File name: Pandora85s1_NewOrleansLA-XULA_20240709_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240710T061029.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240709_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240709 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240709T114920.3Z 8956.492596 58 1 53.71 2 82.44 68.63 119.86 48.71 0.00 1 0.00 1 0 25 7.144e-01 2.926e-02 2.320e-01 4.538e-03 7.757257e-01 2.582046e-03 8.060978e-03 -6.000000e+00 4.213107e-01 230.31 -2.00 3.24 -2.00 321.49 0.00e+00 -1.347569e-02 1.433761e-03 7.597668e-03 -6.000000e+00 2.404110e-02 293.94 -2.00 20.00 -2.00 320.81 0.00e+00 7.039 0.004 302.00 328.00 3 1.1991e+00 9.8104e-03 9.6657e-02 -6.0000e+00 1.0460e+00 3.6093e-01 1.4024e-02 8.7255e-02 -6.0000e+00 1.1404e+00 -6.3548e-01 1.2904e-02 1.9722e-02 -6.0000e+00 6.7806e-01 2.7032e-01 5.9252e-03 2.0753e-02 -6.0000e+00 2.8678e-01 7.6790e-05 -4.5698e-04 1.2616e-04 9.7829e-05 -6.0000e+00 2.0472e-02 -9.2261e-03 12 8 8 10 0 0 92.07 27.15 0.63 -0.00923 -0.01266 46 5 1 5 0 1167.530 34.50 20.01 27.15 33.46 15.5 1013.21 900000 132332 900000 -103985 -177600 900000 900000 -206262 -25687 -223188 900000 -90319 2902 900000 -104412 900000 -1517 -48461 900000 900000 84886 900000 110218 900000 192279 900000 900000 900000 -80849 900000 -41114 900000 62659 -40346 -41196 -38155 -15923 -59976 61440 900000 165969 61609 65977 36562 524538 -28740 91629 100965 7361 74187 -7875 70338 12142 -5054 77326 29764 4784 31067 3779 -11849 22412 34003 18973 31421 10076 30570 -8964 21952 2373 15770 26220 18690 2966 2040 12466 -6698 -6454 -17820 -7156 3263 -9117 -1477 -719 -5290 304 3424 -4417 -1525 5164 4491 3706 -4798 1540 -843 1180 -6111 -1007 -1973 -3030 -2241 -2113 -2312 -3338 -3747 -3593 -2209 -853 911 -1908 1910 -103 4584 4017 1768 -342 -890 -2056 -803 -1444 -123 986 2333 3304 1249 612 349 -2378 604 -1259 812 653 -231 -1091 498 -1108 621 -82 790 759 1510 928 -2665 -1013 -789 900000 584 900000 -917 -2920 900000 900000 -5459 -134 -9665 900000 -1195 17 900000 -2596 900000 -18 -972 900000 900000 562 900000 583 900000 848 900000 900000 900000 -3851 900000 -1396 900000 1023 -2064 -2126 -1818 -639 -4365 1653 900000 2343 2717 2910 2177 2314 -3144 2991 3028 584 3207 -855 3971 1371 -749 5525 3676 806 4138 645 -2242 2916 4080 2937 4892 2147 5394 -2309 4270 606 4055 6974 5804 1003 672 3772 -2201 -1910 -5738 -2206 1058 -3630 -638 -352 -2957 172 2023 -2997 -1047 3371 2907 2290 -3017 872 -491 732 -4327 -791 -1820 -3219 -2312 -2303 -2338 -3068 -3248 -3249 -2125 -853 957 -2071 2236 -141 6152 5716 2581 -495 -1237 -2827 -1119 -2137 -189 1538 3493 4698 1758 903 500 -3392 829 -1785 1299 1105 -435 -2220 995 -2416 1430 -188 1817 1771 3435 2131 -5926 -2085 -1595 SS 20240709T120727.8Z 8956.505183 63 1 54.05 2 78.76 70.66 116.99 52.23 0.00 1 0.00 1 0 25 2.487e-01 1.309e-02 2.053e-02 1.018e-03 5.685215e-01 5.225664e-04 6.604167e-03 -6.000000e+00 1.424753e-01 230.31 -2.00 3.24 -2.00 319.91 0.00e+00 8.820406e-04 1.732043e-04 3.708164e-03 -6.000000e+00 6.571276e-03 293.94 -2.00 20.00 -2.00 319.04 0.00e+00 4.949 0.001 302.00 328.00 3 6.7025e-01 1.5577e-03 5.8894e-02 -6.0000e+00 3.5470e-01 8.4446e-03 1.9030e-03 3.6204e-02 -6.0000e+00 3.8452e-01 -5.5860e-02 1.5545e-03 1.4398e-02 -6.0000e+00 