File name: Pandora85s1_NewOrleansLA-XULA_20240823_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240824T060655.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240823_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240823T124917.3Z 9001.534228 244 1 54.07 2 74.50 85.88 54.26 260.24 0.00 1 0.00 1 0 25 2.280e-01 1.986e-02 4.865e-02 3.057e-03 4.462904e-01 1.560322e-03 5.383223e-03 -6.000000e+00 1.307852e-01 229.29 -2.00 3.24 -2.00 319.41 0.00e+00 2.045159e-03 4.415382e-04 2.749780e-03 -6.000000e+00 6.149906e-03 294.35 -2.00 20.00 -2.00 318.50 0.00e+00 3.672 0.001 302.00 328.00 3 4.0251e+00 4.4828e-03 4.3973e-02 -6.0000e+00 3.2437e-01 1.2767e-02 5.2793e-03 2.6733e-02 -6.0000e+00 3.5173e-01 -4.1047e-02 3.8857e-03 1.1076e-02 -6.0000e+00 2.1044e-01 8.0156e-03 2.0575e-03 3.0162e-03 -6.0000e+00 8.9666e-02 1.4879e-04 -8.0473e-04 8.7248e-05 3.7930e-05 -6.0000e+00 6.2026e-03 -2.0867e-02 12 9 8 11 32 0 99.49 27.07 0.55 -0.02087 -0.02691 23 3 1 5 0 2350.450 34.25 20.00 27.07 32.85 21.0 1017.86 900000 -14815 -9212 24913 -4546 900000 -81808 -64358 -72040 -59907 5650 -17558 35365 81510 10792 177468 -32527 -20221 -18900 12746 4032 -40 -10653 23658 -7937 22690 22546 -2408 2705 38970 -29174 34766 -6825 -6839 -23339 -11877 -573 -9946 -2512 8390 13296 6639 19272 6057 -2391 572 13383 3104 -114 2892 3483 7818 -1459 -8376 6820 3780 -2520 -2067 4434 -6335 -2443 4033 -403 -884 2406 5907 2930 1613 -559 2531 4851 4552 -3541 693 331 -1856 -3454 -3664 -3213 821 -3722 -1695 -2837 -5815 503 -1209 -384 1525 2973 -491 2877 -1474 -744 -2104 -524 -798 -763 -552 739 -190 598 -2103 -967 -1988 -1605 -2352 -1204 252 395 1308 3184 2893 2851 1422 -409 -741 -975 -1413 -1031 564 954 892 2009 538 537 -18 -2714 -940 -1180 -135 -475 -195 -708 4 -597 -428 -419 692 638 972 752 -492 -721 -271 900000 -322 -209 408 -92 900000 -3389 -2474 -3393 -2768 141 -570 769 1360 444 1640 -2763 -1639 -1628 847 305 -3 -949 1587 -785 1752 1814 -246 249 2451 -3913 2808 -946 -1054 -4271 -1830 -81 -1764 -495 1637 2868 1666 4491 1672 -728 171 3557 916 -35 880 1113 2624 -586 -3556 2897 1721 -1155 -960 1907 -2971 -1106 1805 -208 -510 1449 3414 1646 893 -324 1581 3115 3174 -2757 508 230 -1304 -2219 -2205 -1940 531 -2695 -1372 -2405 -5435 466 -1228 -412 1572 3095 -526 3037 -1502 -698 -1897 -475 -803 -812 -666 924 -252 766 -2579 -1140 -2243 -1888 -3017 -1506 328 545 1815 4736 4630 4402 2294 -633 -1072 -1357 -2005 -1535 883 1558 1457 3162 835 799 -26 -4059 -1335 -1751 -206 -749 -328 -1250 8 -1089 -832 -810 1355 1276 1932 1444 -959 -1350 -497 SS 20240823T130024.2Z 9001.541947 247 1 54.08 2 72.10 87.23 56.56 261.89 0.00 1 0.00 1 0 17 4.942e-02 1.133e-02 5.098e-03 8.456e-04 3.886204e-01 4.270762e-04 4.374984e-03 -6.000000e+00 2.825827e-02 229.29 -2.00 3.24 -2.00 318.35 0.00e+00 1.805792e-03 8.606541e-05 1.197282e-03 -6.000000e+00 1.309155e-03 294.35 -2.00 20.00 -2.00 317.38 0.00e+00 3.208 0.000 302.00 328.00 3 2.2092e+00 1.1654e-03 3.7139e-02 -6.0000e+00 7.0165e-02 -4.4512e-02 1.3368e-03 1.9325e-02 -6.0000e+00 7.6075e-02 1.2165e-03 8.7044e-04 9.2377e-03 -6.0000e+00 4.5582e-02 -8.9108e-03 4.5340e-04 2.4603e-03 -6.0000e+00 1.9444e-02 1.5638e-03 -4.3009e-04 2.3867e-05 2.6010e-05 -6.0000e+00 1.3426e-03 -2.1934e-02 