File name: Pandora85s1_NewOrleansLA-XULA_20240728_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240729T061446.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240728_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240728T120136.9Z 8975.501122 221 1 54.23 2 81.86 72.96 12.56 177.31 0.00 1 0.00 1 0 25 6.705e-01 2.775e-02 2.327e-01 4.469e-03 7.319890e-01 2.505359e-03 8.046195e-03 -6.000000e+00 3.910480e-01 229.90 -2.00 3.24 -2.00 321.32 0.00e+00 -2.820864e-03 1.343342e-03 6.478212e-03 -6.000000e+00 2.164972e-02 294.42 -2.00 20.00 -2.00 320.64 0.00e+00 6.603 0.003 302.00 328.00 3 1.5851e+00 9.2951e-03 8.3391e-02 -6.0000e+00 9.7279e-01 3.2954e-01 1.2553e-02 6.0427e-02 -6.0000e+00 1.0595e+00 -5.2816e-01 1.1488e-02 1.8536e-02 -6.0000e+00 6.3391e-01 2.1263e-01 5.5071e-03 1.0206e-02 -6.0000e+00 2.7252e-01 7.8957e-05 -6.3406e-04 1.2504e-04 6.4896e-05 -6.0000e+00 1.8877e-02 -2.2492e-02 12 8 8 10 0 0 46.92 27.25 0.77 -0.02249 -0.02726 44 5 1 5 0 1232.300 34.50 20.01 27.25 35.06 23.8 1017.00 900000 900000 900000 -88201 -197758 900000 -185568 -17128 -125908 -203983 64685 900000 -67071 900000 900000 -123964 79121 -72503 900000 900000 900000 -115736 207823 900000 277803 900000 399111 900000 -18754 900000 -61247 900000 63771 -31986 -52083 19991 -9862 -33573 28183 63384 74932 30876 98806 59355 -8785 -24145 157312 27523 -23461 46624 21802 65839 8364 -5618 52300 36851 4798 23008 22737 4682 14022 21309 -1468 -15190 11727 23647 -11096 17287 11474 11594 22079 10848 -1046 1892 1068 -6106 -13254 -2580 -4897 9144 -1505 324 387 -6421 2794 6691 -2952 656 3587 -2107 3260 -2739 -1555 -4908 -2242 -10791 2442 -1697 -2474 -561 -2419 -2171 -316 -95 -1677 -1995 -92 -649 133 810 -1162 3956 3645 1518 -940 -969 -3100 -2753 -671 560 786 2238 3350 2043 696 353 -2067 -182 -153 -466 1099 -202 504 -82 -824 -69 -124 561 1308 1273 334 -1849 -926 -1105 900000 900000 900000 -732 -4453 900000 -3519 -74 -1691 -6689 281 900000 -742 900000 900000 -4554 438 -2005 900000 900000 900000 -5761 903 900000 1207 900000 1734 900000 -489 900000 -2715 900000 1136 -1682 -3395 599 -411 -2028 1114 2176 2703 1905 3263 2992 -874 -2801 3008 1962 -2895 3019 1980 4349 1094 -928 5273 4596 863 3529 3429 812 2175 3213 -310 -4205 2762 5066 -3293 3921 2932 3366 6630 3595 -401 683 362 -2000 -4204 -778 -1594 3004 -597 148 201 -3896 1647 4078 -2107 472 2557 -1444 2199 -1829 -974 -3147 -1501 -8292 1922 -1622 -2517 -599 -2584 -2328 -299 -83 -1548 -1995 -96 -720 147 989 -1641 5478 5341 2278 -1398 -1373 -4370 -3957 -997 870 1254 3447 4898 2935 979 480 -3009 -255 -215 -752 1846 -379 1003 -163 -1767 -158 -280 1283 3017 2908 731 -4125 -1928 -2257 SS 20240728T121631.7Z 8975.511478 226 1 54.01 2 78.75 74.67 12.79 193.22 0.00 1 0.00 1 0 25 2.651e-01 1.328e-02 3.353e-02 1.309e-03 5.747143e-01 6.743024e-04 6.815734e-03 -6.000000e+00 1.519697e-01 229.90 -2.00 3.24 -2.00 320.05 0.00e+00 1.200417e-03 2.375873e-04 4.177883e-03 -6.000000e+00 7.026073e-03 294.42 -2.00 20.00 -2.00 319.20 0.00e+00 4.947 0.001 302.00 328.00 3 1.1342e+00 2.0428e-03 5.9726e-02 -6.0000e+00 3.7789e-01 9.5161e-03 2.5175e-03 3.8373e-02 -6.0000e+00 4.0949e-01 -6.8446e-02 2.0993e-03 1.4646e-02 -6.0000e+00 2.4524e-01 1.9041e-02 1.0842e-03 4.4596e-03 -6.0000e+00 1.0451e-01 7.0915e-04 -6.2778e-05 3.5774e-05 5.2308e-05 -6.0000e+00 7.2023e-03 -2.3675e-02 12 8 8 10 0 0 26.94 27.35 0.52 -0.02368 -0.02415 173 19 1 5 0 312.140 34.50 20.01 27.35 36.33 23.8 1017.18 900000 -78014 27633 -83229 -112255 -74662 -116153 -100964 -98729 -106283 -60437 -64826 -55657 -13216 -34108 29434 -32250 -29766 -10774 -2446 2925 -35456 -13386 -4868 -8014 1912 -7030 11842 -18982 -7986 -18000 5907 -4849 -9389 -16703 -8983 -10803 -11970 -2276 1536 4429 3515 6237 3606 1475 -1862 6478 2779 -2582 -243 1169 4546 2303 2103 5231 4677 1783 3136 1486 -277 1649 2876 2239 2209 4303 2291 -1144 165 -418 2351 3645 2363 1752 863 300 -1808 -3718 -4266 -4104 -2026 -2667 -1989 -1514 -2938 -1320 143 119 1124 1836 1114 1343 139 -1261 -2395 -2209 -2492 -539 327 505 93 -705 -1839 -2302 -1827 -1178 -1312 -421 -91 316 1202 1668 2466 2017 1403 71 -822 -613 -356 175 577 643 819 1065 1004 360 62 -1431 -1009 -321 -512 -163 -629 -699 -920 -568 -25 -37 682 935 579 299 -236 -633 -382 900000 -996 138 -1297 -2179 -934 -2299 -1934 -2131 -2782 -1065 -1266 -1173 -230 -915 511 -1198 -1193 -392 -88 105 -1888 -583 -211 -393 91 -386 537 -1122 -424 -1181 361 -385 -882 -1719 -817 -1044 -1345 -282 225 674 594 1092 676 287 -381 1245 564 -570 -55 281 1181 677 676 1617 1529 625 1110 529 -98 573 1044 913 1019 1971 1081 -538 83 -203 1254 2199 1455 1118 543 178 -1075 -2035 -2231 -2215 -1222 -1771 -1516 -1209 -2566 -1129 130 115 1128 1763 1136 1301 127 -1091 -2165 -1957 -2495 -574 374 619 121 -903 -2215 -2663 -2096 -1322 -1594 -534 -115 428 1681 2458 3927 3187 2195 112 -1236 -889 -525 271 904 1044 1314 1650 1584 550 91 -2157 -1476 -471 -808 -272 -1142 -1285 -1774 -1113 -51 -77 1456 1955 1206 621 -468 -1246 -738 SS 20240728T122223.7Z 8975.515552 229 1 54.01 2 77.53 75.33 13.12 199.16 0.00 1 0.00 1 0 25 1.858e-01 1.247e-02 1.469e-02 9.376e-04 5.293190e-01 4.809169e-04 6.130322e-03 -6.000000e+00 1.064988e-01 229.90 -2.00 3.24 -2.00 319.60 0.00e+00 1.397938e-03 1.439587e-04 3.010367e-03 -6.000000e+00 4.923677e-03 294.42 -2.00 20.00 -2.00 318.70 0.00e+00 4.497 0.001 302.00 328.00 3 9.9661e-01 1.3995e-03 5.3132e-02 -6.0000e+00 2.6482e-01 -9.6468e-03 1.6762e-03 3.1333e-02 -6.0000e+00 2.8696e-01 -3.6638e-02 1.2994e-03 1.3247e-02 -6.0000e+00 1.7186e-01 5.6431e-03 6.8074e-04 3.4953e-03 -6.0000e+00 7.3243e-02 1.3027e-03 -2.4837e-04 2.5796e-05 4.1317e-05 -6.0000e+00 5.0470e-03 -2.4003e-02 12 8 8 10 0 0 29.58 27.42 0.45 -0.02400 -0.02587 244 27 1 5 0 221.330 34.50 20.01 27.42 36.89 23.8 1017.20 900000 -72694 -13044 -63478 -78147 -51449 -76117 -62942 -67727 -69821 -49355 -45074 -42943 -20614 -23048 -3503 -19991 -15909 -2324 -7096 309 -17725 -7682 -5648 -5693 -3013 -5416 -1349 -10788 -7632 -11390 536 -2814 -5965 -10212 -10308 -7849 -9451 -2827 2270 3013 1970 3711 3387 780 1220 4350 1570 37 345 1171 2925 1601 2246 3948 2712 2105 2275 785 17 332 2302 2432 2879 3876 1670 -568 -571 -716 1382 2256 1935 1229 925 349 -1346 -3052 -4117 -4306 -2694 -2337 -1790 -1691 -2651 -1327 -65 322 1117 1704 1421 1187 78 -948 -2308 -1811 -2030 -727 177 613 67 -623 -1561 -2372 -1964 -831 -1268 -529 -295 132 1210 1780 2181 2023 1317 63 -613 -563 -123 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