File name: Pandora85s1_NewOrleansLA-XULA_20240903_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240904T073936.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240903_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240903T123532.0Z 9012.524677 55 1 54.50 2 78.64 88.13 84.16 85.73 0.00 1 0.00 1 0 17 3.170e-01 1.670e-02 1.200e-01 2.441e-03 5.534731e-01 1.278194e-03 6.926386e-03 -6.000000e+00 1.819599e-01 228.92 -2.00 3.24 -2.00 320.21 0.00e+00 4.280902e-03 4.736046e-04 4.848726e-03 -6.000000e+00 8.949591e-03 293.95 -2.00 20.00 -2.00 319.38 0.00e+00 4.901 0.001 302.00 328.00 3 2.3894e+00 3.9267e-03 5.9458e-02 -6.0000e+00 4.5159e-01 1.9492e-02 4.8911e-03 3.8886e-02 -6.0000e+00 4.9014e-01 -7.2972e-02 4.1867e-03 1.5666e-02 -6.0000e+00 2.9298e-01 1.9140e-02 2.1549e-03 3.5655e-03 -6.0000e+00 1.2534e-01 2.1480e-04 -6.3561e-04 6.8212e-05 7.4372e-05 -6.0000e+00 8.6883e-03 -2.7726e-02 12 8 8 10 0 0 99.44 27.07 0.59 -0.02773 -0.03250 53 6 1 5 0 1028.200 34.50 20.01 27.07 32.75 21.6 1013.32 900000 -107691 -49384 60085 4816 900000 -57285 -106568 -106626 -111751 900000 -60307 165315 900000 71277 900000 -84838 -14362 -30438 7150 50745 -34746 -11768 38900 2720 99860 32291 60291 -2183 72513 -43970 31335 4288 6050 -25988 -34038 -10427 -14997 -526 13106 7388 6696 19158 -709 4575 -8322 12322 8374 3341 3754 191 9864 -1901 -3819 8329 3922 -772 1910 35 -4667 -1152 8179 810 1581 5663 5743 -1212 2005 -3218 775 4938 2959 -80 1075 780 -575 -2578 -1546 -4669 553 -1376 -1740 -1570 -4467 -1229 1400 268 1020 2202 0 2632 -1010 -1181 -2236 -1191 -4599 -678 -479 1174 -616 -177 -2027 -2716 -2592 -451 -1717 -1233 265 583 1058 1517 2904 2075 1710 -494 -436 -693 -480 -561 208 1152 1092 1339 531 472 317 -1708 -1077 -919 -659 -52 -509 -756 -223 -551 -35 -87 804 899 684 376 -368 -904 -466 900000 -1700 -491 229 30 900000 -627 -2104 -2385 -2925 900000 -1047 393 900000 627 900000 -5086 -472 -1289 223 1074 -1752 -476 1009 109 1616 1076 1520 -99 1570 -3410 1357 284 446 -2702 -3644 -910 -1559 -57 1509 1056 1061 2853 -123 769 -1624 2204 1443 624 726 41 2146 -514 -1145 2385 1229 -263 646 12 -1632 -391 2677 318 639 2419 2486 -540 856 -1501 389 2726 1811 -48 626 465 -316 -1306 -733 -2344 299 -825 -1209 -1228 -3605 -1018 1216 251 994 2031 0 2460 -909 -995 -1832 -1003 -4497 -685 -520 1422 -808 -227 -2460 -3008 -2865 -506 -1980 -1492 334 740 1460 2184 4490 3352 2731 -769 -637 -978 -687 -847 333 1901 1791 2124 824 706 456 -2551 -1553 -1393 -1054 -87 -879 -1382 -424 -1060 -73 -179 1675 1910 1452 768 -753 -1773 -892 SS 20240903T124134.4Z 9012.528871 58 1 54.10 2 77.33 88.88 82.90 86.47 0.00 1 0.00 1 0 17 2.073e-01 1.496e-02 4.163e-02 2.072e-03 5.040883e-01 1.061647e-03 6.004808e-03 -6.000000e+00 1.188412e-01 228.92 -2.00 3.24 -2.00 319.75 0.00e+00 2.362849e-03 3.379048e-04 3.354157e-03 -6.000000e+00 5.584515e-03 293.95 -2.00 20.00 -2.00 318.88 0.00e+00 4.432 0.001 302.00 328.00 3 2.5928e+00 3.1308e-03 5.2324e-02 -6.0000e+00 2.9453e-01 -1.2117e-02 3.7681e-03 3.1228e-02 -6.0000e+00 3.1937e-01 -3.7125e-02 2.9923e-03 1.2873e-02 -6.0000e+00 1.9112e-01 6.6822e-03 1.5712e-03 3.3043e-03 -6.0000e+00 8.1569e-02 2.9046e-04 -5.1407e-04 5.8030e-05 4.9681e-05 -6.0000e+00 5.6409e-03 -2.8258e-02 12 8 