File name: Pandora85s1_NewOrleansLA-XULA_20240810_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240811T061222.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240810_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T120913.8Z 8988.506409 51 1 53.91 2 81.69 77.06 147.40 61.32 0.00 1 0.00 1 0 25 6.606e-01 4.404e-02 2.393e-01 6.949e-03 7.460880e-01 3.996041e-03 9.039891e-03 -6.000000e+00 3.957622e-01 229.65 -2.00 3.24 -2.00 321.50 0.00e+00 6.268381e-03 2.235065e-03 9.264140e-03 -6.000000e+00 2.524491e-02 294.59 -2.00 20.00 -2.00 320.84 0.00e+00 6.486 0.003 302.00 328.00 3 2.2599e+00 1.5313e-02 8.7621e-02 -6.0000e+00 9.8189e-01 7.6332e-01 1.9730e-02 6.7399e-02 -6.0000e+00 1.0715e+00 -1.0744e+00 1.6332e-02 2.1062e-02 -6.0000e+00 6.4316e-01 4.3944e-01 8.0027e-03 7.0022e-03 -6.0000e+00 2.7881e-01 3.8490e-05 -1.3884e-03 1.9797e-04 1.4045e-04 -6.0000e+00 1.8977e-02 -2.3076e-02 12 8 8 10 0 0 -32.58 27.02 1.10 -0.02308 -0.03351 24 3 1 5 0 2246.010 34.25 20.01 27.02 32.96 21.1 1016.06 900000 900000 900000 900000 -120871 900000 -13102 900000 -136554 -11978 97095 900000 900000 900000 112202 900000 2013 900000 900000 900000 900000 67773 270919 900000 91741 900000 900000 900000 195037 900000 -49747 900000 85127 13698 -80589 100661 3377 -6882 92153 129138 244181 267955 900000 27652 57791 -13518 900000 70221 28355 232479 91706 141964 28267 -14186 106592 76222 15794 24730 43910 20040 29217 96880 5313 -20677 1867 49041 -5746 63221 19701 23039 42270 44408 -17232 16449 -1395 -4979 -14424 3561 -8551 23816 2042 -4537 3606 -13856 6033 15426 -2253 1561 8628 -7126 6502 -3963 -4654 -9796 7308 -14062 1759 -426 -2212 -2050 696 -5694 -3129 1203 -6880 -5082 -412 -314 1106 -1121 -2387 4808 5421 2589 -1594 903 -2981 -3889 -3968 -2133 3207 4343 5096 2833 1810 607 -4989 1499 -2042 1532 272 1160 649 3087 -1003 4 -1615 -27 1420 661 607 -3060 -875 -421 900000 900000 900000 900000 -6672 900000 -201 900000 -7621 -198 655 900000 900000 900000 963 900000 70 900000 900000 900000 900000 1330 1828 900000 1407 900000 900000 900000 1316 900000 -3143 900000 2125 776 -10577 2173 191 -474 2736 3136 2142 1989 900000 2407 3704 -1760 900000 4027 2544 2823 4888 5076 3452 -2852 6832 6839 2643 3787 5362 2961 3863 6797 1036 -5956 478 8007 -1578 8744 4413 5596 9639 10666 -7092 5116 -478 -1582 -4515 891 -2544 5961 761 -1917 1599 -7937 2997 7455 -1377 956 5022 -4807 3645 -2295 -2566 -5605 3769 -10341 1298 -376 -2095 -2084 678 -5497 -2879 977 -6216 -4862 -397 -322 1117 -1292 -3171 6634 7869 3585 -2232 1274 -4255 -5735 -5704 -3194 4687 6653 7430 4089 2548 834 -7020 1940 -2943 2259 460 2151 1204 5915 -2139 8 -3627 -61 3196 1589 1386 -6765 -1774 -827 SS 20240810T122321.8Z 8988.516225 56 1 53.88 2 78.69 78.71 144.80 65.07 0.00 1 0.00 1 0 17 2.846e-01 1.459e-02 5.897e-02 1.927e-03 5.741098e-01 1.006337e-03 6.836466e-03 -6.000000e+00 1.635938e-01 229.65 -2.00 3.24 -2.00 320.29 0.00e+00 1.209590e-03 3.824380e-04 4.603563e-03 -6.000000e+00 7.809815e-03 294.59 -2.00 20.00 -2.00 319.46 0.00e+00 4.922 0.001 302.00 328.00 3 1.9139e+00 3.1441e-03 6.0531e-02 -6.0000e+00 4.0600e-01 -3.2000e-02 3.9646e-03 4.1337e-02 -6.0000e+00 4.4007e-01 -5.6194e-02 3.4270e-03 1.5016e-02 -6.0000e+00 2.6337e-01 