File name: Pandora85s1_NewOrleansLA-XULA_20240814_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240815T082752.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240814_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240814T122529.9Z 8992.517707 57 1 53.75 2 78.66 80.14 169.08 281.65 0.00 1 0.00 1 0 17 3.927e-01 1.813e-02 1.724e-01 2.747e-03 5.776190e-01 1.443776e-03 6.918757e-03 -6.000000e+00 2.263232e-01 229.58 -2.00 3.24 -2.00 320.45 0.00e+00 3.010160e-03 5.820200e-04 4.773733e-03 -6.000000e+00 1.109097e-02 294.65 -2.00 20.00 -2.00 319.64 0.00e+00 4.911 0.001 302.00 328.00 3 2.5394e+00 4.5918e-03 6.0432e-02 -6.0000e+00 5.6108e-01 9.3492e-03 5.8134e-03 4.0359e-02 -6.0000e+00 6.0844e-01 -1.0327e-01 5.1233e-03 1.5450e-02 -6.0000e+00 3.6445e-01 3.1184e-02 2.6042e-03 4.1365e-03 -6.0000e+00 1.5592e-01 1.8169e-04 -4.4308e-04 7.7324e-05 6.7489e-05 -6.0000e+00 1.0813e-02 -2.7465e-02 12 8 8 10 0 0 25.81 27.51 0.85 -0.02747 -0.03079 55 6 1 5 0 977.100 34.75 20.01 27.51 35.98 21.4 1016.36 900000 -39951 900000 -28107 -160773 900000 -157264 23706 -120388 -124919 -66098 116631 104430 168778 4869 900000 -58531 -16540 74710 118898 106108 -31220 8201 2110 -18032 68199 78981 900000 -5091 74061 -49395 29586 30 -30056 -40300 -12690 -12836 -27510 2924 10494 13638 20353 22829 -3613 -493 -8420 22401 10608 -554 12220 11709 2412 -1007 -6182 14414 9637 2122 783 2614 -1594 2327 8844 1094 -2984 1223 8669 -6530 3690 18 3616 8875 5138 -2493 2783 673 -1783 -5358 -3552 -6698 496 -3567 -1512 -1879 -4386 -184 -819 363 856 1995 486 2556 472 -1085 -3689 -877 -4805 93 849 325 -125 145 -1765 -2372 -2041 -1045 -2385 -502 -14 402 1189 1546 3028 2533 1600 -259 -787 -345 -1384 -600 -262 1158 854 1620 934 66 198 -2373 -723 -566 -43 -229 -533 -330 -206 -777 -137 -364 667 786 658 317 -258 -805 -11 900000 -253 900000 -185 -3717 900000 -3368 102 -2481 -3010 -938 312 335 452 68 900000 -2194 -452 900 987 1051 -1237 222 65 -739 1260 1374 900000 -198 1308 -3359 1085 2 -2655 -4035 -917 -962 -2725 258 1051 1555 2392 2787 -602 -81 -1528 3058 1661 -100 2028 2106 484 -231 -1631 3346 2465 608 232 754 -468 659 2482 370 -1192 516 3449 -2914 1477 8 1696 4153 2714 -1466 1520 353 -873 -2677 -1653 -3316 238 -2108 -1013 -1319 -3411 -146 -702 328 750 1771 435 2306 404 -884 -2980 -719 -4285 91 950 387 -159 180 -2085 -2553 -2198 -1156 -2700 -588 -18 531 1601 2309 4580 3999 2517 -397 -1140 -510 -2107 -899 -417 1891 1386 2527 1425 98 298 -3540 -1034 -854 -69 -382 -969 -599 -392 -1579 -281 -786 1461 1670 1394 678 -526 -1656 -22 SS 20240814T123130.8Z 8992.521884 60 1 53.98 2 77.38 80.84 170.29 283.83 0.00 1 0.00 1 0 25 2.204e-01 1.439e-02 5.837e-02 1.919e-03 5.255320e-01 9.890640e-04 6.174671e-03 -6.000000e+00 1.267087e-01 229.58 -2.00 3.24 -2.00 319.96 0.00e+00 2.285825e-03 3.388531e-04 3.453624e-03 -6.000000e+00 5.957747e-03 294.65 -2.00 20.00 -2.00 319.10 0.00e+00 4.448 0.001 302.00 328.00 3 2.4045e+00 2.9747e-03 5.3199e-02 -6.0000e+00 3.1445e-01 -4.5987e-02 3.6279e-03 3.2561e-02 -6.0000e+00 3.4075e-01 -3.7798e-02 2.9991e-03 1.3510e-02 -6.0000e+00 2.0389e-01 6.0119e-03 1.5635e-03 3.4535e-03 -6.0000e+00 8.6971e-02 3.4431e-04 -2.8048e-04 5.3919e-05 4.7567e-05 -6.0000e+00 6.0009e-03 -2.8658e-02 