File name: Pandora85s1_NewOrleansLA-XULA_20240825_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240826T060725.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240825_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240825T123037.4Z 9003.521266 232 1 54.40 2 78.73 84.31 23.18 254.25 0.00 1 0.00 1 0 17 4.885e-01 3.127e-02 1.487e-01 4.531e-03 5.864065e-01 2.454217e-03 7.150959e-03 -6.000000e+00 2.825670e-01 229.22 -2.00 3.24 -2.00 320.51 0.00e+00 -1.570028e-03 1.010310e-03 5.900350e-03 -6.000000e+00 1.591865e-02 294.27 -2.00 20.00 -2.00 319.71 0.00e+00 4.939 0.001 302.00 328.00 3 3.3576e+00 7.8641e-03 6.4914e-02 -6.0000e+00 6.9942e-01 1.6642e-01 9.8390e-03 5.0988e-02 -6.0000e+00 7.5963e-01 -2.6619e-01 8.2384e-03 1.3941e-02 -6.0000e+00 4.5531e-01 1.1252e-01 4.2036e-03 1.0059e-02 -6.0000e+00 1.9820e-01 7.3288e-05 -8.4169e-04 1.3070e-04 4.2697e-05 -6.0000e+00 1.3792e-02 -2.7179e-02 12 8 8 10 0 0 91.04 27.06 0.56 -0.02718 -0.03350 20 2 1 5 0 2719.870 34.25 20.00 27.06 32.05 21.2 1018.59 900000 900000 -124470 900000 2698 900000 -148421 -108935 -162834 -95302 900000 -67071 900000 900000 900000 900000 -93913 -10619 -43482 160909 280912 9206 13982 900000 -12030 900000 214806 900000 105394 900000 -52137 900000 -3958 7137 -53491 -15831 16753 -18450 16758 42725 60587 35258 71967 5049 12514 -4647 81855 17381 2962 21680 13030 26787 -7169 -14997 27832 18293 -4889 2347 10094 -9683 -694 20551 6769 -1889 6698 14255 -7016 10459 -589 7286 9301 9324 -10349 5328 1126 -3223 -4597 -7001 328 4577 -4689 -3794 -3766 -9258 3652 3523 -562 1094 4515 -3224 7218 -2373 215 -4709 1479 -9421 -2972 -2210 498 -1797 459 -3144 -1527 -2188 -889 -3223 -1957 274 1561 2499 2452 3585 2711 2563 -783 -607 -1170 -2218 -873 -299 1970 1648 3372 293 369 165 -3720 124 -1117 -146 -177 191 -679 794 5 242 -425 942 179 1529 910 -1455 -1266 -1241 900000 900000 -3441 900000 19 900000 -4579 -2532 -7438 -2482 900000 -1451 900000 900000 900000 900000 -6209 -365 -2242 1135 1238 308 450 900000 -594 900000 1231 900000 1672 900000 -4251 900000 -267 484 -6766 -1298 1019 -1813 1396 3371 4700 3869 5773 817 1886 -834 6241 2543 512 3220 2263 4510 -1700 -4182 6011 4571 -1457 666 2613 -2956 -192 5272 2001 -686 2450 4895 -2862 3549 -232 2978 4267 4648 -5933 2786 577 -1565 -2035 -2996 133 2023 -2674 -2478 -2546 -7151 2629 2730 -484 969 3953 -3028 5819 -1954 162 -3591 1104 -8810 -2766 -2344 583 -2123 560 -3702 -1602 -2160 -897 -3598 -2272 330 1985 3196 3489 5145 4079 3817 -1152 -899 -1677 -3265 -1332 -450 3014 2504 5220 454 549 236 -5326 165 -1595 -232 -291 340 -1206 1454 9 476 -881 1969 384 3213 1840 -3023 -2489 -2384 SS 20240825T123648.6Z 9003.525563 235 1 18.04 2 77.40 85.06 24.44 255.81 0.00 1 0.00 1 0 17 2.705e-01 1.666e-02 9.496e-02 3.643e-03 5.320012e-01 1.867273e-03 6.213431e-03 -6.000000e+00 1.546889e-01 229.22 -2.00 3.24 -2.00 319.79 0.00e+00 1.206341e-03 6.030432e-04 3.311346e-03 -6.000000e+00 7.164158e-03 294.27 -2.00 20.00 -2.00 318.92 0.00e+00 4.455 0.001 302.00 328.00 3 2.5052e+00 5.5281e-03 5.3344e-02 -6.0000e+00 3.8404e-01 9.4391e-03 6.6671e-03 3.2890e-02 -6.0000e+00 4.1633e-01 -5.5213e-02 5.3333e-03 1.3006e-02 -6.0000e+00 2.4946e-01 1.5605e-02 2.7991e-03 4.0826e-03 -6.0000e+00 