File name: Pandora85s1_NewOrleansLA-XULA_20240722_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240723T061450.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240722_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240722T115929.4Z 8969.499646 216 1 46.09 2 81.65 71.55 86.76 243.52 0.00 1 0.00 1 0 17 4.869e-01 2.262e-02 2.182e-01 4.112e-03 7.291084e-01 2.268803e-03 8.068140e-03 -6.000000e+00 2.846026e-01 230.02 -2.00 3.24 -2.00 321.25 0.00e+00 -3.339372e-03 1.173701e-03 6.881544e-03 -6.000000e+00 1.447391e-02 294.34 -2.00 20.00 -2.00 320.55 0.00e+00 6.464 0.003 302.00 328.00 3 1.4591e+00 8.2068e-03 8.3669e-02 -6.0000e+00 7.0824e-01 2.2583e-01 1.1304e-02 6.4721e-02 -6.0000e+00 7.7133e-01 -4.0568e-01 1.0605e-02 1.8714e-02 -6.0000e+00 4.5899e-01 1.6721e-01 5.0515e-03 1.1242e-02 -6.0000e+00 1.9601e-01 1.0479e-04 -1.8459e-04 1.1358e-04 6.0698e-05 -6.0000e+00 1.3724e-02 -1.6886e-02 12 9 9 12 1 1 87.08 26.90 0.57 -0.01689 -0.01827 40 5 1 5 0 1123.860 34.25 20.00 26.90 32.62 23.4 1015.93 900000 900000 900000 -168566 -224233 900000 -81604 900000 -160989 -205179 -10577 -176245 34604 900000 16086 900000 24 -117305 900000 127441 900000 -74273 74562 78974 900000 40172 92883 900000 -51015 125868 -31906 900000 22851 -48634 -66165 14333 -8887 -34001 32094 52587 61039 12387 57806 30244 11841 -35142 47106 27590 -7636 -1955 -1270 64867 7160 74 33257 21882 12899 10067 5100 -3515 6877 16363 320 -10123 14852 18763 -6494 10421 4140 8579 17541 10301 3144 -2931 3201 -7086 -10302 -2886 -8130 3423 -5415 -2176 -1403 -3357 1487 1572 -2177 2529 3326 -2228 4147 -2749 -108 -5535 -1125 -4147 -298 -461 -469 -1284 -1344 -1760 -1639 -1501 -3178 -1319 537 -455 -567 947 811 3917 2501 1364 -662 -760 -2112 -1782 -338 110 308 1604 2691 1067 1049 592 -2166 -64 -892 -377 888 24 -631 -575 -890 659 -110 519 720 1372 439 -1552 -740 -847 900000 900000 900000 -2269 -4813 900000 -416 900000 -2401 -5374 -42 -3975 138 900000 109 900000 0 -4267 900000 510 900000 -2318 537 600 900000 547 781 900000 -1674 705 -983 900000 576 -2841 -4660 430 -352 -2000 1194 1978 2491 907 2845 2021 952 -4542 2714 1976 -813 -209 -148 4439 974 12 4192 3283 2225 1829 955 -691 1202 2737 70 -2574 3595 4460 -1772 2694 1218 2509 5385 3684 1237 -1188 1134 -2506 -3403 -942 -2700 1182 -2441 -1110 -810 -1968 885 1007 -1539 1781 2369 -1658 2750 -1822 -72 -3567 -748 -3274 -264 -440 -511 -1500 -1537 -1873 -1566 -1452 -3001 -1319 556 -507 -687 1171 1139 5515 3750 2067 -988 -1082 -2973 -2564 -506 174 497 2498 3981 1555 1580 865 -3151 -90 -1278 -616 1516 46 -1209 -1165 -1939 1433 -252 1206 1694 3165 970 -3279 -1550 -1745 SS 20240722T121339.4Z 8969.509483 221 1 53.93 2 78.73 73.16 89.39 245.32 0.00 1 0.00 1 0 17 2.670e-01 1.260e-02 2.035e-02 9.695e-04 5.783295e-01 4.999435e-04 6.756005e-03 -6.000000e+00 1.529462e-01 230.02 -2.00 3.24 -2.00 320.04 0.00e+00 1.126673e-03 1.744287e-04 3.964245e-03 -6.000000e+00 7.070085e-03 294.34 -2.00 20.00 -2.00 319.19 0.00e+00 4.937 0.001 302.00 328.00 3 5.5796e-01 1.5123e-03 5.9438e-02 -6.0000e+00 3.8044e-01 1.6785e-03 1.8654e-03 3.7751e-02 -6.0000e+00 4.1238e-01 -6.3770e-02 1.5486e-03 1.4721e-02 -6.0000e+00 2.4693e-01 1.9725e-02 7.9758e-04 4.3587e-03 -6.0000e+00 1.0507e-01 1.2694e-03 -2.8838e-04 2.6353e-05 5.1832e-05 -6.0000e+00 7.2565e-03 -1.6066e-02 12 8 8 10 0 0 99.84 26.95 0.41 -0.01607 -0.01823 337 37 1 5 0 160.010 34.25 20.01 26.95 33.74 23.4 1015.94 900000 -97040 -36153 -98492 -111431 -58009 -108823 -91818 -96890 -93017 -56453 -89715 -60286 -44482 -32837 1772 -24296 -26395 -13105 -11201 -4751 -23787 -13636 -9867 -7915 -6417 -13967 1491 -15277 -13343 -16374 -4202 -4460 -7980 -13241 -13089 -12416 -9601 -3082 884 4232 2476 3183 2021 3203 1354 3154 2653 -768 -502 1518 4624 2436 2323 4639 3420 3000 3465 1705 175 2248 2872 1979 3915 4234 2178 -411 -515 -94 1427 2870 2202 1600 1084 378 -1803 -3179 -3838 -4922 -2745 -2400 -1660 -1795 -2457 -1359 -336 366 1368 1756 1248 1144 81 -1064 -2325 -1943 -1735 -847 196 592 -67 -712 -1837 -2457 -1992 -1199 -1231 -601 -280 112 1228 1742 2223 1810 1125 109 -680 -446 -70 260 527 643 665 1116 841 405 167 -1226 -829 -256 -192 -239 -661 -825 -797 -377 -72 72 618 750 551 231 -220 -592 -479 900000 -1477 -335 -1751 -2097 -603 -1975 -1589 -2034 -2111 -945 -2231 -1328 -1056 -869 41 -832 -1021 -487 -437 -183 -1122 -594 -450 -388 -334 -823 75 -870 -751 -1067 -287 -356 -745 -1321 -1246 -1233 -1068 -391 133 654 428 581 389 620 271 634 546 -169 -115 370 1223 729 696 1469 1153 1059 1244 615 63 791 1065 827 1817 1982 1048 -196 -245 -46 790 1664 1392 1045 695 229 -1090 -1763 -2043 -2752 -1596 -1640 -1213 -1480 -2059 -1198 -316 343 1325 1732 1227 1069 76 -941 -2022 -1771 -1678 -883 233 749 -85 -890 -2269 -2918 -2224 -1389 -1460 -745 -368 149 1690 2652 3497 2823 1816 169 -1002 -665 -107 397 854 1030 1052 1776 1303 606 252 -1806 -1187 -389 -313 -412 -1190 -1505 -1522 -732 -144 149 1310 1560 1140 475 -447 -1150 -916 SS 20240722T141847.8Z 8969.596387 297 1 53.79 2 52.11 86.92 113.93 259.52 0.00 1 0.00 1 0 17 1.739e-02 1.204e-02 2.077e-03 1.251e-03 2.083919e-01 6.408358e-04 2.347771e-03 -6.000000e+00 9.970945e-03 230.01 -2.00 3.24 -2.00 315.56 0.00e+00 9.224992e-04 6.392574e-05 1.915286e-04 -6.000000e+00 4.606695e-04 294.34 -2.00 20.00 -2.00 314.73 0.00e+00 1.624 0.000 302.00 328.00 3 4.7297e+00 1.6562e-03 1.9018e-02 -6.0000e+00 2.4802e-02 3.1309e-02 1.8468e-03 9.9218e-03 -6.0000e+00 2.6874e-02 6.3934e-03 1.0568e-03 4.7906e-03 -6.0000e+00 1.6092e-02 -1.2430e-02 4.7693e-04 1.3262e-03 -6.0000e+00 6.8549e-03 7.2879e-04 -2.5510e-04 3.5136e-05 1.7074e-05 -6.0000e+00 4.7244e-04 -2.2921e-02 12 8 8 10 0 0 99.86 27.40 0.48 -0.02292 -0.02484 34 4 1 5 0 1581.850 34.50 20.00 27.40 36.02 23.6 1016.47 900000 1762 4556 -1404 -6331 -675 -3862 -1643 -2869 -3048 -2613 -5085 -2435 -58 -336 3326 183 37 2454 1235 3429 86 1112 2011 1347 1382 908 1209 -1627 -617 -742 1144 899 -981 -5113 -4257 -5017 -3799 -958 362 186 -302 694 949 320 -99 1550 354 -396 -730 -237 2025 716 706 1510 1187 1203 516 325 -386 647 1524 2008 1851 2059 529 -888 -1392 -1198 689 1844 1252 575 483 517 -896 -1765 -2710 -3842 -1881 -2457 -1817 -2018 -2650 -1005 -597 -343 728 1490 940 1212 353 -490 -1553 -996 -1271 -215 396 1009 329 4 -1170 -1601 -1492 -1133 -1114 -616 -255 -15 879 1586 2560 2077 1590 396 -422 -763 -404 -235 397 435 731 752 457 349 304 -751 -376 -441 -452 185 -337 -690 -756 -491 26 -140 342 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