File name: Pandora85s1_NewOrleansLA-XULA_20240727_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240728T061513.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240727_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240727T120100.5Z 8974.500700 216 1 54.24 2 81.87 72.68 21.41 212.82 0.00 1 0.00 1 0 25 6.211e-01 1.760e-02 2.301e-01 2.975e-03 7.338754e-01 1.645041e-03 9.029336e-03 -6.000000e+00 3.601067e-01 229.92 -2.00 3.24 -2.00 321.23 0.00e+00 2.605555e-04 8.619232e-04 1.008548e-02 -6.000000e+00 1.969313e-02 294.41 -2.00 20.00 -2.00 320.53 0.00e+00 6.615 0.003 302.00 328.00 3 8.9287e-01 6.0075e-03 9.3078e-02 -6.0000e+00 8.9724e-01 1.6875e-01 8.3627e-03 8.0853e-02 -6.0000e+00 9.7653e-01 -2.6277e-01 8.1373e-03 2.1573e-02 -6.0000e+00 5.8432e-01 9.4277e-02 3.8740e-03 1.1411e-02 -6.0000e+00 2.5348e-01 1.5791e-04 -1.3101e-04 8.1124e-05 9.2029e-05 -6.0000e+00 1.7378e-02 -2.0741e-02 12 8 8 10 0 0 -0.24 27.07 0.61 -0.02074 -0.02173 84 9 1 5 0 645.630 34.50 20.00 27.07 33.59 23.8 1014.76 900000 900000 900000 900000 -238899 900000 -206464 -70948 -56407 -223333 900000 -129479 -103058 900000 71799 900000 -31097 -107061 900000 359255 900000 -91579 20637 7659 69384 23818 239400 900000 -22847 237333 -84669 900000 9169 -40174 -52252 -22457 -19343 -32313 10778 36108 22405 8020 30227 10430 -10466 -23239 39098 7864 -15275 19681 42 24349 -895 -3789 26898 14550 4965 13485 5024 4587 4540 5688 -821 -5893 4419 8656 -4421 6625 6137 4859 9276 5297 1210 902 1515 -6207 -7305 -1643 -5913 1526 -1407 -1143 -815 -4579 409 2690 -988 2537 2662 -38 1915 -2157 -948 -2677 -2774 -5313 259 -586 800 -1026 -1446 -1960 -2181 -2116 -1975 -2375 -168 44 -27 2019 974 3370 2403 1372 -928 -1071 -1505 1288 -5 -27 482 1400 2272 791 185 213 -2076 -1229 -451 -662 -88 -789 -799 -726 -852 178 -17 520 1192 916 322 -724 -646 -239 900000 900000 900000 900000 -3584 900000 -2228 -224 -178 -4232 900000 -1125 -925 900000 208 900000 -333 -2759 900000 1040 900000 -2545 191 89 482 283 693 900000 -437 687 -3555 900000 220 -1815 -2723 -832 -728 -1600 424 1369 1155 529 1707 749 -939 -2409 2230 633 -1632 1584 5 2355 -125 -601 3434 2233 880 2249 897 797 785 1029 -179 -1554 1176 2268 -1181 1780 1609 1475 3098 1998 488 354 550 -2194 -2365 -487 -1945 545 -621 -590 -478 -2782 252 1742 -706 1829 1956 -29 1335 -1462 -604 -1720 -1922 -4353 217 -578 827 -1151 -1595 -2169 -2171 -1962 -1895 -2468 -180 47 -31 2541 1312 4918 3724 2147 -1437 -1581 -2175 1856 -7 -41 753 2258 3487 1193 271 301 -2907 -1682 -663 -1050 -157 -1468 -1591 -1446 -1819 383 -39 1192 2759 2101 706 -1590 -1338 -484 SS 20240727T121610.3Z 8974.511231 221 1 54.06 2 78.72 74.42 23.29 221.03 0.00 1 0.00 1 0 25 2.552e-01 1.297e-02 1.994e-02 1.015e-03 5.739197e-01 5.222581e-04 6.773010e-03 -6.000000e+00 1.462729e-01 229.92 -2.00 3.24 -2.00 319.92 0.00e+00 1.606584e-03 1.760622e-04 3.937690e-03 -6.000000e+00 6.762392e-03 294.41 -2.00 20.00 -2.00 319.06 0.00e+00 4.935 0.001 302.00 328.00 3 6.6763e-01 1.5608e-03 5.9095e-02 -6.0000e+00 3.6375e-01 1.6126e-02 1.9125e-03 3.6889e-02 -6.0000e+00 3.9418e-01 -6.8089e-02 1.5717e-03 1.4727e-02 -6.0000e+00 2.3606e-01 1.9633e-02 8.1428e-04 4.0523e-03 -6.0000e+00 1.0058e-01 1.1369e-03 -6.5700e-05 2.7476e-05 