File name: Pandora85s1_NewOrleansLA-XULA_20240816_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240817T061152.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240816_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240816T122627.8Z 8994.518377 117 1 54.36 2 78.67 80.86 145.73 262.80 0.00 1 0.00 1 0 17 3.641e-01 1.598e-02 1.162e-01 2.221e-03 5.791260e-01 1.164833e-03 7.014413e-03 -6.000000e+00 2.095044e-01 229.52 -2.00 3.24 -2.00 320.35 0.00e+00 3.116805e-03 4.548353e-04 4.814462e-03 -6.000000e+00 1.028492e-02 294.60 -2.00 20.00 -2.00 319.53 0.00e+00 4.914 0.001 302.00 328.00 3 2.1750e+00 3.6560e-03 6.0486e-02 -6.0000e+00 5.1999e-01 -6.0771e-03 4.6306e-03 4.0780e-02 -6.0000e+00 5.6382e-01 -8.6698e-02 4.0401e-03 1.5936e-02 -6.0000e+00 3.3743e-01 2.6499e-02 2.0544e-03 4.0311e-03 -6.0000e+00 1.4431e-01 2.6130e-04 -4.2748e-04 6.1457e-05 6.9482e-05 -6.0000e+00 9.9756e-03 -2.9628e-02 12 8 8 10 0 0 -3.63 27.31 0.63 -0.02963 -0.03284 75 8 1 5 0 724.720 34.50 20.01 27.31 35.32 21.3 1015.21 900000 -6563 -27323 253927 -139761 900000 -109399 -72048 -124319 -150228 -35662 900000 22972 56217 -24616 900000 -63819 -22910 36331 49545 20595 -34287 3734 7723 -28785 20786 35337 91142 16101 55820 -33110 38907 -20163 -15109 -29046 -15823 -10751 -19899 -3642 8023 6224 11678 18068 -5850 -3622 -3625 17198 7054 -2459 4805 3734 10985 781 -4402 8407 6030 2189 2924 1488 -1976 566 6062 359 -711 2216 7179 -4450 2592 -81 2654 5377 3341 -1929 2736 1457 -1650 -6133 -2564 -5943 -306 -3595 -1628 -2563 -4478 -484 883 81 1566 1820 938 1715 340 -1217 -2581 -983 -3398 -543 810 207 -10 -69 -1574 -2241 -2431 -1297 -1886 -946 26 625 1078 1849 2810 2268 1440 -275 -828 -165 -962 -766 558 1112 940 1410 553 47 78 -1869 -797 -625 -87 -382 -378 -812 -504 -578 -200 -432 753 956 674 317 -314 -516 -312 900000 -30 -172 550 -2641 900000 -1611 -811 -2691 -4716 -378 900000 169 377 -469 900000 -2584 -684 661 847 495 -1448 109 232 -1359 639 987 1460 526 1233 -1993 1356 -1484 -1204 -2729 -1240 -829 -1917 -360 865 804 1578 2441 -957 -592 -604 2621 1214 -437 912 703 2149 187 -1215 2209 1706 669 908 464 -623 174 1870 131 -297 910 2853 -1916 1033 -34 1237 2799 1932 -1120 1610 817 -870 -3053 -1167 -2882 -160 -2289 -1086 -1953 -3493 -385 746 74 1471 1749 905 1568 292 -998 -2071 -810 -3227 -540 915 250 -13 -88 -1887 -2613 -2656 -1453 -2155 -1130 32 787 1480 2648 4355 3481 2324 -432 -1229 -234 -1405 -1177 901 1761 1478 2256 866 71 114 -2829 -1161 -907 -141 -655 -668 -1526 -942 -1148 -404 -919 1621 2096 1476 669 -632 -1036 -613 SS 20240816T123235.0Z 8994.522627 120 1 53.77 2 77.36 81.59 146.98 263.32 0.00 1 0.00 1 0 17 2.253e-01 1.357e-02 6.096e-02 1.586e-03 5.287413e-01 8.158427e-04 6.236316e-03 -6.000000e+00 1.290934e-01 229.52 -2.00 3.24 -2.00 319.87 0.00e+00 2.002371e-03 2.694720e-04 3.449678e-03 -6.000000e+00 5.977950e-03 294.60 -2.00 20.00 -2.00 319.00 0.00e+00 4.442 0.001 302.00 328.00 3 2.0562e+00 2.4327e-03 5.3260e-02 -6.0000e+00 3.2068e-01 -4.2358e-02 2.9552e-03 3.2930e-02 -6.0000e+00 3.4747e-01 -3.7538e-02 2.3826e-03 1.3473e-02 -6.0000e+00 2.0820e-01 6.7562e-03 1.2434e-03 3.5701e-03 -6.0000e+00 8.8905e-02 4.8722e-04 -3.6665e-04 4.4075e-05 5.1482e-05 -6.0000e+00 6.1199e-03 -3.0018e-02 12 