File name: Pandora85s1_NewOrleansLA-XULA_20240720_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240722T214131.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240720_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240720T115637.4Z 8967.497655 195 1 53.77 2 82.03 70.88 112.13 249.69 0.00 1 0.00 1 0 25 6.760e-01 3.865e-02 2.406e-01 6.796e-03 7.753496e-01 3.798924e-03 7.965962e-03 -6.000000e+00 3.996749e-01 230.05 -2.00 3.24 -2.00 321.58 0.00e+00 -8.945379e-03 2.104263e-03 4.345293e-03 -6.000000e+00 2.152029e-02 294.31 -2.00 20.00 -2.00 320.91 0.00e+00 6.730 0.004 302.00 328.00 3 2.0141e+00 1.4649e-02 8.2911e-02 -6.0000e+00 9.9439e-01 6.7281e-01 1.9668e-02 5.8774e-02 -6.0000e+00 1.0841e+00 -1.0353e+00 1.6214e-02 1.8849e-02 -6.0000e+00 6.3987e-01 4.3026e-01 7.6429e-03 1.2461e-02 -6.0000e+00 2.7357e-01 4.1614e-05 -7.7091e-04 1.8906e-04 8.3178e-05 -6.0000e+00 1.9161e-02 -1.4919e-02 12 9 8 11 32 0 93.85 26.92 0.35 -0.01492 -0.02071 29 3 1 5 0 1853.760 34.25 20.00 26.92 32.24 23.4 1015.22 900000 900000 900000 -62068 -131061 900000 900000 900000 -92447 -112982 900000 -97764 66202 9741 85049 900000 11885 -4264 900000 78597 900000 28483 54781 33410 900000 139316 900000 273746 -64779 900000 -6315 900000 271684 -54615 -64031 55084 -29932 -27541 75420 125784 271780 45526 103658 305021 17017 -44811 196448 99341 18089 86166 11979 900000 94206 3240 88351 49713 42475 41915 21715 -10910 44890 51968 10900 16082 25156 64081 -15242 39167 15283 19503 1820 25071 672 -6510 17048 -14908 -16427 -10237 -9850 17338 -7046 820 1984 -5708 8289 3142 -3620 3506 6479 14755 4378 -6986 -1410 -4057 2437 -11989 1283 -4133 -4228 -2658 -1262 -1670 -2788 -3908 -7417 -3313 3249 1491 -1756 259 -1206 7019 3352 2414 -615 -385 -4556 -3122 -2254 -1212 1512 2673 5890 500 290 1320 -1859 921 -2803 -565 3236 1424 -1202 575 -1032 1206 -588 1443 370 2139 1154 -2995 -2370 -1035 900000 900000 900000 -1454 -5276 900000 900000 900000 -2888 -4752 900000 -3759 557 170 818 900000 300 -133 900000 1133 900000 650 954 783 900000 1473 900000 1809 -4126 900000 -255 900000 1796 -4725 -6001 1602 -2077 -2111 2492 3076 1796 3129 4110 2016 1552 -7374 2856 3808 1602 4043 1282 900000 5479 510 6423 5618 5390 5429 3330 -2185 4954 5495 1916 3040 4788 8386 -4301 6523 3444 4795 610 7175 250 -2504 4777 -5133 -5157 -2909 -2949 4595 -2841 357 886 -2990 4019 1721 -2249 2111 3846 7943 2478 -4130 -752 -2218 1352 -8867 972 -3849 -4129 -2722 -1249 -1678 -2544 -3362 -6859 -3173 3073 1532 -1859 301 -1622 9696 4688 3427 -873 -565 -6806 -4713 -3284 -1850 2298 3914 8672 753 422 1843 -2598 1236 -4244 -889 5560 2749 -2374 1183 -2316 2842 -1374 3365 882 4937 2722 -6870 -5069 -2137 SS 20240720T121224.6Z 8967.508618 200 1 6.76 2 78.79 72.67 115.20 251.14 0.00 1 0.00 1 0 17 3.984e-01 1.797e-02 1.843e-01 7.239e-03 5.979869e-01 3.813793e-03 6.990925e-03 -6.000000e+00 2.312383e-01 230.05 -2.00 3.24 -2.00 320.29 0.00e+00 -5.485838e-04 1.454075e-03 4.641642e-03 -6.000000e+00 1.147959e-02 294.31 -2.00 20.00 -2.00 319.45 0.00e+00 4.960 0.001 302.00 328.00 3 2.2138e+00 1.1927e-02 6.1884e-02 -6.0000e+00 5.7473e-01 3.3543e-02 1.5061e-02 4.3595e-02 -6.0000e+00 6.2384e-01 -1.0301e-01 1.2969e-02 1.4878e-02 -6.0000e+00 3.7117e-01 3.5335e-02 