File name: Pandora85s1_NewOrleansLA-XULA_20240705_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182450.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240705_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240705T115117.7Z 8952.493955 58 1 54.06 2 81.70 68.52 75.49 66.04 0.00 1 0.00 1 0 17 6.342e-01 2.230e-02 2.500e-01 3.645e-03 7.492474e-01 2.028620e-03 7.981992e-03 -6.000000e+00 3.713885e-01 230.43 -2.00 3.24 -2.00 321.35 0.00e+00 -7.502212e-03 1.103715e-03 6.754695e-03 -6.000000e+00 2.144477e-02 293.73 -2.00 20.00 -2.00 320.67 0.00e+00 6.495 0.003 302.00 328.00 3 1.3945e+00 7.5816e-03 8.6060e-02 -6.0000e+00 9.2196e-01 1.1608e-01 1.0980e-02 7.0465e-02 -6.0000e+00 1.0041e+00 -2.5592e-01 1.0760e-02 1.9004e-02 -6.0000e+00 6.0004e-01 9.8675e-02 4.9764e-03 1.4745e-02 -6.0000e+00 2.5428e-01 1.0906e-04 -1.9300e-04 1.0091e-04 5.9042e-05 -6.0000e+00 1.8019e-02 -6.7370e-03 12 8 8 10 0 0 61.45 27.26 0.69 -0.00674 -0.00819 58 6 1 5 0 931.950 34.50 20.01 27.26 34.63 15.3 1013.03 900000 -136755 900000 -7223 900000 900000 -49592 -182644 -152486 -284182 900000 -130847 -137763 900000 -70727 900000 186942 -106743 900000 900000 24012 66004 900000 900000 40225 900000 900000 900000 -28553 370960 -48698 208557 -46481 -50120 -69106 -20604 -15092 -59530 32687 132444 80610 21040 36361 39825 -3185 -11920 54403 63607 -2354 17604 -6102 60748 4231 6833 34425 17653 6299 8998 -272 -7499 -4437 16237 8011 -8595 6416 19576 -11585 27877 -531 9973 17384 10043 3945 366 5689 -3342 -1656 -7613 -8824 3931 -8346 -3595 -523 -3950 1337 2989 -1640 24 4697 -1013 2721 -3244 -1191 -1515 332 -4488 -1018 -833 -758 -2080 -1134 -1733 -1667 -1688 -1131 -2381 -620 -556 -166 2586 1097 4145 3319 1695 -438 -1158 -2214 -373 -1909 -21 1114 1130 2754 757 -881 -97 -1303 -309 -1151 361 -231 -300 -738 -94 -546 279 2 923 884 905 514 -1553 -737 -364 900000 -573 900000 -26 900000 900000 -176 -1589 -1179 -9525 900000 -1139 -1554 900000 -638 900000 663 -2384 900000 900000 179 328 900000 900000 356 900000 900000 900000 -547 1315 -1312 739 -1747 -2221 -3748 -665 -492 -3566 973 1831 2229 1171 1843 2005 -246 -1010 2411 2638 -199 1304 -638 3726 513 896 3771 2453 1041 1490 -49 -1382 -783 2458 1480 -2151 1533 4178 -3028 5564 -152 2697 5014 3376 1443 134 1837 -1063 -517 -2461 -2812 1294 -3712 -1785 -287 -2438 837 1818 -1110 17 3165 -712 1746 -2063 -775 -990 212 -3483 -891 -781 -809 -2374 -1249 -1774 -1532 -1582 -1103 -2339 -631 -603 -195 3073 1501 6092 4811 2492 -635 -1729 -3266 -556 -2843 -32 1736 1713 4225 1149 -1311 -138 -1824 -425 -1743 579 -393 -561 -1485 -187 -1176 604 5 2112 2055 2069 1116 -3420 -1521 -741 SS 20240705T120558.1Z 8952.504144 63 1 53.93 2 78.73 70.16 72.68 67.44 0.00 1 0.00 1 0 17 2.662e-01 1.288e-02 4.093e-02 1.177e-03 5.849922e-01 6.052005e-04 6.793573e-03 -6.000000e+00 1.524738e-01 230.43 -2.00 3.24 -2.00 320.11 0.00e+00 3.668250e-04 2.161559e-04 4.147672e-03 -6.000000e+00 7.007466e-03 293.73 -2.00 20.00 -2.00 319.27 0.00e+00 4.935 0.001 302.00 328.00 3 9.3547e-01 1.8446e-03 6.0079e-02 -6.0000e+00 3.7973e-01 -7.2969e-03 2.2863e-03 3.9381e-02 -6.0000e+00 4.1147e-01 -5.0458e-02 1.9218e-03 1.4726e-02 -6.0000e+00 2.4640e-01 1.1591e-02 9.8392e-04 4.8056e-03 -6.0000e+00 