8 8 10 0 0 11.94 27.36 0.49 -0.03002 -0.03277 107 12 1 5 0 502.480 34.50 20.01 27.36 35.65 21.2 1015.32 900000 -46844 -64613 -61953 -104667 117827 -88554 -49357 -80310 -90451 -38520 -15560 -10016 -11149 -16696 40344 -41165 -14644 -4218 1871 9896 -18640 -1398 -4622 -13437 4900 9872 17342 -6374 666 -25285 12599 -10654 -8699 -15713 -12344 -8081 -15232 -1667 2652 4312 4036 7456 -1261 -856 -243 7267 3378 -933 2020 2203 6496 725 -1172 5255 4067 2092 902 944 -1542 213 3596 2056 985 3367 3627 -1705 379 -45 1920 3457 2267 -569 2242 873 -1278 -4416 -3268 -4338 -2421 -2582 -1936 -1928 -3615 -655 491 312 1237 1990 1312 1784 265 -1066 -2214 -1490 -2458 -769 524 596 160 -191 -1819 -2717 -2020 -1090 -1648 -815 -241 493 953 1592 2305 2206 1433 111 -786 -419 -677 -174 471 917 821 1228 566 200 312 -1422 -949 -559 -233 -383 -392 -822 -708 -345 -152 -93 571 852 662 208 -245 -648 -289 900000 -594 -1099 -1064 -2574 292 -1781 -748 -1901 -2658 -715 -241 -170 -240 -473 786 -2089 -627 -178 80 409 -1041 -67 -244 -844 274 553 901 -402 39 -2112 844 -1042 -943 -1869 -1350 -876 -2024 -233 436 745 770 1461 -282 -194 -56 1575 772 -228 496 578 1816 237 -389 1766 1451 790 353 366 -600 81 1406 906 494 1670 1813 -860 184 -23 1067 2168 1454 -388 1460 544 -800 -2572 -1773 -2427 -1498 -1744 -1497 -1567 -3224 -601 450 306 1261 2065 1365 1764 247 -1001 -2018 -1394 -2433 -807 588 755 205 -240 -2289 -3133 -2300 -1279 -1987 -1028 -303 658 1309 2402 3572 3536 2276 170 -1196 -611 -1006 -271 740 1499 1336 1935 872 312 467 -2082 -1341 -825 -365 -633 -701 -1486 -1333 -657 -297 -191 1190 1740 1405 427 -479 -1267 -551 SS 20240816T123754.0Z 8994.526319 123 1 54.10 2 76.22 82.21 148.06 263.77 0.00 1 0.00 1 0 17 1.403e-01 1.231e-02 1.737e-02 1.153e-03 4.904067e-01 5.882065e-04 5.667840e-03 -6.000000e+00 8.037269e-02 229.52 -2.00 3.24 -2.00 319.46 0.00e+00 1.643548e-03 1.682666e-04 2.580375e-03 -6.000000e+00 3.721687e-03 294.60 -2.00 20.00 -2.00 318.55 0.00e+00 4.099 0.001 302.00 328.00 3 1.8445e+00 1.6921e-03 4.8324e-02 -6.0000e+00 1.9966e-01 -5.8660e-02 2.0125e-03 2.8008e-02 -6.0000e+00 2.1633e-01 -1.4948e-02 1.5288e-03 1.2234e-02 -6.0000e+00 1.2962e-01 -1.0848e-03 8.0602e-04 3.1448e-03 -6.0000e+00 5.5354e-02 8.6885e-04 -3.6669e-04 3.2103e-05 3.8092e-05 -6.0000e+00 3.8099e-03 -3.0397e-02 12 8 8 10 0 0 13.20 27.41 0.54 -0.03040 -0.03315 156 17 1 5 0 346.750 34.50 20.01 27.41 36.02 21.3 1015.39 900000 -33629 -40158 -41192 -65252 8654 -71492 -37691 -57615 -58488 -39757 -22522 -15871 -7915 -20740 10109 -21793 -11215 -1455 3946 3428 -12107 -4342 -1264 -8288 3603 793 4170 -5604 -2112 -13458 1398 -5889 -5601 -9933 -8550 -6148 -10175 -1678 2072 2258 2252 3891 257 166 918 4231 2327 -288 624 1840 3423 1404 727 3036 2930 1724 826 466 -1126 372 2560 1804 2225 3166 2708 -878 -233 -963 1768 2178 1903 304 1292 613 -888 -3001 -3465 -4798 -2583 -2739 -1780 -1994 -2671 -1138 -6 514 1121 1888 1430 1624 522 -1041 -2125 -1542 -1873 -511 281 511 42 -397 -1451 -2520 -2159 -852 -1424 -758 -369 223 957 1842 2467 2091 1382 176 -746 -318 -301 254 428 745 575 977 629 261 136 -1156 -943 -300 -258 -390 -435 -804 -757 -355 -174 -45 459 787 525 239 -138 -592 -322 900000 -590 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