File name: Pandora85s1_NewOrleansLA-XULA_20240808_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240809T061215.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240808_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240808 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240808T122223.5Z 8986.515549 57 1 53.74 2 78.69 78.04 123.43 68.38 0.00 1 0.00 1 0 25 3.295e-01 1.669e-02 8.324e-02 2.519e-03 5.840218e-01 1.334649e-03 6.847456e-03 -6.000000e+00 1.896570e-01 229.69 -2.00 3.24 -2.00 320.40 0.00e+00 1.657129e-03 5.316699e-04 4.521845e-03 -6.000000e+00 9.583877e-03 294.57 -2.00 20.00 -2.00 319.59 0.00e+00 4.920 0.001 302.00 328.00 3 2.3912e+00 4.2252e-03 6.0472e-02 -6.0000e+00 4.7108e-01 -1.8894e-02 5.3645e-03 4.0373e-02 -6.0000e+00 5.1134e-01 -6.6263e-02 4.7766e-03 1.5149e-02 -6.0000e+00 3.0604e-01 1.9306e-02 2.4263e-03 4.6053e-03 -6.0000e+00 1.3134e-01 2.0854e-04 -2.3077e-04 7.0626e-05 5.6836e-05 -6.0000e+00 9.0380e-03 -2.1629e-02 12 8 8 10 0 0 52.56 27.25 0.78 -0.02163 -0.02336 59 7 1 5 0 910.750 34.50 20.00 27.25 34.99 21.3 1008.25 900000 -45150 900000 -89261 -94018 900000 -136329 -74852 -158864 -123037 -90934 900000 45413 900000 4214 900000 -46396 9880 92592 55645 900000 -38184 -25023 55054 -621 45338 87164 93555 -5722 31719 -22565 56992 -1685 -20073 -37780 -13506 -10817 -22672 -5646 3683 12131 13670 21345 -7185 -5824 -11196 22299 4893 -2675 11580 3276 10014 2139 -4774 10627 8472 -908 1490 2625 3205 -1284 6540 -1898 -4017 2674 6323 -6182 4421 -248 3334 6868 5334 -2397 2335 463 -3300 -5987 -3395 -4519 -2140 -2339 -1286 -1601 -4203 235 2644 1198 894 2851 575 2641 -48 -1295 -3604 -1070 -3870 -591 168 -119 -388 129 -2004 -2017 -1883 -1522 -1578 -618 345 433 1257 1389 2852 2403 1217 -370 -606 -1033 -885 -487 -32 1117 791 1270 844 501 -32 -1898 -667 -859 -423 -329 -389 -476 -175 -707 2 -55 536 1001 522 297 -706 -397 -280 900000 -262 900000 -936 -1061 900000 -2309 -772 -4367 -2657 -1518 900000 245 900000 55 900000 -1423 192 864 806 900000 -1509 -884 946 -20 1013 1348 1355 -215 825 -1135 1539 -96 -1552 -3551 -951 -775 -2103 -536 392 1396 1708 2630 -1231 -1002 -2069 3016 803 -490 1924 641 2052 478 -1248 2580 2211 -271 445 766 908 -381 1906 -672 -1648 1129 2603 -2782 1785 -110 1476 3366 2880 -1439 1306 248 -1668 -2810 -1614 -2064 -1092 -1411 -820 -1156 -3361 191 2260 1028 807 2581 528 2264 -42 -1084 -2996 -911 -3552 -605 184 -138 -479 154 -2434 -2218 -1945 -1633 -1832 -749 411 555 1752 2025 4468 3699 1868 -550 -902 -1493 -1304 -755 -50 1775 1247 1928 1322 758 -47 -2720 -921 -1263 -658 -567 -690 -894 -325 -1408 5 -117 1152 2184 1138 620 -1413 -790 -548 SS 20240808T122827.8Z 8986.519766 60 1 54.16 2 77.40 78.75 122.25 69.43 0.00 1 0.00 1 0 17 2.089e-01 1.357e-02 5.406e-02 1.647e-03 5.332781e-01 8.503430e-04 6.300573e-03 -6.000000e+00 1.196479e-01 229.69 -2.00 3.24 -2.00 319.90 0.00e+00 1.888992e-03 2.839763e-04 3.552793e-03 -6.000000e+00 5.607721e-03 294.57 -2.00 20.00 -2.00 319.03 0.00e+00 4.454 0.001 302.00 328.00 3 2.1141e+00 2.5351e-03 5.3598e-02 -6.0000e+00 2.9734e-01 -4.1416e-02 3.0956e-03 3.3590e-02 -6.0000e+00 3.2228e-01 -2.7908e-02 2.5444e-03 1.3667e-02 -6.0000e+00 1.9317e-01 2.4084e-03 1.3251e-03 3.6296e-03 -6.0000e+00 8.2722e-02 4.4983e-04 -3.5818e-04 