File name: Pandora85s1_NewOrleansLA-XULA_20240724_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240725T061432.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240724_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240724T122521.8Z 8971.517613 227 1 54.51 2 76.50 74.84 64.46 241.83 0.00 1 0.00 1 0 25 2.193e-01 1.783e-02 5.587e-02 2.961e-03 4.884128e-01 1.536775e-03 5.730538e-03 -6.000000e+00 1.262914e-01 229.98 -2.00 3.24 -2.00 319.64 0.00e+00 2.477241e-03 4.715867e-04 2.883026e-03 -6.000000e+00 6.104690e-03 294.37 -2.00 20.00 -2.00 318.76 0.00e+00 4.177 0.001 302.00 328.00 3 3.4129e+00 4.4924e-03 4.9273e-02 -6.0000e+00 3.1371e-01 6.1795e-02 5.3956e-03 2.8612e-02 -6.0000e+00 3.4021e-01 -2.7962e-02 4.2776e-03 1.2625e-02 -6.0000e+00 2.0370e-01 -1.6444e-03 2.2503e-03 3.0750e-03 -6.0000e+00 8.7813e-02 1.5547e-04 1.4105e-04 8.4332e-05 4.5632e-05 -6.0000e+00 5.9906e-03 -2.2267e-02 12 9 8 11 32 0 99.95 26.96 0.56 -0.02227 -0.02121 30 3 1 5 0 1816.870 34.25 20.00 26.96 32.48 23.5 1019.40 900000 900000 900000 -79743 -73170 900000 26319 -19076 -72771 -85219 33031 -43899 -6494 102074 5293 900000 25 -27033 76216 5712 79053 -9383 15242 26332 20784 12027 14466 62803 -24290 26427 -22775 41454 3886 -19873 -18201 -2098 -12952 -15994 2985 9231 12836 -1361 6392 8934 -452 -13660 12748 3251 -4557 1620 -985 9332 -70 -5132 7368 4902 1740 4748 -170 -3781 995 2483 3780 -3518 3047 4769 -4408 4111 2127 2485 5747 2622 -927 -832 661 -4499 -4806 -4710 -5758 752 -2345 -2896 -1705 -3555 224 549 -346 1329 2551 -630 1754 -123 454 -2527 -1158 -2691 998 -181 610 -450 77 -1179 -817 -1762 -1676 -1040 -428 -168 12 1385 1476 3109 2334 1579 -634 -779 -1787 -1057 -543 -71 382 1512 1805 828 -119 -206 -1452 -1094 -903 -1064 328 -293 -649 -521 -1230 40 -230 625 893 894 492 -821 -177 -77 900000 900000 900000 -2393 -1900 900000 243 -308 -2289 -3369 419 -1254 -148 972 163 900000 1 -1716 1870 302 2099 -609 783 1292 1164 781 956 2537 -2236 1457 -2254 2500 390 -2827 -2563 -239 -1708 -2483 461 1630 2310 -308 1414 2004 -113 -3953 2876 813 -1253 430 -286 2703 -24 -2031 2755 1956 740 1995 -74 -1672 421 1097 1674 -1875 1646 2522 -2425 2038 1110 1447 3690 1732 -652 -571 456 -2975 -2872 -2647 -3333 459 -1589 -2257 -1467 -3095 199 522 -354 1397 2709 -685 1767 -117 398 -2182 -1019 -2678 1090 -212 748 -586 97 -1487 -933 -1924 -1914 -1275 -548 -212 16 1991 2189 4881 3776 2507 -972 -1117 -2492 -1490 -802 -111 620 2415 2793 1255 -174 -307 -2102 -1530 -1325 -1631 544 -495 -1153 -909 -2284 79 -449 1235 1795 1787 947 -1606 -328 -140 SS 20240724T123527.6Z 8971.524625 230 1 54.01 2 74.38 75.96 66.33 243.55 0.00 1 0.00 1 0 17 6.565e-02 1.164e-02 2.810e-03 4.230e-04 4.279961e-01 2.141111e-04 4.805201e-03 -6.000000e+00 3.761936e-02 229.98 -2.00 3.24 -2.00 318.50 0.00e+00 1.531417e-03 4.520522e-05 1.428878e-03 -6.000000e+00 1.738918e-03 294.37 -2.00 20.00 -2.00 317.54 0.00e+00 3.646 0.001 302.00 328.00 3 3.7807e-01 5.8686e-04 4.1975e-02 -6.0000e+00 9.3565e-02 -1.4585e-02 6.7543e-04 2.1615e-02 -6.0000e+00 1.0140e-01 -1.0422e-02 4.4692e-04 1.0173e-02 -6.0000e+00 6.0724e-02 -2.7998e-03 2.3326e-04 2.6580e-03 -6.0000e+00 2.5854e-02 6.0231e-03 -1.8645e-04 1.1847e-05 2.7921e-05 -6.0000e+00 1.7841e-03 -1.9347e-02 12 8 8 10 0 0 26.70 27.00 0.40 -0.01935 -0.02075 674 75 1 5 0 80.120 34.25 20.02 27.00 33.17 23.4 1019.51 900000 -20532 -12739 -19283 -25186 -25371 -26254 -24183 -20617 -20203 -19239 -20433 -14366 -10026 -6709 -1412 -2517 -2249 805 74 2068 -1712 -1074 244 -552 -532 -254 -1753 -4846 -4451 -3879 -770 543 -802 -4290 -5898 -5275 -4468 -428 1123 1285 912 1789 1757 1602 2047 1713 970 524 -163 573 1655 1684 1863 2005 1592 1774 956 455 167 661 1467 2621 3513 2864 790 -344 -1404 -1119 700 1169 1359 1130 883 294 -1044 -2056 -3558 -3898 -2675 -2262 -1805 -1947 -2457 -1546 -563 227 845 1414 1347 938 229 -1014 -1904 -1549 -1415 -687 386 766 149 -509 -1416 -2308 -1842 -747 -1200 -641 -231 194 1105 1815 2127 1785 1278 193 -545 -286 50 425 709 653 657 900 762 351 243 -876 -835 -178 -245 -245 -570 -821 -877 -348 -92 12 652 745 415 182 -179 -693 -603 900000 -885 -557 -912 -1161 -1087 -1170 -1173 -1099 -1188 -1168 -1293 -973 -787 -616 -145 -267 -256 96 9 268 -233 -147 35 -86 -88 -44 -302 -814 -731 -682 -149 107 -178 -987 -1305 -1206 -1156 -128 370 454 351 720 733 678 871 739 421 230 -73 253 793 877 977 1120 927 1002 554 262 95 375 872 1697 2364 1973 549 -240 -963 -785 510 916 1149 938 757 240 -829 -1486 -2576 -2857 -2046 -1895 -1631 -1871 -2425 -1600 -596 244 946 1612 1525 1013 239 -1038 -1865 -1548 -1495 -783 475 973 200 -665 -1803 -2812 -2129 -898 -1511 -813 -308 264 1550 2668 3226 2762 1927 285 -781 -406 72 622 1071 1002 1007 1385 1142 523 346 -1250 -1152 -255 -361 -382 -921 -1383 -1485 -601 -164 22 1206 1405 782 331 -321 -1233 -1056 SS 20240724T124556.2Z 8971.531901 233 1 54.01 2 72.18 77.11 68.29 245.27 0.00 1 0.00 1 0 25 3.788e-02 1.129e-02 1.560e-03 3.423e-04 3.824188e-01 1.733883e-04 4.261176e-03 -6.000000e+00 2.170619e-02 229.98 -2.00 3.24 -2.00 317.98 0.00e+00 1.387273e-03 3.116252e-05 9.698630e-04 -6.000000e+00 1.003321e-03 294.37 -2.00 20.00 -2.00 317.01 0.00e+00 3.221 0.000 302.00 328.00 3 4.2768e-01 4.6719e-04 3.7033e-02 -6.0000e+00 5.3987e-02 -1.3847e-02 5.3165e-04 1.8682e-02 -6.0000e+00 5.8509e-02 -2.4437e-03 3.3140e-04 8.9153e-03 -6.0000e+00 3.5037e-02 -6.5776e-03 1.6948e-04 2.3878e-03 -6.0000e+00 1.4918e-02 9.0648e-03 -2.3248e-04 9.6548e-06 2.4651e-05 -6.0000e+00 1.0293e-03 -1.9645e-02 12 8 8 10 0 0 99.48 27.08 0.39 -0.01965 -0.02139 858 95 1 5 0 62.940 34.25 20.01 27.08 34.38 23.5 1019.45 900000 -9216 -4158 -8460 -13657 -15288 -15040 -13240 -10347 -11311 -11029 -13211 -9901 -5645 -2226 758 -718 69 1670 1431 2374 -305 634 1184 542 517 234 -847 -3099 -3110 -1618 -190 884 -77 -3774 -5426 -5108 -3944 -660 781 959 640 1359 1266 1181 1554 1357 588 280 -504 634 1458 1256 1821 1664 1361 1462 742 341 150 513 1455 2568 3351 2625 541 -375 -1613 -1106 630 1099 1115 901 788 298 -835 -1896 -3195 -3664 -2518 -2262 -1737 -1959 -2601 -1530 -598 144 822 1338 1328 935 314 -964 -1773 -1475 -1260 -655 433 836 178 -472 -1306 -2238 -1720 -736 -1177 -565 -260 106 1118 1786 2041 1837 1293 288 -491 -263 52 372 688 600 591 849 712 290 264 -834 -728 -164 -278 -261 -593 -808 -864 -305 -45 24 615 746 418 153 -217 -721 -602 900000 -608 -284 -607 -945 -992 -997 -954 -822 -1002 -1009 -1259 -1023 -606 -276 107 -114 12 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