12 8 8 10 0 0 99.96 27.08 0.38 -0.02193 -0.02517 210 23 1 5 0 257.480 34.25 20.00 27.08 32.78 21.1 1017.90 900000 -16314 -13983 -10396 -14932 -12844 -24370 -21234 -16969 -15249 -9017 -14794 -7984 -5197 -2259 5803 -3712 -624 -1326 2514 1759 -1861 -992 2572 -313 800 -628 -577 -2311 -1822 -3752 969 -85 530 -5389 -7027 -5059 -5442 -1494 880 1091 1314 2249 132 994 1744 2114 829 215 -298 711 1616 908 1040 1882 1450 886 433 413 -821 333 1783 1994 2996 2810 1211 -428 -937 -894 642 1374 1247 814 842 147 -857 -1985 -3326 -3542 -2503 -2466 -1598 -1894 -2754 -1292 -284 413 1035 1701 1375 1146 292 -864 -1814 -1463 -1425 -637 396 691 196 -258 -1298 -2203 -1894 -921 -1264 -703 -316 91 1063 1836 2156 1919 1285 165 -468 -340 -162 89 720 571 544 883 620 229 111 -927 -788 -356 -323 -247 -444 -871 -737 -306 -42 -9 590 684 519 265 -181 -560 -596 900000 -813 -744 -540 -745 -578 -1258 -1173 -1019 -995 -574 -1017 -575 -437 -221 615 -438 -76 -175 337 248 -274 -146 386 -52 139 -115 -104 -400 -306 -684 189 -19 128 -1387 -1734 -1265 -1422 -448 312 413 538 958 60 449 790 963 381 100 -130 322 791 485 555 1059 849 537 268 253 -500 202 1123 1291 2123 2010 868 -310 -658 -638 471 1076 1058 714 727 121 -692 -1458 -2446 -2608 -1898 -2034 -1405 -1854 -2755 -1346 -301 464 1156 1935 1559 1299 308 -893 -1785 -1455 -1480 -740 470 873 261 -336 -1658 -2716 -2219 -1123 -1603 -894 -422 123 1525 2726 3274 2963 1932 244 -674 -468 -226 131 1081 869 831 1365 936 333 160 -1293 -1101 -494 -470 -376 -722 -1423 -1239 -521 -74 -17 1066 1263 958 491 -323 -995 -1042 SS 20240823T133647.4Z 9001.567215 268 1 4.00 2 64.22 91.76 64.12 266.89 0.00 1 0.00 1 0 17 2.897e-02 1.482e-02 2.035e-02 7.241e-03 2.923515e-01 3.665989e-03 3.277228e-03 -6.000000e+00 1.656915e-02 229.29 -2.00 3.24 -2.00 317.01 0.00e+00 1.714372e-03 5.094265e-04 5.029400e-04 -6.000000e+00 7.675071e-04 294.34 -2.00 20.00 -2.00 316.07 0.00e+00 2.285 0.000 302.00 328.00 3 4.1843e+00 9.6651e-03 2.6684e-02 -6.0000e+00 4.1141e-02 1.3321e-02 1.0881e-02 1.3892e-02 -6.0000e+00 4.4601e-02 -4.8281e-03 6.3846e-03 6.7475e-03 -6.0000e+00 2.6724e-02 -1.0625e-02 3.1126e-03 1.9072e-03 -6.0000e+00 1.1404e-02 5.8181e-04 -5.5639e-04 2.0576e-04 2.0535e-05 -6.0000e+00 7.8686e-04 -2.4050e-02 12 9 9 12 1 1 999.00 27.17 0.58 -0.02405 -0.02823 1 3 1 5 0 1996.490 34.50 20.00 27.17 33.51 21.1 1018.16 900000 -8245 -14302 -3768 -2593 2421 1721 3295 -4565 1651 -1247 -8789 6297 4677 3540 6377 -3537 -5543 881 3369 -1171 2699 1162 7530 -1203 3624 -207 3121 -5696 3869 -4308 1954 2587 -184 -8665 -6251 -3767 -3068 -1085 1102 654 -3063 1070 167 -395 3256 2774 -880 92 -1178 652 3347 -2066 273 3780 1700 -81 71 162 -1135 -897 2817 1642 2172 3957 1497 -312 -1341 -1029 -844 2029 2011 -989 845 -342 -634 -434 -4106 -2909 -1093 -2842 -1631 -1378 -3772 -557 -432 -309 539 2730 1285 1088 88 -335 -1925 -1962 -1968 444 630 2162 -407 102 -1263 -1824 -2373 -850 -2157 -762 -291 639 578 1195 2790 2547 1086 68 586 -1125 1068 -1158 10 829 97 1692 450 334 255 -1272 -1068 -307 -988 -275 -346 -371 -1385 -408 24 192 511 1140 933 52 -87 -914 -673 900000 -1096 -2167 -513 -316 255 183 376 -633 235 -187 -1416 946 829 739 1358 -906 -1514 237 922 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