4.5650e-05 4.8372e-05 -6.0000e+00 5.6764e-03 -2.2137e-02 12 8 8 10 0 0 54.87 27.31 0.55 -0.02214 -0.02483 97 11 1 5 0 558.230 34.50 20.01 27.31 35.37 21.4 1008.31 900000 -56077 900000 -56500 -80187 84642 -86408 -36179 -100308 -102612 -42218 15286 -24551 10690 -14996 35426 -27830 9085 1618 11870 29459 -22858 -7866 18323 -6489 15128 9370 17135 -7951 -5600 -15059 10618 -3204 -9807 -21184 -14373 -11122 -12125 -4670 -145 2862 3638 6621 -2407 82 -2173 9528 2643 -1882 3663 -227 4616 1332 -1282 5586 3503 1035 1045 984 1404 -115 4369 1054 438 2846 3293 -2786 1041 -341 1571 3323 3015 -420 1293 -19 -1849 -3499 -3765 -5131 -1744 -2073 -1329 -1765 -3117 -563 1009 376 1211 2518 1553 1908 128 -1088 -2614 -1600 -2565 -761 689 452 134 -526 -1876 -2511 -1899 -1531 -1485 -697 -189 89 1444 1664 2514 2230 1388 216 -655 -583 -282 -282 317 925 591 882 683 541 7 -1406 -904 -674 -381 -346 -696 -777 -643 -462 -36 -382 841 879 512 384 -334 -446 -257 900000 -729 900000 -853 -1429 272 -1595 -453 -2738 -3213 -766 164 -461 177 -400 694 -1180 293 62 436 955 -1270 -383 738 -366 736 507 856 -489 -336 -1103 706 -283 -1044 -2568 -1551 -1211 -1528 -660 -24 491 680 1277 -530 18 -494 1968 593 -453 867 -60 1294 426 -419 1839 1235 389 401 374 520 -43 1670 464 219 1399 1620 -1395 537 -171 870 2070 1898 -282 836 -13 -1140 -1980 -2021 -2866 -1067 -1387 -1017 -1423 -2741 -512 913 365 1222 2569 1589 1853 117 -1007 -2362 -1489 -2532 -796 814 570 169 -691 -2325 -3009 -2134 -1790 -1773 -869 -249 118 2064 2493 3855 3535 2177 326 -981 -843 -414 -436 496 1494 952 1375 1037 829 10 -2026 -1326 -989 -594 -568 -1238 -1392 -1200 -874 -73 -777 1732 1846 1074 775 -672 -857 -485 SS 20240808T123348.2Z 8986.523475 63 1 53.82 2 76.26 79.36 121.22 70.34 0.00 1 0.00 1 0 17 1.528e-01 1.240e-02 2.650e-02 1.256e-03 4.965364e-01 6.420280e-04 5.725636e-03 -6.000000e+00 8.747844e-02 229.69 -2.00 3.24 -2.00 319.49 0.00e+00 1.893152e-03 1.866762e-04 2.591281e-03 -6.000000e+00 4.050390e-03 294.57 -2.00 20.00 -2.00 318.58 0.00e+00 4.111 0.001 302.00 328.00 3 1.9705e+00 1.8585e-03 4.8603e-02 -6.0000e+00 2.1740e-01 -4.4853e-02 2.2158e-03 2.8219e-02 -6.0000e+00 2.3562e-01 -1.9883e-02 1.6879e-03 1.2495e-02 -6.0000e+00 1.4115e-01 -5.6112e-04 8.8670e-04 3.1070e-03 -6.0000e+00 6.0180e-02 7.4597e-04 -3.2379e-04 3.4856e-05 4.1026e-05 -6.0000e+00 4.1497e-03 -2.2660e-02 12 8 8 10 0 0 37.57 27.35 0.51 -0.02266 -0.02509 133 15 1 5 0 404.590 34.50 20.00 27.35 35.70 21.4 1008.37 900000 -38857 87376 -51253 -47499 1049 -57362 -43528 -59544 -66007 -35204 -347 -26533 -9199 -15808 12786 -23126 -5470 1428 918 12541 -11293 -6389 -374 -2225 -427 7401 5353 -9580 -7907 -12677 6257 -3245 -4168 -13241 -11506 -9298 -10330 -4326 860 1630 3393 5067 -916 350 -146 5746 1868 -422 1118 455 2859 691 16 3507 2772 1082 837 327 546 387 2189 1907 2099 2736 2457 -1153 4 -672 1371 2312 2084 359 1510 -70 -1434 -2802 -3928 -4510 -2331 -2513 -1666 -1593 -2829 -1061 495 656 1206 2239 1637 1524 360 -955 -2546 -1377 -2198 -548 304 609 244 -497 -1560 -2393 -2058 -1368 -1405 -730 -387 143 1249 1678 2335 2060 1320 225 -766 -544 -282 201 293 659 525 909 863 284 138 -1323 -899 -393 -230 -267 -459 -810 -627 -506 -68 16 620 816 376 169 -168 -456 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