File name: Pandora85s1_NewOrleansLA-XULA_20240702_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182518.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240702_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240702T120443.3Z 8949.503279 156 1 53.88 2 78.74 69.84 39.08 89.69 0.00 1 0.00 1 0 17 3.415e-01 1.475e-02 1.013e-01 2.136e-03 5.758889e-01 1.120247e-03 6.774009e-03 -6.000000e+00 1.965253e-01 230.51 -2.00 3.24 -2.00 320.35 0.00e+00 -4.901758e-04 4.361164e-04 4.776298e-03 -6.000000e+00 9.754054e-03 293.57 -2.00 20.00 -2.00 319.53 0.00e+00 4.943 0.001 302.00 328.00 3 2.0961e+00 3.5207e-03 6.1548e-02 -6.0000e+00 4.8935e-01 -5.5643e-02 4.4622e-03 4.3472e-02 -6.0000e+00 5.3097e-01 -3.2760e-02 3.9088e-03 1.4569e-02 -6.0000e+00 3.1680e-01 5.1427e-03 1.9764e-03 6.2123e-03 -6.0000e+00 1.3528e-01 2.8006e-04 3.0432e-04 5.9654e-05 4.8184e-05 -6.0000e+00 9.3612e-03 -5.6175e-03 12 8 8 10 0 0 37.89 27.50 0.63 -0.00562 -0.00333 80 9 1 5 0 673.470 34.50 20.00 27.50 35.83 15.3 1013.42 900000 -117170 900000 -116778 -56399 900000 -97907 -161909 -80537 -87198 900000 -39450 -82893 900000 -79371 211431 -23572 -23080 58521 3343 2661 -18478 7569 14035 -7251 13784 41630 43744 -27473 -11860 -16356 8126 -14291 -16050 -31600 -19619 -17390 -23237 2203 10560 12376 6483 7519 2317 -1214 -3423 8221 9949 -312 -2509 -2031 9869 9 -693 8661 4073 881 414 -1942 -1537 -407 6245 2754 303 3525 5310 -4856 4449 160 1968 4318 3167 2537 348 792 -2868 -2061 -5530 -3151 -1320 -4925 -2437 -1359 -2132 -697 1421 180 430 2660 268 1604 -311 -1091 -3105 -961 -2912 -467 -15 184 -327 -614 -1593 -1906 -2497 -1293 -1246 -880 72 416 1921 1836 2753 2439 1602 -349 -1051 -1270 -441 -395 519 631 793 1474 608 -269 -314 -1743 -383 -691 -24 -253 -563 -873 -449 -361 148 -41 515 685 629 648 -737 -598 -215 900000 -1536 900000 -1726 -423 900000 -1141 -4111 -1056 -1379 900000 -443 -1725 900000 -2494 440 -589 -634 779 83 70 -608 198 380 -269 448 1074 1092 -1338 -501 -817 375 -961 -1233 -2841 -1507 -1393 -2302 208 1130 1520 926 1128 380 -209 -613 1336 1619 -58 -502 -401 1942 2 -183 2256 1170 273 132 -624 -481 -127 1942 993 127 1422 2101 -2053 1878 68 942 2304 1843 1521 207 440 -1498 -969 -2585 -1510 -716 -3006 -1674 -1037 -1635 -561 1208 165 410 2535 258 1444 -265 -882 -2505 -806 -2825 -476 -17 225 -420 -766 -1858 -2157 -2716 -1468 -1429 -1058 91 531 2656 2667 4292 3710 2542 -536 -1534 -1810 -640 -607 841 997 1232 2325 940 -402 -453 -2595 -553 -1017 -39 -437 -1002 -1640 -839 -718 299 -86 1108 1498 1359 1338 -1464 -1186 -420 SS 20240702T121043.1Z 8949.507443 159 1 53.82 2 77.52 70.50 37.81 90.38 0.00 1 0.00 1 0 17 2.066e-01 1.261e-02 5.848e-02 1.502e-03 5.291930e-01 7.709194e-04 6.134449e-03 -6.000000e+00 1.188898e-01 230.51 -2.00 3.24 -2.00 319.91 0.00e+00 3.515487e-04 2.564011e-04 3.475865e-03 -6.000000e+00 5.551616e-03 293.57 -2.00 20.00 -2.00 319.04 0.00e+00 4.496 0.001 302.00 328.00 3 1.9105e+00 2.3104e-03 5.4094e-02 -6.0000e+00 2.9581e-01 -6.1597e-02 2.8137e-03 3.4224e-02 -6.0000e+00 3.2075e-01 -1.4007e-02 2.2951e-03 1.3187e-02 -6.0000e+00 1.9157e-01 -2.5236e-03 1.1894e-03 4.1440e-03 -6.0000e+00 8.1118e-02 5.3585e-04 1.1680e-04 4.1905e-05 4.2644e-05 -6.0000e+00 5.6205e-03 -5.7664e-03 12 8 8 