1.0648e-01 2.9711e-04 -6.4823e-04 1.0078e-04 4.4823e-05 -6.0000e+00 7.3463e-03 -2.5463e-02 12 9 9 12 1 1 36.00 27.04 0.42 -0.02546 -0.03033 15 5 1 5 0 1127.050 34.25 20.00 27.04 31.98 21.2 1018.43 900000 -75399 -106069 940 -40885 39993 -93805 -62852 -103742 -89007 -48379 -52520 45259 46677 34859 146696 -60345 -14096 -27722 37257 20650 -11833 -3983 13719 6191 39621 11882 43322 -11969 46209 -28000 13148 -6963 -6812 -25922 -11277 -8679 -13512 -2824 8198 10680 8206 12476 1957 1248 266 10135 1846 2814 1788 -6883 5373 -1628 -1399 8040 4175 8 -688 -153 -3424 -703 5843 2922 2574 5065 4012 -556 1291 -1022 2394 3998 3682 -1886 1492 -202 -2127 -3226 -2517 -3529 -497 -2946 -2037 -2019 -4618 -458 460 293 1470 2292 445 2261 -296 -803 -2186 -2179 -3372 -1123 35 535 424 182 -1725 -2059 -2510 -1513 -1201 -909 -48 244 1225 1730 2583 2502 1700 -227 -493 -1168 -1052 263 432 720 726 1316 564 409 503 -1814 -753 -587 20 -522 -170 -1235 -209 -504 -187 -199 1039 707 1076 210 -397 -875 -621 900000 -1447 -2809 10 -596 242 -2233 -1228 -3502 -2909 -1117 -1325 499 630 656 1095 -4095 -661 -1625 1218 836 -673 -212 658 350 1717 713 1893 -868 1855 -2597 944 -705 -777 -3316 -1302 -1011 -1887 -389 1239 1849 1601 2474 449 293 64 2246 450 694 461 -2074 1591 -523 -487 2745 1554 3 -285 -62 -1411 -282 2315 1322 1213 2549 2056 -285 641 -538 1364 2567 2392 -1336 1002 -130 -1370 -1894 -1383 -2000 -308 -2037 -1607 -1672 -4230 -426 429 291 1514 2400 471 2242 -279 -758 -2008 -2072 -3399 -1193 39 682 543 229 -2169 -2497 -2873 -1784 -1442 -1146 -63 326 1762 2599 3976 3978 2675 -346 -742 -1702 -1557 404 673 1165 1168 2042 899 627 738 -2619 -1098 -853 32 -890 -298 -2199 -385 -941 -372 -400 2107 1466 2215 419 -787 -1662 -1205 SS 20240825T124119.7Z 9003.528700 238 1 53.99 2 76.43 85.61 25.36 256.87 0.00 1 0.00 1 0 17 1.385e-01 1.217e-02 9.487e-03 8.112e-04 4.936552e-01 4.129443e-04 5.645699e-03 -6.000000e+00 7.925015e-02 229.22 -2.00 3.24 -2.00 319.25 0.00e+00 1.707176e-03 1.103455e-04 2.333948e-03 -6.000000e+00 3.669885e-03 294.27 -2.00 20.00 -2.00 318.34 0.00e+00 4.157 0.001 302.00 328.00 3 1.1106e+00 1.1727e-03 4.8539e-02 -6.0000e+00 1.9675e-01 -2.6887e-02 1.3816e-03 2.7036e-02 -6.0000e+00 2.1328e-01 -2.1140e-02 1.0188e-03 1.2145e-02 -6.0000e+00 1.2780e-01 1.5902e-03 5.3735e-04 3.0883e-03 -6.0000e+00 5.4560e-02 1.6772e-03 -3.1950e-04 2.2513e-05 3.5636e-05 -6.0000e+00 3.7629e-03 -2.6833e-02 12 8 8 10 0 0 40.21 27.03 0.43 -0.02683 -0.02923 251 28 1 5 0 215.090 34.25 20.01 27.03 32.03 21.2 1018.46 900000 -52195 -49000 -41647 -41326 -33626 -59113 -54667 -50507 -44607 -36075 -40955 -24012 -21815 -12433 -3734 -15686 -8830 -8119 -1249 -2651 -7475 -6099 -97 -4150 645 -845 -2239 -7881 -4210 -7663 1095 -2913 -2902 -7236 -9356 -6584 -7667 -1707 2178 3149 2431 4130 1577 2005 2033 2775 1257 623 193 1139 2802 1414 1323 3171 2107 1252 952 631 -177 579 2066 2391 3618 3671 1465 -164 -737 -1182 999 1462 1594 882 1057 -124 -1022 -2312 -3907 -4140 -2653 -2392 -1892 -1894 -2723 -1495 -212 427 1099 1572 1436 1197 259 -964 -2058 -1535 -1782 -836 325 769 82 -481 -1375 -2357 -2058 -799 -1273 -891 -239 157 1270 1950 2137 1861 1326 107 -482 -320 -94 283 576 602 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