File name: Pandora85s1_NewOrleansLA-XULA_20240811_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240812T061250.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240811_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240811T121002.6Z 8989.506974 55 1 55.31 2 81.62 77.44 157.88 56.23 0.00 1 0.00 1 0 25 6.249e-01 6.366e-02 1.676e-01 9.869e-03 7.619323e-01 5.742709e-03 9.023723e-03 -6.000000e+00 3.748006e-01 229.63 -2.00 3.24 -2.00 321.48 0.00e+00 1.990060e-02 3.048813e-03 3.223521e-03 -6.000000e+00 2.473573e-02 294.61 -2.00 20.00 -2.00 320.80 0.00e+00 6.443 0.003 302.00 328.00 3 2.5892e+00 2.1236e-02 7.3643e-02 -6.0000e+00 9.2595e-01 1.2571e+00 2.6132e-02 3.8203e-02 -6.0000e+00 1.0118e+00 -1.4320e+00 1.8457e-02 2.1194e-02 -6.0000e+00 6.0405e-01 5.3441e-01 9.3918e-03 1.6893e-02 -6.0000e+00 2.6367e-01 2.2321e-05 -1.7809e-03 2.8101e-04 2.2716e-04 -6.0000e+00 1.8013e-02 -1.9021e-02 12 8 8 10 0 0 43.94 27.02 1.26 -0.01902 -0.03240 15 2 1 5 0 3687.040 34.25 20.01 27.02 33.05 21.1 1016.67 900000 900000 900000 900000 -30373 900000 -30162 900000 -85024 2449 15636 900000 900000 900000 35411 900000 113464 82865 900000 900000 900000 66122 900000 900000 72516 900000 900000 900000 343154 900000 -11932 900000 900000 63050 -64321 86285 92568 4403 94022 144785 254638 900000 900000 82227 37398 887 900000 123106 32157 900000 95187 900000 35180 -25532 167498 113105 12085 37319 89472 34515 27479 139480 528 -30916 2064 114878 -317 102266 42093 46891 78199 83578 -30931 10825 12388 -4419 -20891 13470 -11869 50856 9727 -1304 4708 -17423 17459 29025 -797 -822 13950 -8248 16999 -672 1356 -10392 10162 -17980 -329 -975 -2604 -1035 5263 -8038 -4118 249 -2559 -6442 -1387 -2851 1111 -1299 -3691 6944 6503 1326 -3291 2673 -5206 -4700 -7535 -5963 6444 6531 7310 3797 3059 1227 -8830 1637 -2526 976 1649 1205 2989 6047 -3181 915 -1747 -191 869 1232 2685 -5010 -3499 898 900000 900000 900000 900000 -2352 900000 -1680 900000 -7102 81 422 900000 900000 900000 1510 900000 3061 3245 900000 900000 900000 2819 900000 900000 2335 900000 900000 900000 3284 900000 -862 900000 900000 3347 -11865 3469 3367 409 3960 4157 2681 900000 900000 5352 3830 132 900000 5538 3693 900000 6378 900000 5051 -7111 7054 8228 2383 5572 7536 4790 4050 7076 120 -11008 587 10776 -91 10474 8138 9560 13098 14079 -14937 3595 3688 -1379 -6858 3004 -3613 9687 3352 -584 2244 -10127 8255 12946 -458 -489 7998 -5296 8851 -387 719 -6088 5184 -12767 -232 -811 -2538 -1066 5001 -8065 -3533 187 -2015 -5661 -1221 -2719 1110 -1489 -4936 9318 8491 1827 -4599 3354 -6888 -6350 -11064 -9137 8948 8834 10229 5313 4155 1635 -12585 2063 -3582 1413 2698 2189 5720 11875 -6747 1996 -4084 -446 2040 2847 5794 -10889 -7012 1811 SS 20240811T122353.5Z 8989.516591 60 1 54.36 2 78.69 79.06 155.46 61.43 0.00 1 0.00 1 0 17 3.032e-01 1.602e-02 9.570e-02 2.311e-03 5.776037e-01 1.210481e-03 6.812517e-03 -6.000000e+00 1.744076e-01 229.63 -2.00 3.24 -2.00 320.37 0.00e+00 1.761029e-03 4.760104e-04 4.581556e-03 -6.000000e+00 8.678609e-03 294.61 -2.00 20.00 -2.00 319.55 0.00e+00 4.920 0.001 302.00 328.00 3 2.2480e+00 3.8227e-03 6.0419e-02 -6.0000e+00 4.3294e-01 -2.4486e-02 4.8268e-03 4.0464e-02 -6.0000e+00 4.6966e-01 -7.5625e-02 4.2240e-03 