5.1827e-05 -6.0000e+00 6.9336e-03 -2.2471e-02 12 8 8 10 0 0 27.59 27.15 0.40 -0.02247 -0.02296 260 29 1 5 0 207.900 34.50 20.01 27.15 34.96 23.8 1014.84 900000 -89236 -28576 -80817 -111779 -72207 -105969 -88481 -86258 -99313 -62681 -69635 -57970 -41674 -25146 1960 -26835 -28703 -9221 -10177 -862 -28384 -9871 -11035 -11257 -4321 -6234 1179 -16953 -12063 -18771 -1416 -5744 -7431 -11303 -9784 -12299 -10648 -1828 1790 4153 2809 3878 2863 1320 413 4770 1773 -448 1615 1714 4089 1834 3040 4666 4026 3091 3023 1837 935 1282 2244 2299 3676 4059 2032 -368 -646 -391 1488 2363 1819 1154 958 179 -1691 -3550 -4275 -4240 -2836 -2405 -1797 -1780 -2762 -1206 -59 553 1325 1830 1150 877 39 -1222 -2324 -2002 -2159 -776 245 617 -102 -724 -1576 -2476 -1994 -961 -1331 -557 -311 344 1227 1870 2300 1879 1277 93 -597 -589 -188 369 516 683 670 1162 935 387 -13 -1206 -1163 -242 -371 -292 -655 -844 -825 -469 -107 -89 628 955 630 269 -314 -601 -372 900000 -1386 -271 -1336 -2345 -957 -2055 -1620 -1775 -2614 -1216 -1537 -1348 -1039 -667 48 -1022 -1233 -358 -427 -35 -1522 -448 -548 -614 -236 -365 64 -1055 -719 -1339 -101 -496 -739 -1188 -966 -1301 -1273 -243 256 681 514 746 581 277 89 1003 391 -104 384 441 1148 534 955 1558 1422 1147 1148 698 350 479 881 1006 1657 2001 1031 -184 -323 -204 859 1438 1207 793 645 114 -997 -2074 -2392 -2454 -1716 -1593 -1367 -1430 -2417 -1103 -55 536 1337 1878 1180 858 35 -1128 -2102 -1780 -2168 -836 285 766 -135 -941 -1919 -2898 -2187 -1088 -1635 -679 -401 451 1743 2799 3570 3029 2037 143 -910 -868 -282 555 824 1081 1096 1829 1432 599 -19 -1752 -1647 -360 -593 -497 -1163 -1524 -1558 -901 -212 -185 1320 1971 1295 551 -635 -1159 -705 SS 20240727T122203.5Z 8974.515318 224 1 53.98 2 77.49 75.08 24.12 223.89 0.00 1 0.00 1 0 25 1.801e-01 1.250e-02 1.062e-02 7.488e-04 5.287804e-01 3.826570e-04 6.089271e-03 -6.000000e+00 1.032094e-01 229.92 -2.00 3.24 -2.00 319.51 0.00e+00 1.597461e-03 1.105351e-04 2.842729e-03 -6.000000e+00 4.771473e-03 294.41 -2.00 20.00 -2.00 318.60 0.00e+00 4.486 0.001 302.00 328.00 3 5.6293e-01 1.1039e-03 5.2759e-02 -6.0000e+00 2.5666e-01 -4.0825e-04 1.3173e-03 3.0456e-02 -6.0000e+00 2.7813e-01 -3.8637e-02 1.0124e-03 1.3241e-02 -6.0000e+00 1.6656e-01 7.6183e-03 5.3116e-04 3.3427e-03 -6.0000e+00 7.0967e-02 2.0167e-03 -1.5326e-04 2.0557e-05 4.0541e-05 -6.0000e+00 4.8922e-03 -2.2596e-02 12 8 8 10 0 0 10.28 27.21 0.39 -0.02260 -0.02375 362 40 1 5 0 149.090 34.50 20.01 27.21 35.58 23.8 1014.84 900000 -59811 -33364 -61733 -70676 -60431 -66588 -66437 -57745 -68194 -48605 -52030 -45334 -28083 -18730 -9216 -14379 -14001 -4585 -3821 -2218 -13755 -7692 -6858 -5634 -4831 -3641 -3699 -12399 -9351 -11239 -1932 -2199 -4549 -7929 -8501 -8166 -7495 -1903 1324 2675 2792 3295 2840 1931 1589 3527 1491 891 542 921 3261 2053 2428 3230 2810 2609 1548 921 341 1175 1747 2765 3443 3714 1305 -516 -923 -744 974 1865 1721 1278 841 195 -1359 -2426 -3946 -4261 -2679 -2454 -1813 -1980 -2629 -1375 -361 442 1237 1540 1484 1108 214 -1209 -2319 -2043 -1725 -815 428 777 5 -672 -1584 -2381 -1965 -959 -1322 -572 -211 289 1203 1837 2193 1861 1298 145 -563 -518 -21 415 703 621 647 1045 881 258 160 -1061 -930 -305 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