164 3001 2013 2117 1079 5668 -3474 3543 -822 -173 -1535 1058 9834 -8980 -1166 597 900000 900000 900000 900000 2764 900000 2532 -639 900000 900000 900000 900000 900000 900000 5207 900000 900000 4456 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 5898 900000 2846 900000 3013 3074 -11547 2669 4583 3287 900000 900000 900000 900000 900000 900000 5711 -936 900000 900000 2146 900000 -1882 900000 900000 5525 900000 900000 8119 8338 8922 2770 1670 900000 5143 -7994 4896 900000 -10442 900000 -1309 7298 7469 900000 5863 1185 9284 -16192 5159 2978 6542 900000 -98 1323 8741 2656 11721 15678 3552 -3564 16036 -20281 13160 -1292 10495 -7919 15317 -20552 3214 -14188 6706 -6643 10887 7485 8120 1312 4455 -52 5208 8511 -5581 16354 -8816 16547 16690 15433 -2282 5790 -19118 1500 -29967 -12859 6862 19 23742 -1512 -5067 3135 -18925 10463 -15545 3870 3055 3634 2062 11212 -7514 7758 -1982 -421 -3805 2501 21670 -19969 -2397 1151 SS 20240630T114832.5Z 8947.492042 192 1 53.94 2 81.87 67.95 26.40 126.55 0.00 1 0.00 1 0 17 5.282e-01 1.688e-02 1.127e-01 2.556e-03 7.196280e-01 1.389250e-03 8.328912e-03 -6.000000e+00 3.057902e-01 230.57 -2.00 3.24 -2.00 321.16 0.00e+00 -2.326951e-03 7.103681e-04 8.093038e-03 -6.000000e+00 1.517017e-02 293.46 -2.00 20.00 -2.00 320.45 0.00e+00 6.612 0.003 302.00 328.00 3 6.3575e-01 4.9727e-03 8.7557e-02 -6.0000e+00 7.6317e-01 1.0040e-01 6.9180e-03 7.1032e-02 -6.0000e+00 8.2969e-01 -2.0371e-01 6.6440e-03 1.9514e-02 -6.0000e+00 4.9498e-01 7.5306e-02 3.1481e-03 1.1324e-02 -6.0000e+00 2.0994e-01 2.1309e-04 2.8244e-05 6.8978e-05 7.5022e-05 -6.0000e+00 1.4491e-02 -2.0076e-03 12 8 8 10 0 0 0.79 27.37 0.58 -0.00201 -0.00180 111 12 1 5 0 485.900 34.50 20.01 27.37 35.29 15.2 1019.30 900000 -204094 900000 -198330 -208109 900000 -189550 -261034 -89133 -161592 900000 -130583 -67930 900000 -111603 900000 -38721 -90027 900000 3236 -42652 -66074 -10472 4792 -26650 29315 132495 102401 -61129 -25404 -40409 3623 -38095 -26727 -50800 -27615 -32461 -45858 16164 46 22612 19871 37432 6237 2890 -9991 25882 24413 2259 5790 -4398 22712 4534 3598 17710 13582 7089 6795 -635 -4505 -4728 9244 2909 2618 6032 9868 -4302 6162 -1918 5036 6465 6390 2569 -109 1832 -6565 -4114 -7288 -4916 632 -4573 -2225 -411 -1792 -473 2863 455 945 3564 -941 2468 -717 -1426 -5538 -844 -3776 -558 -662 -195 -870 -1273 -1684 -2523 -2504 -1387 -1469 -129 -308 -1 2274 1779 3035 2742 1611 -365 -1021 -1357 -114 -704 -146 930 1051 1760 708 10 -249 -1858 -643 -704 87 -225 -134 -1127 -699 -501 206 1 811 620 625 786 -675 -897 -319 900000 -1940 900000 -2020 -2167 900000 -1716 -5613 -444 -1719 900000 -1333 -457 900000 -1890 900000 -453 -1973 900000 33 -722 -1431 -136 60 -511 350 594 612 -1796 -538 -1157 81 -1537 -1091 -2656 -1107 -1463 -2775 652 3 1256 1252 2106 497 240 -960 1779 1757 214 567 -530 2381 638 565 2641 2246 1317 1296 -128 -915 -963 1747 662 686 1536 2453 -1213 1608 -585 1652 2393 2553 1088 -46 701 -2462 -1372 -2453 -1739 249 -2266 -1258 -237 -1135 -316 1993 345 743 2777 -755 1814 -508 -971 -3932 -622 -3059 -512 -656 -218 -1031 -1469 -1802 -2635 -2476 -1426 -1511 -137 -353 -1 2883 2564 4460 4210 2484 -553 -1481 -1937 -165 -1089 -237 1528 1679 2684 1059 14 -374 -2741 -931 -1047 148 -404 -249 -2252 -1397 -1072 470 1 1856 1443 1432 1792 -1468 -1853 -651 SS 20240630T120352.7Z 8947.502693 197 1 53.98 2 78.77 69.66 23.84 132.75 0.00 1 0.00 1 0 25 2.393e-01 1.281e-02 2.169e-02 9.386e-04 5.629068e-01 4.795932e-04 6.542541e-03 -6.000000e+00 1.370435e-01 230.57 -2.00 3.24 -2.00 319.91 0.00e+00 1.183225e-03 1.586423e-04 3.689777e-03 -6.000000e+00 6.291281e-03 293.46 -2.00 20.00 -2.00 319.05 0.00e+00 4.954 0.001 302.00 328.00 3 5.0346e-01 1.4304e-03 5.8727e-02 -6.0000e+00 3.4144e-01 -1.5566e-03 1.7438e-03 3.5646e-02 -6.0000e+00 3.7005e-01 -4.7694e-02 1.4245e-03 1.4390e-02 -6.0000e+00 2.2152e-01 1.1348e-02 7.3609e-04 3.8272e-03 -6.0000e+00 9.3328e-02 1.3336e-03 1.1968e-04 2.5545e-05 4.8219e-05 -6.0000e+00 6.4528e-03 -2.6927e-03 12 8 8 10 0 0 -6.28 27.48 0.44 -0.00269 -0.00179 298 33 1 5 0 181.130 34.50 20.01 27.48 36.64 15.2 1019.47 -20733 -109506 -42665 -87636 -82099 -34445 -102464 -107546 -72326 -77535 -47790 -65547 -56150 -20507 -38353 -3242 -20426 -14863 -11312 -8605 -12408 -20254 -4501 -12471 -11517 -7140 -5432 -2551 -20585 -13651 -12984 -5530 -8425 -5881 -11887 -12653 -12313 -9374 -1352 1064 3384 4393 4989 1991 2234 1198 3314 3363 -309 880 951 4233 2252 3055 4462 3361 2890 1938 682 -295 513 2957 2527 3966 3804 2188 -769 -605 -749 1727 2179 2158 1515 1185 54 -1952 -2813 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