File name: Pandora85s1_NewOrleansLA-XULA_20240717_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240722T211615.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240717_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240717T120300.0Z 8964.502083 99 1 53.19 2 80.42 71.14 147.98 269.15 0.00 1 0.00 1 0 25 5.161e-01 4.017e-02 1.480e-01 6.475e-03 6.928065e-01 3.622528e-03 7.322148e-03 -6.000000e+00 3.045857e-01 230.11 -2.00 3.24 -2.00 321.16 0.00e+00 -6.435265e-03 1.806949e-03 4.594030e-03 -6.000000e+00 1.792849e-02 294.27 -2.00 20.00 -2.00 320.43 0.00e+00 5.723 0.002 302.00 328.00 3 3.0094e+00 1.3013e-02 7.2797e-02 -6.0000e+00 7.5370e-01 3.8729e-01 1.6960e-02 5.3515e-02 -6.0000e+00 8.2128e-01 -6.3011e-01 1.4411e-02 1.6241e-02 -6.0000e+00 4.8928e-01 2.6967e-01 7.0347e-03 1.2684e-02 -6.0000e+00 2.0930e-01 4.3576e-05 -7.5068e-04 1.8711e-04 5.7679e-05 -6.0000e+00 1.4670e-02 -1.4708e-02 12 8 8 10 0 0 99.55 27.21 0.96 -0.01471 -0.02035 18 2 1 5 0 2954.620 34.50 20.01 27.21 34.32 19.4 1016.23 900000 900000 900000 -63417 -200052 900000 900000 -72535 -78154 -120816 900000 -52399 30352 900000 -43479 900000 12127 8472 900000 31354 900000 -66172 18911 900000 900000 900000 900000 900000 -57458 900000 -39521 900000 99147 12983 -47331 69646 20308 -26158 80279 222644 126405 43809 98023 180132 10001 -42517 232128 56001 22009 49514 16832 115195 17809 8166 108145 16769 21550 35767 18979 -4183 28190 22242 -5233 -15658 8415 42008 -8647 35810 8965 15140 38126 26204 -4325 -3255 12807 -18202 -15189 -19359 -907 12121 -9325 -3116 2151 -7328 3188 1302 -6160 3520 7309 -8498 8539 -3646 3494 1227 -2192 -9056 2015 -1159 77 -3050 -1183 -1327 -1645 -2820 -4988 -1554 1732 226 -1543 861 -780 4962 4440 1112 -361 276 -4800 -2542 -2108 -1455 961 3139 5683 1349 -204 640 -2449 2246 -908 -1141 2258 655 -923 1115 -1351 1276 -979 558 -686 2513 1628 -3651 -533 -1110 900000 900000 900000 -980 -10760 900000 900000 -1162 -1520 -4009 900000 -959 278 900000 -1194 900000 250 194 900000 628 900000 -3521 476 900000 900000 900000 900000 900000 -3689 900000 -2239 900000 1872 646 -4290 1841 908 -2124 2728 2242 3898 3364 4565 3741 1120 -7948 2776 3912 2216 3958 2023 5800 2623 1444 7623 3113 3988 5853 3583 -950 4524 3934 -1347 -5056 2346 8461 -2803 7505 2601 4688 10726 8972 -1868 -1347 4610 -7301 -5851 -7445 -304 4104 -4215 -1539 1143 -4637 1932 864 -4677 2529 5148 -6919 5560 -2495 2109 747 -1475 -7456 1724 -1085 81 -3506 -1304 -1358 -1522 -2473 -4652 -1511 1716 242 -1817 1096 -1051 6964 6556 1690 -536 386 -6872 -3638 -3164 -2301 1523 4771 8097 1945 -288 863 -3289 3060 -1268 -1819 3902 1167 -1778 2220 -2746 2708 -2217 1269 -1601 5601 3471 -7694 -1100 -2257 SS 20240717T132424.9Z 8964.558622 143 1 50.44 2 63.37 79.95 164.69 282.55 0.00 1 0.00 1 0 17 5.109e-02 1.526e-02 6.291e-03 2.087e-03 2.854131e-01 1.058208e-03 3.182236e-03 -6.000000e+00 2.928996e-02 230.11 -2.00 3.24 -2.00 317.10 0.00e+00 1.414737e-03 1.519874e-04 4.773864e-04 -6.000000e+00 1.352581e-03 294.27 -2.00 20.00 -2.00 316.17 0.00e+00 2.218 0.000 302.00 328.00 3 4.8404e+00 2.7976e-03 2.6028e-02 -6.0000e+00 7.2875e-02 1.7405e-02 3.1548e-03 1.3655e-02 -6.0000e+00 7.8970e-02 1.2049e-02 1.8648e-03 6.6035e-03 -6.0000e+00 4.7281e-02 -1.6720e-02 9.1196e-04 1.8424e-03 -6.0000e+00 2.0126e-02 3.2196e-04 -9.0069e-06 5.9385e-05 2.0010e-05 -6.0000e+00 1.3881e-03 -2.0327e-02 12 9 9 12 9 1 98.91 27.44 0.52 -0.02033 -0.02039 13 2 1 5 0 3602.420 34.75 20.00 27.44 36.46 19.5 1016.92 900000 3655 25176 -7499 -23009 19739 3941 -11304 -9785 -8635 -617 -16750 -9246 9093 -5317 21222 -1505 -3977 7791 492 4900 -3213 -1329 2187 2488 343 1827 7800 -8210 2701 -4540 5136 1521 -2915 -6411 -3833 -6001 -6598 358 1668 1196 -764 613 3499 -56 -3544 2571 767 -946 660 -492 2658 599 492 3128 923 1204 1391 259 -1589 656 1320 1143 810 2259 1469 -1906 -166 -1373 883 2256 2307 665 -282 1143 -2027 -3160 -4239 -3606 -996 -2906 -1798 -1459 -2611 -660 -362 -278 769 2565 855 1997 315 -247 -1193 -1787 -1770 -50 463 789 379 -16 -1062 -2034 -1612 -1053 -1463 -250 -379 80 1114 1399 2503 2387 1677 6 -334 -1555 -921 -396 262 395 1007 1632 650 -167 357 -1510 -649 -378 -618 587 -494 -1021 -638 -989 82 25 368 287 986 651 -617 -658 -99 900000 420 2491 -928 -3006 1688 400 -1461 -1400 -1213 -90 -2595 -1446 1372 -1075 3759 -362 -1025 1873 133 1309 -934 -379 629 755 102 551 2359 -2489 766 -1432 1600 491 -1062 -2384 -1299 -2143 -2676 160 817 671 -435 358 2040 -34 -2233 1520 453 -558 380 -295 1657 408 331 2155 667 885 1033 192 -1179 480 1008 891 689 1991 1262 -1558 -135 -1132 734 2089 2163 652 -275 1044 -1861 -2629 -3493 -2898 -795 -2684 -1732 -1452 -2779 -725 -404 -331 950 3028 1019 2347 346 -263 -1261 -1897 -1918 -56 578 1029 490 -22 -1316 -2465 -1872 -1286 -1846 -326 -495 109 1594 2039 3784 3613 2443 9 -444 -2094 -1248 -536 378 575 1471 2327 954 -235 499 -2052 -838 -499 -841 844 -720 -1537 -978 -1524 133 41 612 488 1663 1068 -1030 -1061 -157 SS 20240717T132910.4Z 8964.561925 146 1 42.32 2 62.35 80.45 165.65 283.93 0.00 1 0.00 1 0 17 1.942e-02 1.152e-02 2.307e-03 1.031e-03 2.748977e-01 5.241547e-04 3.060260e-03 -6.000000e+00 1.112712e-02 230.11 -2.00 3.24 -2.00 316.55 0.00e+00 1.110568e-03 6.496453e-05 3.772656e-04 -6.000000e+00 5.139741e-04 294.27 -2.00 20.00 -2.00 315.63 0.00e+00 2.143 0.000 302.00 328.00 3 3.5234e+00 1.3719e-03 2.5080e-02 -6.0000e+00 2.7685e-02 3.3991e-03 1.5394e-03 1.3048e-02 -6.0000e+00 3.0005e-02 6.2323e-03 8.9044e-04 6.2984e-03 -6.0000e+00 1.7964e-02 -1.1819e-02 4.1984e-04 1.7228e-03 -6.0000e+00 7.6434e-03 1.3265e-03 -2.4591e-04 2.9239e-05 2.0101e-05 -6.0000e+00 5.2764e-04 -1.7463e-02 12 9 9 12 1 1 95.81 27.47 0.48 -0.01746 -0.01931 44 6 1 5 0 940.300 34.50 20.00 27.47 36.68 19.5 1016.97 900000 -696 3534 -2872 -8493 -479 -3969 -4794 -3900 -4738 -3128 -5932 -4865 268 -1172 3660 -174 575 2732 1258 2931 -205 811 1480 1185 944 1011 1160 -2818 -903 -1259 1281 667 265 -4180 -4466 -4604 -4356 -777 870 494 67 563 1106 244 244 1510 728 -144 -797 23 1629 742 1051 1568 974 1420 783 102 -134 865 1502 1866 2352 2378 558 -962 -1106 -1186 554 1133 1286 779 746 373 -1126 -2009 -3416 -3522 -2038 -2353 -1824 -1854 -2485 -1398 -572 -187 783 1518 1261 1198 404 -861 -1655 -1323 -1381 -365 583 690 210 -308 -1099 -1919 -1649 -643 -1102 -413 -333 14 1001 1473 2131 1995 1418 298 -407 -620 -120 268 567 612 707 951 629 215 209 -924 -419 -369 -218 -170 -391 -855 -860 -378 -53 -95 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