1.5557e-02 1.7423e-03 4.8655e-03 -6.0000e+00 1.1277e-01 3.4204e-04 -3.4057e-04 5.3560e-05 5.8191e-05 -6.0000e+00 7.7452e-03 -2.4369e-02 12 8 8 10 0 0 25.92 27.09 0.64 -0.02437 -0.02693 95 11 1 5 0 567.140 34.25 20.00 27.09 33.74 21.2 1016.25 900000 -28840 900000 -62758 -142462 900000 -131137 -61421 -130016 -112307 -83264 9180 -45981 2027 -34727 111292 -30674 4617 -3747 9655 37503 -23594 -12480 14133 -6599 17845 16000 31801 -17876 -279 -35169 31976 -6609 -11218 -28419 -15120 -10711 -19231 -1190 884 5186 8602 14271 -3228 -338 -4828 9999 4046 -4106 5083 2850 6764 -1288 -2737 9502 5728 880 1737 1825 -12 516 5908 -904 -116 1902 4600 -2398 2946 4 2838 4582 3507 -1159 1278 -277 -2027 -3917 -4319 -5324 -1643 -2029 -2330 -1535 -3605 -607 1600 730 1585 1914 1514 1453 196 -1569 -2571 -1680 -2507 -928 453 491 284 -485 -2159 -2186 -2427 -1198 -1533 -902 -49 362 1218 1662 2424 2524 1376 -76 -286 -769 -653 -429 -127 923 892 1334 1155 575 -160 -2078 -1161 -557 -188 -287 -558 -695 -591 -587 -171 -237 559 958 624 199 -258 -415 -181 900000 -179 900000 -636 -2997 900000 -2414 -634 -3077 -2510 -1486 69 -708 24 -757 690 -910 107 -103 250 775 -913 -441 414 -262 597 574 974 -863 -11 -2259 1243 -441 -889 -2733 -1215 -859 -1929 -121 108 718 1270 2120 -543 -56 -854 1715 682 -775 914 566 1447 -331 -779 2594 1711 288 577 599 -4 168 1929 -352 -46 824 1962 -1057 1226 2 1392 2535 1968 -703 740 -154 -1126 -2004 -2107 -2708 -918 -1239 -1651 -1131 -2930 -509 1413 648 1461 1803 1422 1302 177 -1353 -2167 -1468 -2322 -974 506 584 360 -605 -2548 -2485 -2598 -1319 -1833 -1063 -61 479 1655 2498 3736 4027 2190 -117 -416 -1145 -991 -649 -203 1524 1459 2104 1773 854 -243 -3095 -1669 -843 -301 -486 -980 -1291 -1148 -1157 -343 -501 1196 2085 1355 417 -537 -824 -352 SS 20240810T122919.1Z 8988.520360 59 1 54.08 2 77.43 79.41 143.69 66.52 0.00 1 0.00 1 0 17 2.225e-01 1.297e-02 5.642e-02 1.321e-03 5.280038e-01 6.765711e-04 6.235367e-03 -6.000000e+00 1.274493e-01 229.65 -2.00 3.24 -2.00 319.78 0.00e+00 1.930373e-03 2.172388e-04 3.442995e-03 -6.000000e+00 5.901764e-03 294.59 -2.00 20.00 -2.00 318.90 0.00e+00 4.464 0.001 302.00 328.00 3 1.6959e+00 2.0003e-03 5.3373e-02 -6.0000e+00 3.1671e-01 -3.9263e-02 2.4251e-03 3.2941e-02 -6.0000e+00 3.4322e-01 -3.1732e-02 1.9519e-03 1.3508e-02 -6.0000e+00 2.0562e-01 4.9496e-03 1.0189e-03 3.5314e-03 -6.0000e+00 8.7704e-02 6.8180e-04 -4.4533e-04 3.6488e-05 4.6996e-05 -6.0000e+00 6.0444e-03 -2.4632e-02 12 8 8 10 0 0 25.31 27.14 0.49 -0.02463 -0.02798 147 16 1 5 0 367.850 34.50 20.00 27.14 34.04 21.1 1016.33 900000 -67657 144807 -35897 -91524 1663 -80649 -49765 -81365 -82919 -59929 -25317 -45228 -3481 -17302 3565 -27293 -5955 1125 -38 6415 -15736 -4430 -1435 -7480 -3079 8709 13864 -9707 -5210 -17274 6464 -3158 -5213 -16825 -15106 -9395 -12254 -2023 905 3396 3104 6761 -569 1360 -1149 6439 674 128 1742 1249 3668 448 69 3962 3170 1011 1694 455 603 466 3234 1265 2103 3433 2779 -575 82 -609 1204 2845 2576 341 1516 -521 -1435 -3173 -3542 -4954 -2588 -2627 -2136 -1617 -2701 -887 421 691 1404 2032 1639 1401 181 -1149 -2162 -1908 -2289 -830 379 572 164 -366 -1819 -2549 -2179 -1313 -1536 -541 -92 273 1111 1751 2366 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