10 0 0 36.08 27.54 0.54 -0.00577 -0.00489 117 13 1 5 0 459.970 34.50 20.01 27.54 36.11 15.2 1013.48 900000 -64258 119989 -53628 -46066 900000 -68263 -111516 -39770 -57110 -7419 -37276 -54690 15727 -35480 50293 -16306 -20927 9259 10582 -8488 -12584 81 1569 -5733 3826 5583 10585 -21461 -8303 -14999 1195 -15564 -7613 -18953 -12240 -14546 -16050 671 3110 4891 2030 3103 1641 1123 -1395 4102 4415 -545 -263 344 4694 1156 758 3863 2331 1330 1771 -370 -604 410 3346 2626 2943 2642 3347 -1994 1255 -380 1681 2415 2692 1935 1177 500 -2153 -2058 -4358 -3410 -2017 -3353 -1710 -1683 -2097 -901 617 245 871 2232 1191 1354 11 -1289 -2540 -1484 -2306 -375 19 459 -103 -741 -1683 -2400 -1832 -1174 -1353 -562 -202 542 1322 1957 2481 2179 1263 -314 -670 -738 -207 -33 618 545 566 993 494 88 -137 -1388 -590 -682 -13 -213 -583 -741 -583 -372 -39 -37 772 712 428 377 -288 -649 -246 900000 -913 299 -769 -567 900000 -1059 -3037 -611 -1171 -98 -704 -1457 258 -1200 869 -623 -919 328 395 -403 -630 4 76 -330 215 323 575 -1533 -524 -1131 90 -1591 -802 -2236 -1296 -1674 -2176 94 474 852 398 637 355 247 -320 906 985 -131 -66 92 1347 378 248 1321 848 509 688 -145 -232 158 1330 1173 1474 1325 1656 -997 605 -196 961 1450 1737 1289 769 309 -1336 -1155 -2389 -1925 -1284 -2353 -1264 -1392 -1865 -790 575 244 848 2188 1166 1332 10 -1130 -2333 -1331 -2350 -404 22 563 -133 -929 -2083 -2719 -2091 -1330 -1656 -718 -258 737 1852 2867 3895 3506 2002 -478 -1011 -1083 -309 -49 986 859 923 1565 761 130 -206 -2024 -837 -1033 -21 -358 -1015 -1355 -1066 -721 -78 -77 1562 1468 877 768 -562 -1266 -474 SS 20240702T121602.8Z 8949.511143 162 1 54.17 2 76.43 71.08 36.68 91.02 0.00 1 0.00 1 0 17 1.530e-01 1.228e-02 2.569e-02 1.157e-03 4.942333e-01 5.880865e-04 5.687737e-03 -6.000000e+00 8.762367e-02 230.51 -2.00 3.24 -2.00 319.50 0.00e+00 1.393609e-03 1.701203e-04 2.723175e-03 -6.000000e+00 4.023766e-03 293.57 -2.00 20.00 -2.00 318.60 0.00e+00 4.159 0.001 302.00 328.00 3 1.7724e+00 1.6996e-03 4.9135e-02 -6.0000e+00 2.1828e-01 -5.5417e-02 2.0208e-03 2.8702e-02 -6.0000e+00 2.3654e-01 -1.5395e-02 1.5421e-03 1.2402e-02 -6.0000e+00 1.4162e-01 -1.1622e-03 8.0915e-04 3.1332e-03 -6.0000e+00 5.9707e-02 8.7093e-04 1.0435e-04 3.2207e-05 3.7568e-05 -6.0000e+00 4.1254e-03 -5.7247e-03 12 8 8 10 0 0 27.20 27.58 0.49 -0.00572 -0.00494 159 18 1 5 0 340.650 34.75 20.01 27.58 36.34 15.3 1013.53 54267 -64085 -1584 -44198 -50871 39833 -59133 -72506 -37374 -51641 -17214 -45762 -39104 -6455 -21129 11486 -9183 -12918 5844 -527 -6592 -5411 -2985 1762 -1678 1753 638 401 -15471 -7094 -9458 -1267 -5390 -4640 -12584 -10144 -10153 -8361 61 2372 3330 2249 2630 1226 1378 510 2279 2744 -345 -7 735 3896 1088 2230 3199 1899 1244 795 -639 -619 643 2660 2664 2978 2969 1663 -1249 -162 -794 1445 1996 2220 1421 1163 306 -1850 -2671 -3996 -4091 -2597 -3111 -1676 -1749 -2331 -1278 455 597 1184 1993 1289 1307 210 -1270 -2084 -1420 -1873 -596 247 564 -21 -601 -1707 -2314 -2155 -1021 -1278 -657 -102 206 1370 1826 2484 1769 1231 -70 -552 -600 15 95 722 548 586 1058 727 161 7 -1349 -821 -444 -139 -240 -604 -748 -807 -361 39 -65 683 674 547 266 -330 -648 -276 324 -1497 -22 -942 -1067 319 -1341 -2119 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