File name: Pandora85s1_NewOrleansLA-XULA_20240812_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240813T061217.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240812_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240812T121032.1Z 8990.507316 51 1 53.04 2 81.63 77.78 168.07 41.85 0.00 1 0.00 1 0 25 6.494e-01 5.935e-02 1.916e-01 9.275e-03 7.562748e-01 5.511764e-03 8.053507e-03 -6.000000e+00 3.917189e-01 229.62 -2.00 3.24 -2.00 321.54 0.00e+00 1.020093e-02 2.999812e-03 4.035924e-04 -6.000000e+00 2.690182e-02 294.62 -2.00 20.00 -2.00 320.87 0.00e+00 6.447 0.003 302.00 328.00 3 2.5931e+00 2.0741e-02 7.4406e-02 -6.0000e+00 9.6811e-01 1.0793e+00 2.6360e-02 4.1486e-02 -6.0000e+00 1.0582e+00 -1.3292e+00 2.0285e-02 1.9283e-02 -6.0000e+00 6.3557e-01 5.0859e-01 9.9971e-03 1.4373e-02 -6.0000e+00 2.7747e-01 2.4700e-05 -1.6765e-03 2.7098e-04 1.5218e-04 -6.0000e+00 1.9482e-02 -1.9912e-02 12 8 8 10 0 0 7.39 27.31 1.32 -0.01991 -0.03251 16 2 1 5 0 3314.740 34.50 20.01 27.31 34.96 21.8 1016.00 900000 900000 900000 900000 -46904 900000 13088 900000 -95137 26866 26779 900000 900000 900000 900000 900000 74282 900000 900000 900000 900000 33605 900000 172442 128650 900000 900000 900000 900000 900000 -19911 900000 343745 158563 -47960 110388 43837 -4995 112956 900000 230891 900000 900000 62853 32029 -28726 900000 127851 42837 900000 113416 900000 37856 -9503 162211 106308 27048 48588 77372 38771 40157 198379 5564 -39453 -4642 124844 -15345 48808 36806 41718 78563 62257 -29896 22156 18365 -3866 -26523 23927 -18254 28061 6105 4318 -3919 -20637 21739 24732 -37 3417 9282 -7164 9640 2443 1748 -9682 1440 -22010 5056 2769 -1004 -1791 3421 -8845 550 2941 167 -5692 -477 1772 791 -1379 -1799 7206 6542 2729 -4148 1164 -4010 -5376 -6552 -4907 5041 4463 7232 2046 2766 723 -8056 -570 -2855 177 1874 2316 2391 4057 -2530 974 -1354 -592 1065 1700 2159 -4045 -2112 -82 900000 900000 900000 900000 -2914 900000 342 900000 -7154 593 569 900000 900000 900000 900000 900000 2307 900000 900000 900000 900000 1566 900000 1832 2103 900000 900000 900000 900000 900000 -1351 900000 3091 2994 -6350 2977 2247 -449 3554 900000 2906 900000 900000 4690 3225 -4790 900000 4943 3967 900000 5710 900000 4833 -2076 6709 7838 4426 6334 7235 5054 5055 5351 1146 -13157 -1331 9990 -4829 8074 7148 8589 12644 12594 -13953 6454 5086 -1189 -9133 4754 -5826 6560 2124 1782 -1810 -12161 9714 11407 -21 1941 5053 -4538 5391 1362 926 -5144 805 -16299 3359 2205 -954 -1841 3282 -8892 450 2156 129 -5011 -420 1628 798 -1591 -2174 8882 8588 3736 -5895 1496 -5285 -7358 -9577 -7481 7149 6219 9385 2705 3503 901 -10611 -746 -3777 262 3093 4205 4294 7587 -5398 2152 -3200 -1414 2536 3976 4767 -8869 -4257 -157 SS 20240812T122422.9Z 8990.516932 56 1 53.67 2 78.69 79.41 166.00 52.13 0.00 1 0.00 1 0 17 4.149e-01 1.673e-02 1.074e-01 2.200e-03 5.704941e-01 1.144483e-03 6.937308e-03 -6.000000e+00 2.375610e-01 229.62 -2.00 3.24 -2.00 320.33 0.00e+00 2.214941e-03 4.411611e-04 4.905785e-03 -6.000000e+00 1.113861e-02 294.62 -2.00 20.00 -2.00 319.50 0.00e+00 4.921 0.001 302.00 328.00 3 2.1472e+00 3.5908e-03 6.0801e-02 -6.0000e+00 5.9026e-01 -1.3098e-02 4.5161e-03 4.1855e-02 -6.0000e+00 6.3974e-01 -9.9956e-02 3.8526e-03 1.5281e-02 -6.0000e+00 3.8350e-01 3.4893e-02 1.9605e-03 4.5577e-03 -6.0000e+00 1.6429e-01 2.7312e-04 -2.5185e-04 6.0796e-05 6.1721e-05 -6.0000e+00 1.1271e-02 -2.3123e-02 12 8 8 10 0 0 -9.80 27.40 0.55 -0.02312 -0.02502 79 9 1 5 0 679.290 34.50 20.01 27.40 35.81 21.9 1016.02 900000 -48913 900000 -102523 -150738 320411 -157996 -65637 -129418 -121587 -71533 34256 2613 49826 -37319 95433 -29517 -10116 12857 27773 18540 -35970 10434 -6880 -14114 18227 50497 43740 -6002 9363 -28040 19177 -4416 -10634 -29321 -15632 -19222 -25555 -7554 2185 8794 12330 19869 -2902 -2415 -5810 15521 5315 1804 7846 5476 10420 1772 -3401 10265 6463 559 536 1218 2062 1429 7815 770 -2193 3173 5933 -3765 1748 1257 2739 6108 4549 -2480 2131 -684 -3425 -4908 -2394 -5727 -1967 -2626 -1739 -2130 -4069 -360 1367 635 899 2401 903 1717 363 -832 -3333 -1965 -3590 -773 559 -221 155 -396 -2202 -2271 -2305 -1419 -1687 -994 -100 860 1058 1735 2989 2677 1598 3 -840 -749 -1161 -473 112 827 819 1332 1076 612 -40 -1812 -1107 -659 -297 -247 -170 -657 -724 -425 -40 -74 426 906 742 310 -430 -790 -223 900000 -420 900000 -1737 -3848 687 -4202 -774 -3303 -3208 -1212 213 26 395 -889 737 -918 -286 317 631 485 -1643 304 -257 -618 618 1300 1201 -260 349 -1702 860 -292 -846 -2862 -1267 -1682 -2730 -815 262 1160 1727 2745 -526 -443 -1123 2477 957 347 1481 1039 2103 431 -950 2704 1858 177 174 388 636 445 2420 286 -949 1310 2409 -1621 773 535 1295 3199 2627 -1460 1269 -394 -1845 -2426 -1097 -2804 -1058 -1677 -1175 -1630 -3181 -288 1159 579 856 2306 875 1572 313 -681 -2707 -1648 -3451 -777 638 -270 199 -502 -2643 -2638 -2520 -1603 -1939 -1196 -127 1157 1465 2507 4648 4324 2571 5 -1243 -1071 -1702 -727 183 1315 1361 2135 1681 924 -58 -2746 -1624 -964 -487 -425 -301 -1235 -1359 -844 -81 -156 921 1988 1622 652 -906 -1590 -438 SS 20240812T123023.4Z 8990.521104 59 1 53.90 2 77.41 80.11 165.01 55.73 0.00 1 0.00 1 0 25 2.254e-01 1.352e-02 6.299e-02 1.566e-03 5.225488e-01 8.044423e-04 6.179004e-03 -6.000000e+00 1.290910e-01 229.62 -2.00 3.24 -2.00 319.88 0.00e+00 2.274814e-03 2.665906e-04 3.479510e-03 -6.000000e+00 5.979663e-03 294.62 -2.00 20.00 -2.00 319.01 0.00e+00 4.458 0.001 302.00 328.00 3 2.0290e+00 2.3982e-03 5.3193e-02 -6.0000e+00 3.2075e-01 -4.6975e-02 2.9174e-03 3.2613e-02 -6.0000e+00 3.4763e-01 -3.6902e-02 2.3573e-03 1.3512e-02 -6.0000e+00 2.0827e-01 6.0697e-03 1.2290e-03 3.4131e-03 -6.0000e+00 8.8833e-02 4.9912e-04 -2.7265e-04 4.3584e-05 5.0012e-05 -6.0000e+00 6.1238e-03 -2.3815e-02 12 8 8 10 0 0 13.46 27.46 0.43 -0.02381 -0.02586 114 13 1 5 0 472.740 34.50 20.01 27.46 36.12 21.9 1016.02 900000 -51377 63237 -59873 -101194 115546 -102001 -34387 -85607 -86774 -53483 -21657 -18862 -4981 -27010 29288 -26917 -8930 2556 7763 8327 -14623 -3391 -2084 -11089 9528 7193 17743 -6171 -5113 -13629 6285 -6168 -4898 -17853 -13214 -12512 -17070 -5274 1776 3080 5703 5777 -1265 -632 -2966 8720 1695 -776 2579 2141 5711 1697 -1706 4652 3727 1059 1792 514 420 1542 3791 1994 1025 3158 3848 -1567 -154 -490 1770 3638 2927 -151 1385 -48 -1087 -3324 -3876 -4944 -2379 -2767 -1863 -1825 -3274 -964 785 364 1249 2431 1661 1152 637 -888 -2517 -2008 -2702 -501 424 408 22 38 -2012 -2595 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