12 8 8 10 0 0 23.44 27.56 0.61 -0.02866 -0.03077 81 9 1 5 0 666.380 34.75 20.00 27.56 36.29 21.3 1016.39 900000 -3718 51980 -41260 -101468 900000 -108658 23932 -91315 -90602 -48852 16028 22867 18482 -14953 97072 -39259 -9028 6994 21405 27008 -23424 -2742 3333 -16666 17310 24631 27500 -5300 23262 -25863 11741 -5184 -10775 -20547 -14823 -12327 -18487 177 4646 4437 9558 8674 -3152 -2386 -4274 10969 4041 -766 2526 3214 7373 -174 -2063 6086 5570 916 -125 -623 -350 -401 4336 970 -386 2863 4571 -3112 227 -303 1679 4663 3647 -1461 1338 404 -1697 -3631 -3734 -4785 -1628 -2811 -1557 -1601 -3255 -594 1065 435 855 2456 1585 1831 499 -1350 -2720 -1290 -3126 -33 398 555 -73 -576 -1646 -2316 -1615 -612 -1636 -944 -400 184 1177 1625 2605 2211 1439 127 -823 -200 -1174 -380 162 941 803 1289 843 237 -251 -1446 -1118 -387 -262 -403 -517 -657 -628 -649 61 -36 574 854 764 255 -232 -632 -282 900000 -29 263 -548 -2298 900000 -2542 166 -2290 -2526 -951 171 265 280 -395 1017 -1851 -346 250 709 890 -1298 -125 153 -1020 807 1120 1215 -311 1023 -2052 749 -453 -1125 -2415 -1565 -1315 -2394 23 705 720 1621 1577 -675 -516 -958 2155 863 -176 581 786 1923 -54 -709 2078 2004 328 -46 -230 -126 -145 1582 407 -185 1453 2300 -1618 112 -157 878 2713 2330 -1015 887 255 -999 -1966 -2068 -2735 -939 -1925 -1127 -1304 -2713 -512 971 426 876 2379 1542 1809 463 -1192 -2337 -1130 -3118 -34 444 699 -93 -719 -2049 -2638 -1825 -713 -1963 -1186 -528 244 1684 2424 3966 3491 2248 191 -1234 -287 -1731 -586 252 1516 1288 2001 1344 366 -373 -2092 -1652 -565 -404 -689 -911 -1220 -1162 -1271 122 -76 1173 1775 1585 534 -465 -1212 -553 SS 20240814T123651.6Z 8992.525597 63 1 54.11 2 76.24 81.47 171.35 286.18 0.00 1 0.00 1 0 17 1.415e-01 1.288e-02 2.533e-02 1.387e-03 4.870102e-01 7.086219e-04 5.681419e-03 -6.000000e+00 8.109392e-02 229.58 -2.00 3.24 -2.00 319.50 0.00e+00 2.344024e-03 2.047948e-04 2.679020e-03 -6.000000e+00 3.755742e-03 294.65 -2.00 20.00 -2.00 318.59 0.00e+00 4.103 0.001 302.00 328.00 3 2.1913e+00 2.0493e-03 4.8368e-02 -6.0000e+00 2.0147e-01 -5.4310e-02 2.4364e-03 2.7923e-02 -6.0000e+00 2.1831e-01 -2.2681e-02 1.8658e-03 1.2355e-02 -6.0000e+00 1.3080e-01 1.9607e-04 9.8547e-04 3.0439e-03 -6.0000e+00 5.5839e-02 6.1473e-04 -4.1489e-04 3.8928e-05 4.1878e-05 -6.0000e+00 3.8446e-03 -2.8676e-02 12 8 8 10 0 0 52.94 27.61 0.54 -0.02868 -0.03179 117 13 1 5 0 462.440 34.75 20.01 27.61 36.56 21.3 1016.47 900000 -37359 -566 -53722 -70469 47821 -76317 -28536 -43238 -51276 -36861 -14926 -6663 -1054 -20071 10818 -19021 -7733 3633 4771 6864 -10303 -4904 -8189 -13402 582 8728 13036 -7119 2509 -14949 3934 -4066 -7679 -12704 -11864 -10783 -12141 -2629 702 1476 4225 5340 -1234 -775 -643 6111 1591 -346 1749 2180 3949 449 -12 3985 3452 1337 669 830 -370 -234 3058 1428 2255 2844 3335 -1952 11 -665 1752 3030 2613 504 1279 122 -1620 -3218 -3548 -4845 -2312 -2896 -1892 -1570 -2987 -1212 154 327 684 1996 1596 1668 430 -1145 -2384 -1364 -2078 -632 128 598 45 -380 -1492 -2322 -2051 -1008 -1716 -484 -357 151 1017 1705 2532 1984 1257 167 -637 -430 -409 -18 349 1021 638 1030 833 -31 -39 -1242 -914 -334 -256 -291 -526 -647 -888 -432 -246 -7 570 895 497 239 -117 -584 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