8 10 0 0 88.25 27.08 0.40 -0.02826 -0.03212 53 6 1 5 0 1020.650 34.25 20.00 27.08 32.98 21.7 1013.41 900000 -53963 -65580 -234 -52398 900000 -66618 -46722 -90634 -75139 42809 -53100 4905 70025 8228 90084 -50736 -3914 -15413 2673 23428 -14246 -14123 24623 6432 31124 17579 28148 -5663 18703 -28436 18641 4959 -1818 -17014 -21668 -2988 -16370 -5222 5096 5415 3934 9484 -3151 1178 -4149 7727 4864 2444 2742 -890 6726 -1304 -2679 5975 3891 522 593 592 -3265 -608 5606 609 3170 4591 3856 -2213 723 -2245 1885 3266 2816 -54 986 60 -1681 -2062 -2818 -4611 -610 -2451 -2078 -1732 -3692 -795 967 437 968 1958 214 1831 -217 -855 -2816 -1286 -2615 -963 -431 852 35 -26 -1827 -2345 -2334 -724 -1857 -644 242 376 1346 1825 2481 2127 1808 19 -479 -629 -522 -470 84 972 858 1194 494 -71 133 -1283 -1187 -618 -494 -252 -609 -918 -537 -367 -163 -291 738 957 811 431 -149 -795 -436 900000 -938 -1431 -3 -963 900000 -1346 -859 -2948 -2338 432 -1459 87 806 218 1274 -3362 -178 -856 132 989 -889 -890 1124 382 1541 1044 1501 -405 1039 -2775 1322 464 -205 -2276 -2880 -340 -2428 -832 814 1010 818 1979 -779 284 -1071 1804 1181 620 716 -257 1991 -460 -952 2095 1458 210 243 240 -1348 -245 2244 284 1618 2329 1984 -1153 389 -1184 1066 2084 1962 -37 659 41 -1072 -1190 -1540 -2607 -373 -1655 -1607 -1400 -3275 -726 934 425 981 2016 224 1794 -214 -792 -2543 -1179 -2535 -1049 -502 1045 45 -33 -2224 -2762 -2587 -822 -2308 -787 309 513 1872 2783 3865 3427 2866 30 -726 -917 -772 -733 132 1582 1394 1880 762 -106 200 -1874 -1678 -910 -767 -409 -1072 -1624 -985 -680 -323 -579 1490 1967 1666 855 -295 -1515 -848 SS 20240903T124639.7Z 9012.532404 61 1 54.09 2 76.23 89.51 81.84 87.10 0.00 1 0.00 1 0 17 1.235e-01 1.270e-02 1.642e-02 1.326e-03 4.709360e-01 6.721495e-04 5.454437e-03 -6.000000e+00 7.059548e-02 228.92 -2.00 3.24 -2.00 319.29 0.00e+00 2.406888e-03 1.818529e-04 2.384799e-03 -6.000000e+00 3.267369e-03 293.95 -2.00 20.00 -2.00 318.38 0.00e+00 4.102 0.001 302.00 328.00 3 2.1327e+00 1.9132e-03 4.7522e-02 -6.0000e+00 1.7516e-01 -3.1976e-02 2.2570e-03 2.6009e-02 -6.0000e+00 1.8991e-01 -1.4012e-02 1.6799e-03 1.1903e-02 -6.0000e+00 1.1380e-01 -2.7417e-03 8.8743e-04 2.9634e-03 -6.0000e+00 4.8615e-02 6.5497e-04 -4.2181e-04 3.7046e-05 3.9291e-05 -6.0000e+00 3.3541e-03 -2.9177e-02 12 8 8 10 0 0 69.69 27.10 0.53 -0.02918 -0.03235 100 11 1 5 0 540.860 34.50 20.00 27.10 33.18 21.7 1013.46 900000 -48407 -44983 -29979 -36731 -19522 -42542 -44847 -59321 -45913 -17260 -33097 -8993 2134 -4399 22420 -23586 -4552 -11145 1854 7208 -11284 -9725 7897 846 6366 5586 4873 -9648 6327 -13830 5647 -1993 -1659 -11294 -15350 -8633 -9120 -1583 1857 548 2094 4808 289 2707 -872 4165 1169 65 1077 571 3918 -217 275 4031 2441 1050 557 -168 -1275 -387 2934 1570 3358 3434 2284 -177 -746 -1545 640 1949 2004 703 1113 485 -723 -2099 -2645 -4381 -1869 -2394 -1878 -1677 -2578 -1381 13 521 1025 1560 1149 1547 -68 -1124 -2035 -1607 -2349 -912 178 879 446 -293 -1567 -2244 -2338 -847 -1523 -710 121 242 1151 1793 2528 2065 1394 -29 -668 -428 -257 105 417 815 693 1045 611 215 115 -1176 -1125 -471 -396 -138 -624 -744 -791 -463 -202 17 635 884 646 287 -137 -693 -433 900000 -1227 -1227 -725 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