1.0395e-01 8.6295e-04 2.0044e-05 3.1707e-05 5.1839e-05 -6.0000e+00 7.1792e-03 -7.6435e-03 12 8 8 10 0 0 36.14 27.33 0.49 -0.00764 -0.00749 211 23 1 5 0 255.550 34.50 20.01 27.33 35.52 15.3 1012.87 15032 -125892 -30150 -84814 -107009 -7572 -98954 -105314 -87336 -120544 -34537 -73384 -59712 -38145 -41281 5670 -30789 -25587 83 -3511 -16049 -14727 -15697 -4425 -8857 -5153 -4925 7044 -20191 -12455 -22661 -130 -9663 -11189 -13767 -11202 -11893 -16826 -2005 4414 4909 2662 4912 3418 2066 958 4185 3276 -370 683 192 4890 3000 2608 4865 3783 2813 2326 412 -768 187 2319 3576 3031 3484 2355 -1077 696 -860 1904 2950 2682 1570 975 580 -1913 -3005 -4759 -4318 -2565 -2820 -2040 -1676 -2379 -1214 183 385 1277 2264 1280 955 9 -1317 -2311 -1594 -1907 -872 229 508 -108 -861 -1862 -2461 -1943 -937 -1366 -598 -210 281 1475 1852 2328 2010 1170 12 -758 -699 -38 207 628 589 640 959 612 152 99 -1305 -882 -420 -218 -323 -618 -822 -829 -433 -5 -24 725 788 481 377 -288 -618 -336 55 -2299 -235 -1169 -1708 -43 -1477 -1911 -1534 -3322 -428 -1441 -1227 -797 -1114 117 -1047 -914 3 -118 -643 -590 -654 -180 -416 -251 -252 316 -1141 -661 -1507 -8 -779 -1030 -1307 -996 -1129 -1950 -245 623 733 446 854 628 390 186 803 646 -78 150 46 1260 871 831 1502 1242 973 826 147 -271 66 849 1448 1397 1609 1102 -503 320 -425 1041 1692 1663 1008 612 342 -1129 -1624 -2512 -2377 -1598 -1927 -1489 -1370 -1973 -1059 170 357 1225 2192 1237 931 8 -1148 -1986 -1442 -1847 -963 271 640 -136 -1118 -2260 -2872 -2144 -1077 -1612 -736 -274 372 2121 2810 3641 3244 1868 19 -1158 -1038 -57 315 1014 980 1047 1513 940 236 148 -1902 -1257 -640 -355 -559 -1111 -1498 -1584 -845 -11 -49 1535 1696 1028 768 -583 -1193 -666 SS 20240705T121214.2Z 8952.508498 66 1 53.98 2 77.45 70.85 71.46 68.03 0.00 1 0.00 1 0 17 1.889e-01 1.261e-02 1.463e-02 8.501e-04 5.338327e-01 4.330036e-04 6.180366e-03 -6.000000e+00 1.081881e-01 230.43 -2.00 3.24 -2.00 319.62 0.00e+00 1.225721e-03 1.303146e-04 3.128000e-03 -6.000000e+00 4.971906e-03 293.73 -2.00 20.00 -2.00 318.73 0.00e+00 4.470 0.001 302.00 328.00 3 8.0944e-01 1.2605e-03 5.3188e-02 -6.0000e+00 2.6944e-01 -1.4760e-02 1.5109e-03 3.1997e-02 -6.0000e+00 2.9195e-01 -3.3117e-02 1.1769e-03 1.3434e-02 -6.0000e+00 1.7483e-01 5.1903e-03 6.1438e-04 3.4939e-03 -6.0000e+00 7.3764e-02 1.5928e-03 9.5571e-07 2.3296e-05 4.1379e-05 -6.0000e+00 5.0937e-03 -8.1749e-03 12 8 8 10 0 0 34.11 27.38 0.46 -0.00817 -0.00817 307 34 1 5 0 175.820 34.50 20.00 27.38 35.76 15.3 1012.92 -30277 -85049 -43923 -60933 -62828 -50456 -63525 -69395 -59740 -76228 -45190 -53448 -47549 -25618 -23995 2154 -12373 -14719 -3115 -4088 -10047 -11916 -6837 -4750 -6145 -4273 -270 -201 -13765 -10206 -10888 -4316 -4329 -5727 -11184 -9090 -7893 -10652 -3145 3196 2793 1718 2852 2990 1855 1728 3302 2635 421 114 543 3398 2026 2799 3385 2674 2718 1510 152 -115 788 2294 2752 3711 3164 1462 -572 -531 -929 1571 2168 2225 1573 755 157 -1361 -2415 -4411 -4670 -2633 -2743 -1914 -1711 -2278 -1275 -163 489 1154 1730 1361 981 -82 -1270 -2364 -1725 -1581 -692 421 565 -126 -656 -1610 -2590 -1893 -963 -1239 -686 -191 287 1430 1857 2321 1888 1264 -53 -725 -490 -56 326 689 641 644 1129 708 321 61 -1214 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