File name: Pandora85s1_NewOrleansLA-XULA_20240815_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240816T061147.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240815_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240815T123414.1Z 8993.523774 88 1 53.77 2 76.90 81.47 159.54 268.14 0.00 1 0.00 1 0 17 4.060e-01 1.831e-02 1.549e-01 2.610e-03 5.097415e-01 1.354852e-03 6.041750e-03 -6.000000e+00 2.334334e-01 229.55 -2.00 3.24 -2.00 319.98 0.00e+00 3.517480e-03 4.649457e-04 3.409379e-03 -6.000000e+00 1.156825e-02 294.64 -2.00 20.00 -2.00 319.12 0.00e+00 4.297 0.001 302.00 328.00 3 3.1198e+00 4.0890e-03 5.1386e-02 -6.0000e+00 5.7924e-01 -2.2206e-02 4.9912e-03 3.1105e-02 -6.0000e+00 6.2807e-01 -4.7494e-02 4.1045e-03 1.3494e-02 -6.0000e+00 3.7570e-01 7.5112e-03 2.1418e-03 3.1944e-03 -6.0000e+00 1.6182e-01 1.9426e-04 -3.4070e-04 7.4219e-05 5.7690e-05 -6.0000e+00 1.1144e-02 -2.7633e-02 12 8 8 10 0 0 97.14 27.38 0.75 -0.02763 -0.03019 41 5 1 5 0 1311.330 34.50 20.01 27.38 35.34 21.1 1015.75 900000 900000 74512 147058 -127130 900000 -98687 14857 -104941 -96777 -26205 900000 141296 125365 -20596 281442 -55211 -9511 35232 52068 34188 -25282 2872 7918 24760 33888 46186 89302 16376 51547 -27816 37961 -5327 -21672 -27148 -11679 -11482 -19299 489 11367 6761 13515 14313 -1745 -5573 -3296 14745 7985 -164 8836 5267 12328 1204 -4522 9394 5936 -857 -719 -493 -1615 423 6467 835 -1780 1706 6488 -6366 2369 274 2280 5907 4941 -2262 2042 517 -2316 -6008 -3360 -6031 -448 -3469 -2095 -2794 -4422 -458 1575 32 1171 2470 585 2279 780 -991 -3850 -250 -3942 199 918 -2 369 440 -1688 -2131 -2321 -703 -1991 -904 -57 805 812 1299 3098 2472 1578 883 -426 -1044 -1648 -866 93 1084 734 1473 640 266 -248 -2068 -464 -917 -101 -220 9 -618 -328 -757 -139 -392 476 807 591 239 -567 -710 433 900000 900000 341 374 -3822 900000 -2335 125 -3310 -3126 -440 900000 539 702 -618 716 -3272 -392 1013 1351 1113 -1511 131 365 1039 1379 1739 2181 796 1757 -2314 1912 -477 -2574 -3467 -1212 -1230 -2543 63 1613 1068 2188 2439 -365 -1236 -727 2772 1627 -37 1884 1242 3002 360 -1553 3018 2062 -330 -282 -191 -619 160 2433 339 -833 842 3072 -3271 1096 134 1219 3482 2948 -1496 1269 308 -1403 -3407 -1747 -3283 -260 -2242 -1535 -2317 -3723 -393 1425 32 1111 2374 570 2231 718 -866 -3313 -214 -3910 202 1061 -3 481 560 -2043 -2512 -2580 -802 -2333 -1105 -73 1092 1127 1869 4742 3924 2477 1324 -643 -1524 -2463 -1278 146 1750 1184 2293 977 391 -373 -3039 -651 -1356 -156 -375 15 -1134 -595 -1457 -272 -805 991 1711 1253 489 -1114 -1400 829 SS 20240815T124011.5Z 8993.527911 91 1 54.08 2 75.63 82.17 160.76 268.76 0.00 1 0.00 1 0 17 3.144e-01 1.356e-02 8.982e-02 1.677e-03 4.703340e-01 8.525770e-04 5.425898e-03 -6.000000e+00 1.800809e-01 229.55 -2.00 3.24 -2.00 319.40 0.00e+00 2.409138e-03 2.408082e-04 2.384653e-03 -6.000000e+00 8.340913e-03 294.63 -2.00 20.00 -2.00 318.49 0.00e+00 3.941 0.001 302.00 328.00 3 2.7118e+00 2.4516e-03 4.6271e-02 -6.0000e+00 4.4737e-01 -5.6368e-02 2.9089e-03 2.6146e-02 -6.0000e+00 4.8478e-01 -4.2247e-03 2.2184e-03 1.1876e-02 -6.0000e+00 2.9046e-01 -9.5426e-03 1.1732e-03 2.9415e-03 -6.0000e+00 1.2399e-01 4.3166e-04 -4.5521e-04 4.7129e-05 3.7779e-05 -6.0000e+00 8.5390e-03 -2.8207e-02 