1.4998e-02 -6.0000e+00 2.8115e-01 2.2801e-02 2.1471e-03 4.5919e-03 -6.0000e+00 1.2057e-01 2.4503e-04 -2.4304e-04 6.4614e-05 6.0985e-05 -6.0000e+00 8.2961e-03 -1.9878e-02 12 8 8 10 0 0 28.09 27.07 0.73 -0.01988 -0.02170 73 8 1 5 0 744.570 34.25 20.01 27.07 33.71 21.3 1016.76 900000 21101 900000 -55939 -147430 900000 -153507 38417 -136764 -113251 -68735 900000 -33837 47394 -13577 900000 -58413 -26489 11655 62203 86053 -26157 -1888 13838 -22946 42230 16324 75617 -783 14787 -28762 17409 -10431 -9462 -43863 -13393 -15423 -29138 -5344 5369 10296 16083 12981 -2797 293 -3908 16988 5955 -2285 9596 3897 12571 868 -4613 9204 6247 1477 1913 615 179 2547 7642 -2008 -3062 2860 5489 -4374 4037 -206 2832 6478 4502 -2720 920 -1059 -1461 -4985 -2412 -5388 47 -2296 -2053 -1723 -3540 -591 1063 442 1310 2144 674 1992 259 -1207 -3219 -441 -3438 -692 457 -130 -86 -87 -2198 -1958 -1662 -1168 -1809 -230 -334 782 1002 1527 2476 2613 1453 -346 -909 -1012 -360 -318 -33 1024 938 1360 1081 306 33 -2050 -1117 -871 -223 -324 -196 -768 -281 -708 36 -232 628 932 693 368 -566 -739 -84 900000 76 900000 -504 -2807 900000 -3353 138 -3264 -2397 -991 900000 -434 341 -226 900000 -2157 -787 260 896 1027 -972 -56 380 -997 1027 540 1379 -29 479 -1619 733 -676 -688 -4573 -983 -1209 -3012 -528 586 1257 2039 1806 -476 49 -697 2513 1003 -432 1683 784 2596 203 -1243 2336 1717 443 585 188 54 750 2270 -734 -1282 1240 2339 -1818 1678 -94 1293 3267 2511 -1678 534 -590 -742 -2373 -1066 -2545 24 -1419 -1351 -1275 -2876 -495 877 391 1205 2001 633 1758 216 -1033 -2728 -382 -3216 -677 509 -154 -109 -107 -2560 -2197 -1753 -1280 -2158 -267 -412 1024 1351 2279 3766 4107 2275 -526 -1386 -1496 -541 -476 -52 1669 1513 2116 1637 475 50 -3022 -1593 -1318 -357 -545 -357 -1410 -538 -1378 75 -481 1322 1996 1478 790 -1161 -1446 -169 SS 20240811T122951.9Z 8989.520740 63 1 54.00 2 77.42 79.76 154.37 63.42 0.00 1 0.00 1 0 25 2.260e-01 1.332e-02 7.413e-02 1.653e-03 5.288622e-01 8.475470e-04 6.229929e-03 -6.000000e+00 1.293691e-01 229.63 -2.00 3.24 -2.00 319.91 0.00e+00 1.433041e-03 2.844381e-04 3.549881e-03 -6.000000e+00 5.993003e-03 294.61 -2.00 20.00 -2.00 319.03 0.00e+00 4.460 0.001 302.00 328.00 3 2.1176e+00 2.5300e-03 5.3611e-02 -6.0000e+00 3.2146e-01 -5.1025e-02 3.0903e-03 3.3738e-02 -6.0000e+00 3.4845e-01 -3.2740e-02 2.5241e-03 1.3426e-02 -6.0000e+00 2.0876e-01 4.4109e-03 1.3126e-03 3.7905e-03 -6.0000e+00 8.8989e-02 4.5386e-04 -1.6515e-04 4.5910e-05 4.6936e-05 -6.0000e+00 6.1407e-03 -2.0641e-02 12 8 8 10 0 0 -1.97 27.11 0.51 -0.02064 -0.02188 102 11 1 5 0 529.320 34.50 20.01 27.11 34.04 21.2 1016.88 900000 -14219 75610 -64165 -93011 115762 -81100 -22416 -96018 -85184 -67523 -15528 -21552 -24910 -25148 53347 -29194 -23711 2035 12572 15827 -17422 -1986 -1109 -4437 6351 4549 11892 -8915 -1581 -21525 5688 -6094 -7231 -21068 -11473 -10676 -14160 -4389 1074 4153 6173 9780 -1097 1200 -2583 6310 2789 -368 4359 -218 6343 -68 -464 5251 3570 1194 298 476 327 1297 3651 1846 281 3302 3535 -1490 460 -303 1046 3167 3115 -204 909 114 -1664 -3572 -2737 -5220 -1847 -2335 -1950 -2198 -3463 -579 765 778 1378 2147 1137 1556 477 -1699 -2321 -1617 -2088 -740 402 599 -22 -215 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