6.5753e-03 6.2579e-03 -6.0000e+00 1.5824e-01 2.3083e-04 3.0906e-04 2.0078e-04 5.1292e-05 -6.0000e+00 1.0950e-02 -1.6830e-02 12 9 9 12 1 1 81.43 26.96 0.41 -0.01683 -0.01451 5 5 1 5 0 1125.390 34.25 20.00 26.96 32.83 23.4 1015.33 900000 -90953 900000 -94386 -171373 900000 900000 -9112 -157403 -118043 900000 -96153 -41371 290414 -37231 900000 -3879 -10702 42821 7555 42838 -33841 -31251 -15504 15973 -9350 74675 80817 -33818 5393 6645 18727 35428 -35218 -19324 3944 -1933 -28235 1000 6572 20781 558 10013 12882 -4317 -9465 7693 5480 -5422 6639 -1465 18148 6110 -3565 8961 3752 4579 5982 1158 -6660 3738 86 365 -2732 1837 6471 -436 4311 1022 3116 8059 5352 254 -238 575 -2949 -5917 -6083 -5180 -2485 -3887 -1862 -2019 -2915 -1489 340 389 641 3545 546 660 209 120 -2830 -2188 -2123 -1431 1121 167 49 -636 -2274 -2851 -1543 -1269 -1440 -579 778 113 2108 1771 3058 1828 1849 311 -436 -1059 -1295 -127 -525 361 368 2077 928 260 182 -1053 -1440 -1129 -155 437 -619 -650 -1585 -756 705 -9 1091 391 662 478 -813 -567 -126 900000 -991 900000 -1210 -4395 900000 900000 -64 -5107 -2914 900000 -2170 -642 2048 -867 900000 -90 -294 755 202 846 -1456 -1344 -623 518 -422 1527 1539 -1932 209 286 845 1574 -3577 -1690 261 -143 -3146 102 779 2506 82 1568 2035 -745 -1742 1335 899 -1026 1166 -303 3467 1457 -1024 2459 1143 1444 1902 381 -2306 1167 30 139 -1117 786 2659 -185 1751 452 1531 4310 2936 150 -138 335 -1612 -3012 -2967 -2612 -1401 -2419 -1312 -1491 -2339 -1253 303 343 590 3235 508 582 184 100 -2356 -1913 -1963 -1515 1248 199 62 -783 -2637 -3195 -1613 -1386 -1700 -713 945 148 2816 2644 4649 2906 2892 471 -627 -1568 -1968 -190 -841 591 594 3185 1397 399 269 -1516 -2040 -1704 -247 730 -1081 -1197 -2950 -1485 1462 -19 2299 843 1412 975 -1660 -1097 -239 SS 20240720T122110.2Z 8967.514702 206 1 4.89 2 76.97 73.65 116.91 251.93 0.00 1 0.00 1 0 17 3.586e-01 2.139e-02 2.110e-01 1.007e-02 5.266706e-01 5.227307e-03 6.086359e-03 -6.000000e+00 2.064838e-01 230.05 -2.00 3.24 -2.00 319.83 0.00e+00 6.062602e-04 1.705392e-03 3.080268e-03 -6.000000e+00 9.832821e-03 294.31 -2.00 20.00 -2.00 318.96 0.00e+00 4.318 0.001 302.00 328.00 3 2.9770e+00 1.5425e-02 5.1913e-02 -6.0000e+00 5.1311e-01 2.4546e-02 1.8792e-02 3.2208e-02 -6.0000e+00 5.5643e-01 -7.8202e-02 1.5093e-02 1.3002e-02 -6.0000e+00 3.3298e-01 2.9544e-02 7.8078e-03 3.9382e-03 -6.0000e+00 1.4210e-01 2.0971e-04 -6.0075e-04 2.8294e-04 4.0442e-05 -6.0000e+00 9.7654e-03 -1.7072e-02 12 9 9 12 1 1 999.00 27.00 0.75 -0.01707 -0.02159 2 4 1 5 0 1629.140 34.25 20.01 27.00 33.05 23.4 1015.51 900000 121746 900000 -92964 -28127 900000 -23729 49697 -144488 -104572 -122499 -25247 -35376 246032 -30285 900000 -45318 -20860 79962 53856 90658 -18167 12713 18028 50148 9637 -2468 48079 -29787 -2229 -31756 35117 12440 -17091 -10555 22034 -13153 -19385 -1752 15924 30816 4273 11217 16342 658 -4936 18280 1144 -5384 -2728 -1768 22151 -3255 3354 11711 5277 -1533 1574 6156 -1093 339 -475 249 -1934 4431 6396 -4450 1317 -3403 1154 7135 1390 -1495 658 4571 -3707 -6460 -7453 -981 -2337 -2090 -875 -10 -723 -115 -1261 -1244 811 916 1231 1413 -2300 904 -3152 -1659 -1685 -514 676 -899 532 719 -3022 -2622 -2262 -2057 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