File name: Pandora85s1_NewOrleansLA-XULA_20240721_L2Fit_fwvt1c2d20230315p1-8.txt File generation date: 20240722T215438.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240721_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0669 492.1877 492.3084 492.4291 492.5497 492.6704 492.7911 492.9117 493.0323 493.1529 493.2735 493.3940 493.5146 493.6351 493.7556 493.8761 493.9966 494.1170 494.2375 494.3579 494.4783 494.5987 494.7190 494.8394 494.9597 495.0801 495.2004 495.3207 495.4409 495.5612 495.6814 495.8016 495.9218 496.0420 496.1622 496.2824 496.4025 496.5226 496.6427 496.7628 496.8829 497.0029 497.1229 497.2430 497.3630 497.4829 497.6029 497.7229 497.8428 497.9627 498.0826 498.2025 498.3223 498.4422 498.5620 498.6818 498.8016 498.9214 499.0412 499.1609 499.2806 499.4003 499.5200 499.6397 499.7594 499.8790 499.9986 500.1182 500.2378 500.3574 500.4770 500.5965 500.7160 500.8355 500.9550 501.0745 501.1939 501.3134 501.4328 501.5522 501.6716 501.7909 501.9103 502.0296 502.1489 502.2682 502.3875 502.5068 502.6260 502.7453 502.8645 502.9837 503.1028 503.2220 503.3411 503.4603 503.5794 503.6985 503.8175 503.9366 504.0556 504.1747 504.2937 504.4127 504.5316 504.6506 504.7695 504.8884 505.0073 505.1262 505.2451 505.3640 505.4828 505.6016 505.7204 505.8392 505.9580 506.0767 506.1954 506.3141 506.4328 506.5515 506.6702 506.7888 506.9074 507.0261 507.1446 507.2632 507.3818 507.5003 507.6188 507.7373 507.8558 507.9743 508.0928 508.2112 508.3296 508.4480 508.5664 508.6848 508.8031 508.9214 509.0398 509.1581 509.2763 509.3946 509.5128 509.6311 509.7493 509.8675 509.9857 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240721T115546.8Z 8968.497070 217 1 54.81 2 82.31 70.95 99.21 246.15 0.00 1 0.00 1 0 22 4.402e-03 4.354e-03 4.744e-04 4.735e-04 1.673710e+04 3.560737e+01 1.070151e+03 -6.000000e+00 2.553993e+02 294.32 -2.00 20.00 -2.00 505.32 0.00e+00 2.277559e-03 1.346705e-05 1.454322e-04 -6.000000e+00 1.269095e-04 294.32 -2.00 20.00 -2.00 500.50 0.00e+00 7.712680e-01 9.312032e-03 9.148063e-02 -6.000000e+00 8.644766e-02 230.03 -2.00 3.24 -2.00 502.08 0.00e+00 6.938 0.004 489.00 513.00 1 5.2950e+00 7.1695e-04 1.3103e-02 -6.0000e+00 6.6631e-03 -1.1325e-03 1.7981e-04 2.3055e-03 -6.0000e+00 1.7122e-03 3.2467e-03 1.3323e-03 4.2928e-05 1.0008e-04 -6.0000e+00 4.4829e-04 -8.4853e-03 11 8 0 10 0 0 99.66 26.89 2.05 -0.00849 0.00076 31 3 1 4 0 1767.870 34.25 20.00 26.89 31.70 23.4 1015.79 -909 -562 -309 -109 587 742 744 655 597 621 273 -72 -265 -306 -567 -449 -7 86 -57 171 351 230 299 441 273 524 502 -95 -337 -152 -791 -632 -63 164 -69 303 386 109 -59 -47 -246 -86 156 316 456 501 434 340 22 -460 -464 -849 -937 -815 -533 -432 -97 76 176 401 359 296 343 331 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-27 -108 -481 -554 -792 -895 -815 SQ 20240721T120825.4Z 8968.505849 219 1 5.92 2 79.71 72.39 101.61 247.52 0.00 1 0.00 1 0 22 4.072e-03 4.027e-03 1.002e-04 1.000e-04 1.439301e+04 7.377700e+00 9.311587e+02 -6.000000e+00 2.362433e+02 294.32 -2.00 20.00 -2.00 505.30 0.00e+00 1.681886e-03 2.840669e-06 1.115416e-04 -6.000000e+00 1.173915e-04 294.32 -2.00 20.00 -2.00 500.46 0.00e+00 6.187129e-01 1.969950e-03 7.875826e-02 -6.000000e+00 7.996666e-02 230.03 -2.00 3.24 -2.00 502.05 0.00e+00 5.365 0.002 489.00 513.00 1 2.2755e-01 1.5171e-04 1.0548e-02 -6.0000e+00 6.1635e-03 1.9371e-03 3.8170e-05 1.9802e-03 -6.0000e+00 1.5839e-03 6.6076e-01 1.3825e-03 9.1991e-06 8.6287e-05 -6.0000e+00 4.1467e-04 -8.9425e-03 11 8 0 10 0 0 6.12 26.90 1.95 -0.00894 0.00065 793 88 1 4 0 7.460 34.25 20.01 26.90 32.52 23.5 1015.83 -806 -503 -282 -167 473 749 721 615 543 574 300 -102 -217 -246 -499 -429 -93 9 -117 88 310 177 236 405 333 510 500 -51 -263 -78 -534 -594 9 115 -146 224 398 41 -155 -117 -89 -88 158 304 387 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248 268 561 478 246 543 401 28 303 565 277 485 733 488 186 193 139 51 -3 -206 -448 -550 -681 -878 -816 SQ 20240721T120831.4Z 8968.505919 219 2 5.92 2 79.69 72.40 101.63 247.53 0.00 1 0.00 1 0 22 4.084e-03 4.037e-03 1.003e-04 1.001e-04 1.436349e+04 7.378889e+00 9.297228e+02 -6.000000e+00 2.369525e+02 294.32 -2.00 20.00 -2.00 505.30 0.00e+00 1.703782e-03 2.841495e-06 1.125632e-04 -6.000000e+00 1.177441e-04 294.32 -2.00 20.00 -2.00 500.46 0.00e+00 6.156598e-01 1.970555e-03 7.857451e-02 -6.000000e+00 8.020741e-02 230.03 -2.00 3.24 -2.00 502.05 0.00e+00 5.355 0.002 489.00 513.00 1 2.2968e-01 1.5176e-04 1.0534e-02 -6.0000e+00 6.1821e-03 2.0110e-03 3.8186e-05 1.9755e-03 -6.0000e+00 1.5886e-03 6.6025e-01 1.3866e-03 9.2127e-06 8.6152e-05 -6.0000e+00 4.1591e-04 -9.0481e-03 11 8 0 10 0 0 -9.59 26.90 1.95 -0.00905 0.00057 793 88 1 4 0 7.460 34.25 20.01 26.90 32.52 23.5 1015.83 -781 -495 -296 -160 465 757 722 595 540 582 294 -59 -222 -247 -515 -432 -91 26 -97 127 303 158 274 428 331 485 502 -46 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