2.3013e-01 1.5222e-02 8.0375e-04 4.0915e-03 -6.0000e+00 9.7724e-02 1.1285e-03 2.6726e-05 2.7737e-05 4.5294e-05 -6.0000e+00 6.7587e-03 -1.0389e-02 12 8 8 10 0 0 58.61 27.19 0.41 -0.01039 -0.01019 242 27 1 5 0 223.310 34.50 20.00 27.19 34.08 15.5 1013.20 900000 -103571 -16974 -91298 -107546 -53724 -68022 -104068 -82411 -99719 -48065 -74851 -55572 -33461 -43761 7825 -22279 -27037 -3071 -7098 -14257 -15538 -10069 -726 -12775 -3996 -5223 5121 -22986 -7252 -18383 -2106 -5352 -7690 -11402 -12624 -9983 -12006 -1625 3994 3569 2522 4322 2276 2397 1145 3220 2706 785 1267 750 4102 2545 2093 4619 3021 2434 2743 265 189 1721 3356 3322 3825 3612 1941 -332 -680 -657 1629 2460 2067 1600 1204 495 -1463 -3099 -5547 -4218 -2671 -2665 -1448 -1671 -2516 -1545 -208 272 1144 1784 1171 1073 76 -1323 -2217 -1812 -1590 -741 281 401 -2 -916 -1673 -2625 -2094 -827 -1149 -557 -49 248 1397 1806 2293 1899 1107 9 -714 -481 -124 212 677 736 844 1148 824 99 -1 -1255 -809 -431 -299 -308 -630 -925 -772 -424 47 -8 812 800 625 292 -336 -673 -490 900000 -1933 -148 -1713 -2200 -608 -939 -2335 -1718 -2772 -845 -1836 -1341 -814 -1473 191 -843 -1184 -116 -298 -675 -754 -475 -34 -740 -228 -316 277 -1575 -429 -1369 -157 -480 -793 -1227 -1317 -1073 -1523 -227 588 616 482 861 482 514 253 710 610 186 313 202 1196 762 687 1596 1113 940 1078 105 73 663 1352 1382 1789 1845 1009 -170 -349 -355 906 1548 1316 1048 771 321 -876 -1706 -3225 -2343 -1676 -1836 -1137 -1384 -2257 -1374 -197 273 1121 1773 1158 1066 70 -1172 -1928 -1657 -1550 -824 337 512 -3 -1150 -2058 -3109 -2344 -961 -1373 -696 -61 333 1945 2658 3640 2981 1718 15 -1053 -719 -181 325 1055 1185 1339 1832 1281 149 -1 -1847 -1162 -659 -470 -513 -1140 -1698 -1427 -831 95 -16 1670 1676 1296 602 -661 -1311 -943 SS 20240709T121318.2Z 8956.509239 66 1 54.06 2 77.56 71.31 116.03 53.31 0.00 1 0.00 1 0 25 1.726e-01 1.258e-02 1.012e-02 7.271e-04 5.236873e-01 3.711078e-04 6.044876e-03 -6.000000e+00 9.890559e-02 230.31 -2.00 3.24 -2.00 319.50 0.00e+00 1.389042e-03 1.070098e-04 2.910183e-03 -6.000000e+00 4.561542e-03 293.94 -2.00 20.00 -2.00 318.59 0.00e+00 4.509 0.001 302.00 328.00 3 4.9189e-01 1.0702e-03 5.2953e-02 -6.0000e+00 2.4623e-01 -6.6122e-04 1.2761e-03 3.0628e-02 -6.0000e+00 2.6693e-01 -3.5176e-02 9.7709e-04 1.3135e-02 -6.0000e+00 1.5975e-01 6.0630e-03 5.1150e-04 3.3497e-03 -6.0000e+00 6.7842e-02 2.1324e-03 -3.1003e-06 1.9964e-05 4.2057e-05 -6.0000e+00 4.6916e-03 -1.0724e-02 12 8 8 10 0 0 -0.70 27.22 0.40 -0.01072 -0.01075 375 42 1 5 0 144.140 34.50 20.00 27.22 34.34 15.5 1013.24 900000 -70695 -39028 -56508 -64454 -42168 -57835 -69659 -53400 -68497 -41713 -50057 -42208 -28219 -23173 -6108 -14413 -11932 -4114 -6996 -7214 -9085 -6835 -4912 -5408 -2877 -1011 -1868 -15663 -9478 -10771 -2872 -2049 -3779 -7939 -9518 -8413 -7934 -2057 2457 2579 1832 3314 2977 2238 2106 2760 2392 608 148 570 3317 2189 2577 3468 2500 2385 1989 569 -87 1010 2339 3290 3665 3402 1127 -359 -995 -632 1120 1734 1829 1201 808 124 -1231 -2838 -4461 -4382 -2625 -2499 -1896 -1940 -2359 -1382 -272 272 1102 1671 1373 1105 43 -1363 -2176 -1742 -1611 -727 412 582 -58 -683 -1575 -2499 -1874 -806 -1240 -625 -217 226 1399 1906 2194 1855 1143 68 -707 -403 108 335 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