File name: Pandora85s1_NewOrleansLA-XULA_20240713_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240714T061104.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240713_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240713T115332.3Z 8960.495513 54 1 54.60 2 81.96 69.53 156.97 12.67 0.00 1 0.00 1 0 17 4.925e-01 2.885e-02 1.678e-01 4.737e-03 7.419224e-01 2.685489e-03 7.653625e-03 -6.000000e+00 2.930261e-01 230.20 -2.00 3.24 -2.00 321.44 0.00e+00 -1.038793e-02 1.480821e-03 6.310291e-03 -6.000000e+00 1.751320e-02 294.16 -2.00 20.00 -2.00 320.76 0.00e+00 6.678 0.004 302.00 328.00 3 1.6857e+00 1.0192e-02 8.7438e-02 -6.0000e+00 7.2788e-01 3.0196e-01 1.4340e-02 7.1326e-02 -6.0000e+00 7.9442e-01 -5.6259e-01 1.3371e-02 1.8192e-02 -6.0000e+00 4.6956e-01 2.3675e-01 6.2317e-03 1.7021e-02 -6.0000e+00 1.9997e-01 6.8794e-05 -6.6737e-05 1.3520e-04 8.1927e-05 -6.0000e+00 1.4586e-02 -1.1535e-02 12 8 8 10 0 0 34.17 27.21 0.62 -0.01154 -0.01204 41 5 1 5 0 1331.600 34.50 20.01 27.21 34.23 19.4 1020.04 900000 900000 900000 -161833 -156026 900000 900000 900000 -169762 -216888 900000 -75505 74516 900000 -40726 900000 24789 -55229 900000 900000 900000 -5765 94518 900000 113230 900000 900000 900000 900000 900000 -29401 900000 38349 -36303 -66415 -7255 79212 -67716 22384 156793 102485 30604 75389 67987 57304 -35952 112876 95721 10001 49972 -11286 109586 276 -10769 81589 24296 6367 29754 5214 -7830 25310 32941 993 -5967 17921 30025 -13216 23083 5561 16866 26209 17765 4155 423 7046 -11574 -3698 -18638 -6694 2961 -10395 -1247 2047 -4774 1785 3170 -1959 1798 6487 -3855 6349 -4246 350 -2810 2302 -7390 -610 1061 -1366 -2439 -1860 -1349 -2127 -3606 -4116 -1927 1368 -407 -489 2980 97 772 3645 855 -447 -447 -1984 -1458 -1855 472 1385 1596 4244 802 575 650 -2699 466 -1651 265 1188 722 -681 487 -1529 582 -154 761 252 1411 713 -2058 -1100 -621 900000 900000 900000 -2641 -2154 900000 900000 900000 -3764 -8802 900000 -853 343 900000 -545 900000 228 -1225 900000 900000 900000 -98 609 900000 782 900000 900000 900000 900000 900000 -920 900000 829 -1854 -4585 -264 1276 -5516 917 2093 2783 1873 3088 3035 2795 -4401 3117 3172 810 2875 -1319 4337 36 -1745 5745 3243 1075 4081 893 -1456 3296 4139 191 -1401 3654 5500 -3655 4547 1403 4362 7080 5649 1408 144 2289 -3699 -1086 -6159 -2086 976 -4240 -543 982 -2665 997 1882 -1301 1199 4198 -2728 3844 -2668 201 -1662 1402 -5720 -472 936 -1405 -2686 -1988 -1328 -1900 -3077 -3694 -1825 1321 -427 -559 3392 129 1131 5055 1219 -624 -642 -2825 -2121 -2655 699 2078 2332 6248 1186 823 900 -3741 620 -2442 409 2053 1286 -1315 986 -3177 1272 -353 1766 597 3250 1565 -4352 -2316 -1283 SS 20240713T120919.1Z 8960.506471 59 1 54.06 2 78.74 71.31 156.05 21.82 0.00 1 0.00 1 0 25 2.485e-01 1.322e-02 3.532e-02 1.291e-03 5.698776e-01 6.661501e-04 6.617033e-03 -6.000000e+00 1.429320e-01 230.20 -2.00 3.24 -2.00 320.04 0.00e+00 4.276482e-04 2.331545e-04 3.893222e-03 -6.000000e+00 6.695763e-03 294.16 -2.00 20.00 -2.00 319.19 0.00e+00 4.942 0.001 302.00 328.00 3 1.1262e+00 2.0150e-03 5.9302e-02 -6.0000e+00 3.5530e-01 -6.8611e-03 2.4869e-03 3.7521e-02 -6.0000e+00 3.8517e-01 -4.6536e-02 2.0765e-03 1.4235e-02 -6.0000e+00 2.3021e-01 8.7006e-03 1.0689e-03 4.5877e-03 -6.0000e+00 9.7745e-02 7.2613e-04 6.2901e-05 3.5227e-05 4.6350e-05 -6.0000e+00 6.7609e-03 -1.3367e-02 12 8 8 10 0 0 -2.43 27.29 0.51 -0.01337 -0.01289 174 19 1 5 0 310.640 34.50 20.01 27.29 35.27 19.4 1020.39 900000 -108554 43223 -88344 -109790 900000 -80934 -75166 -73305 -99720 -52292 -83926 -64901 -35963 -38499 19884 -29534 -24707 278 -4635 -4031 -26398 -16154 -5757 -7492 -246 -8025 13223 -23449 -6366 -14798 1688 -6703 -7394 -18464 -16027 -7851 -17296 1126 6609 6438 1416 4359 4468 4030 -2465 4982 3029 751 -674 -690 6302 2106 350 5676 3804 2483 2493 598 -846 1327 2011 2505 2959 3309 2372 -1518 108 -482 1721 3346 2880 1598 1058 363 -1956 -2928 -5476 -4810 -2721 -3340 -1658 -1445 -2370 -1187 -150 230 1596 2127 1051 1391 59 -1242 -2122 -1684 -1729 -878 669 578 278 -641 -1583 -2771 -2116 -1013 -1349 -499 -255 94 1429 1785 2358 1983 1139 -62 -764 -823 -452 208 624 811 609 1179 752 335 -17 -1272 -989 -434 -247 -148 -609 -952 -953 -507 17 81 824 719 593 318 -299 -534 -389 900000 -1844 180 -1401 -2004 900000 -1110 -1107 -1227 -2447 -849 -1996 -1519 -792 -1085 380 -1063 -936 9 -169 -153 -1272 -722 -253 -369 -12 -449 594 -1455 -336 -954 109 -547 -684 -1924 -1561 -744 -2085 138 942 979 249 789 841 773 -513 980 619 162 -154 -171 1633 629 116 1769 1270 876 899 217 -304 469 750 1039 1381 1551 1125 -721 50 -238 942 2060 1788 1031 668 216 -1168 -1596 -2927 -2658 -1688 -2277 -1197 -1170 -2083 -1028 -139 226 1519 2055 1016 1350 54 -1080 -1808 -1505 -1748 -954 776 716 363 -820 -1896 -3211 -2311 -1149 -1657 -607 -328 122 2020 2660 3617 3144 1788 -93 -1145 -1198 -671 323 984 1320 980 1826 1189 512 -25 -1824 -1454 -644 -392 -249 -1066 -1761 -1773 -998 34 171 1696 1511 1235 660 -592 -1050 -756 SS 20240713T121517.7Z 8960.510621 62 1 53.91 2 77.51 71.97 155.58 25.09 0.00 1 0.00 1 0 25 1.781e-01 1.273e-02 1.426e-02 9.284e-04 5.242262e-01 4.749068e-04 6.043800e-03 -6.000000e+00 1.020523e-01 230.20 -2.00 3.24 -2.00 319.57 0.00e+00 1.022102e-03 1.406707e-04 2.959982e-03 -6.000000e+00 4.711587e-03 294.16 -2.00 20.00 -2.00 318.67 0.00e+00 4.492 0.001 302.00 328.00 3 9.7999e-01 1.3799e-03 5.2964e-02 -6.0000e+00 2.5398e-01 -1.0650e-02 1.6501e-03 3.1106e-02 -6.0000e+00 2.7530e-01 -3.7030e-02 1.2704e-03 1.3034e-02 -6.0000e+00 1.6480e-01 6.5363e-03 6.6479e-04 3.5055e-03 -6.0000e+00 7.0054e-02 1.3400e-03 -2.5666e-05 2.5596e-05 3.8949e-05 -6.0000e+00 4.8404e-03 -1.3704e-02 12 8 8 10 0 0 11.34 27.35 0.40 -0.01370 -0.01390 253 28 1 5 0 213.050 34.50 20.01 27.35 35.77 19.4 1020.45 900000 -75420 -29560 -58096 -77312 -19239 -71769 -61783 -65151 -65185 -39813 -53240 -37107 -30934 -24594 -47 -10688 -15340 -7103 -4534 -5602 -13680 -8244 -5887 -7211 -3274 -6058 2146 -17150 -8233 -11444 -1016 -4367 -4376 -9994 -9619 -7249 -9266 -2114 2535 3379 2494 3442 2678 2598 1123 2865 2720 484 -32 792 3927 1947 1820 3645 2636 2413 1932 603 -727 1521 2494 2816 3679 3505 1537 -530 -640 -722 1020 1921 1988 1467 923 412 -1828 -2635 -4939 -4174 -2808 -2873 -1973 -2093 -2330 -1281 -225 510 1236 1979 1294 1220 157 -1446 -2174 -1846 -1553 -771 476 721 13 -563 -1658 -2589 -2073 -1063 -1131 -579 -289 174 1340 1861 2162 1941 1190 66 -606 -499 -51 336 692 652 713 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