12 8 8 10 0 0 79.44 27.41 0.53 -0.02821 -0.03163 74 8 1 5 0 730.720 34.50 20.01 27.41 35.76 21.1 1015.74 900000 8056 15122 -24066 -66770 331740 -73990 -7927 -52723 -65609 -25532 31070 9971 6248 -18421 28217 -19693 -9173 10095 10445 6997 -16912 -495 -557 -15373 10361 10812 23815 -1715 10322 -15706 8217 -2354 -7860 -16679 -7329 -10597 -11229 -3379 773 3801 2785 3812 -614 -979 -1766 7924 2466 -170 1635 1102 5376 419 -1642 3952 3292 608 298 -98 -1213 -51 2432 1225 1240 2373 3487 -2231 -111 -1048 1378 3657 2711 -552 1560 411 -1188 -3846 -2929 -4540 -1709 -2556 -1710 -1796 -3168 -1169 530 457 1395 1926 1355 1605 335 -954 -2584 -1177 -2685 -403 698 578 143 -359 -1495 -2162 -2287 -980 -1099 -804 -202 411 973 1726 2543 2253 1384 288 -848 -433 -644 -358 253 1057 651 1042 614 154 23 -1567 -1036 -680 -173 -538 -569 -615 -484 -577 -154 -119 483 860 575 497 -77 -566 -319 900000 101 198 -480 -1900 542 -2153 -132 -1569 -2478 -680 488 222 178 -825 955 -1227 -561 553 608 443 -1380 -35 -41 -1438 798 868 1674 -149 783 -1682 799 -291 -1152 -2467 -1029 -1589 -1752 -585 157 874 709 1017 -179 -291 -537 2225 737 -53 513 369 1744 157 -677 1654 1448 284 143 -46 -573 -24 1175 611 692 1425 2074 -1333 -64 -620 824 2442 1986 -402 1174 296 -796 -2385 -1815 -2891 -1098 -1929 -1368 -1611 -2901 -1111 533 463 1469 2071 1459 1644 343 -917 -2401 -1105 -2670 -446 822 726 191 -470 -1848 -2589 -2587 -1141 -1389 -1011 -267 546 1390 2556 4027 3506 2123 443 -1231 -631 -955 -531 399 1652 1021 1662 957 232 35 -2312 -1470 -1004 -268 -876 -953 -1080 -881 -1064 -291 -235 973 1697 1136 985 -147 -1079 -596 SS 20240815T125054.2Z 8993.535350 94 1 54.02 2 73.33 83.43 162.96 269.96 0.00 1 0.00 1 0 17 6.224e-02 1.187e-02 7.258e-03 9.484e-04 4.140618e-01 4.812688e-04 4.727899e-03 -6.000000e+00 3.565671e-02 229.55 -2.00 3.24 -2.00 318.67 0.00e+00 1.955966e-03 1.069653e-04 1.583766e-03 -6.000000e+00 1.651422e-03 294.63 -2.00 20.00 -2.00 317.72 0.00e+00 3.429 0.000 302.00 328.00 3 2.2070e+00 1.3276e-03 3.9878e-02 -6.0000e+00 8.8581e-02 -5.8199e-02 1.5305e-03 2.1269e-02 -6.0000e+00 9.5984e-02 -2.7521e-03 1.0339e-03 9.9689e-03 -6.0000e+00 5.7510e-02 -7.9946e-03 5.4458e-04 2.5935e-03 -6.0000e+00 2.4553e-02 1.2412e-03 -4.4173e-04 2.6652e-05 2.7961e-05 -6.0000e+00 1.6906e-03 -2.8872e-02 12 8 8 10 0 0 81.34 27.51 0.48 -0.02887 -0.03219 153 17 1 5 0 353.020 34.75 20.01 27.51 36.51 21.0 1015.70 900000 -12313 -7889 -16992 -31729 -6405 -28052 -21293 -21399 -26865 -17463 -13384 -6962 -9455 -8145 5534 -6716 -1492 1993 2682 609 -4036 -301 477 -4614 1491 2936 2554 -2967 101 -6571 1269 -610 -2306 -6913 -7738 -7049 -6637 -1850 1058 1284 1429 1841 219 646 1047 2703 1591 313 38 895 2333 1234 1134 2201 1775 1134 553 308 -26 355 1897 2144 2992 2990 1634 -823 -910 -1008 1123 1725 1744 650 1049 286 -781 -2476 -3573 -4134 -2555 -2448 -1661 -1881 -2510 -1440 -143 119 1121 1604 1441 1201 455 -813 -1974 -1563 -1684 -712 352 682 129 -351 -1269 -2393 -2137 -879 -1373 -802 -185 184 997 1755 2310 1917 1355 300 -500 -208 -300 49 570 670 547 948 722 383 254 -1130 -945 -357 -223 -296 -550 -722 -805 -338 -72 -37 504 735 495 274 -106 -663 -555 900000 -436 -295 -710 -1420 -205 -1136 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