File name: Pandora85s1_NewOrleansLA-XULA_20240917_L2Fit_fwvt1c2d20230315p1-8.txt File generation date: 20240918T060354.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240917_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0669 492.1877 492.3084 492.4291 492.5497 492.6704 492.7911 492.9117 493.0323 493.1529 493.2735 493.3940 493.5146 493.6351 493.7556 493.8761 493.9966 494.1170 494.2375 494.3579 494.4783 494.5987 494.7190 494.8394 494.9597 495.0801 495.2004 495.3207 495.4409 495.5612 495.6814 495.8016 495.9218 496.0420 496.1622 496.2824 496.4025 496.5226 496.6427 496.7628 496.8829 497.0029 497.1229 497.2430 497.3630 497.4829 497.6029 497.7229 497.8428 497.9627 498.0826 498.2025 498.3223 498.4422 498.5620 498.6818 498.8016 498.9214 499.0412 499.1609 499.2806 499.4003 499.5200 499.6397 499.7594 499.8790 499.9986 500.1182 500.2378 500.3574 500.4770 500.5965 500.7160 500.8355 500.9550 501.0745 501.1939 501.3134 501.4328 501.5522 501.6716 501.7909 501.9103 502.0296 502.1489 502.2682 502.3875 502.5068 502.6260 502.7453 502.8645 502.9837 503.1028 503.2220 503.3411 503.4603 503.5794 503.6985 503.8175 503.9366 504.0556 504.1747 504.2937 504.4127 504.5316 504.6506 504.7695 504.8884 505.0073 505.1262 505.2451 505.3640 505.4828 505.6016 505.7204 505.8392 505.9580 506.0767 506.1954 506.3141 506.4328 506.5515 506.6702 506.7888 506.9074 507.0261 507.1446 507.2632 507.3818 507.5003 507.6188 507.7373 507.8558 507.9743 508.0928 508.2112 508.3296 508.4480 508.5664 508.6848 508.8031 508.9214 509.0398 509.1581 509.2763 509.3946 509.5128 509.6311 509.7493 509.8675 509.9857 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240917T122638.4Z 9026.518500 237 1 9.82 2 82.13 92.31 107.39 271.44 0.00 1 0.00 1 0 225 3.855e-02 3.809e-02 1.202e-02 1.139e-02 1.653708e+03 7.153950e+02 1.543483e+02 -6.000000e+00 2.227294e+03 293.32 -2.00 20.00 -2.00 504.74 0.00e+00 5.907852e-03 3.141894e-04 4.215650e-04 -6.000000e+00 1.108794e-03 293.32 -2.00 20.00 -2.00 499.04 0.00e+00 -3.598743e+00 2.342632e-01 5.564566e-02 -6.000000e+00 7.569768e-01 228.40 -2.00 3.24 -2.00 500.66 0.00e+00 6.803 0.004 489.00 513.00 1 8.0116e+00 1.8062e-02 1.4171e-02 -6.0000e+00 5.8314e-02 3.0002e-01 4.7546e-03 7.0404e-04 -6.0000e+00 1.5012e-02 2.9453e-04 4.8069e-02 1.1045e-03 1.5196e-04 -6.0000e+00 3.9256e-03 -2.7111e-02 12 8 8 10 0 0 38.53 26.83 0.91 -0.02711 0.30631 523 58 1 4 0 18.760 34.25 20.01 26.83 31.92 39.2 1012.56 421 1494 5744 4894 8053 6357 5062 2565 2135 -943 -3321 -2809 -4244 -2304 -3389 -645 4434 1033 462 952 2076 2159 2645 4509 1828 -1628 -2078 -5421 -5967 -6236 -4532 236 -324 1061 2143 -2351 -205 -1116 -1763 -1097 -374 3630 4234 5234 1565 137 -138 -3521 -5793 -9326 -6884 -4183 -3703 -2941 1965 1950 1507 3455 3202 4674 3662 3954 4331 755 -2146 -2171 -735 -5334 -1574 -5458 -3780 943 -2088 -3501 -4135 -4065 -4377 -5304 -7795 -3948 -3699 -1539 -1315 -1339 -2329 -2219 -3171 -1331 1797 316 2525 2921 422 -188 -246 -3904 -4273 -5006 -7517 -5620 -238 -151 1490 88 -3268 -1998 -2164 -898 -811 1860 4307 6277 8392 9247 8769 9287 3646 5122 1724 1682 1406 4788 7383 4065 1045 4254 1958 996 649 1525 -1212 -2984 -3637 1097 4555 2757 2755 5785 1669 4061 5701 4302 3398 675 -1114 891 -1854 -8502 -1523 -1985 2438 537 1935 7265 6332 10161 8125 6458 3080 2522 -1125 -3972 -3295 -5026 -2689 -4048 -763 5043 1217 545 1115 2401 2499 3051 5082 2091 -1881 -2330 -6106 -6696 -7072 -5174 264 -370 1191 2349 -2658 -225 -1228 -1963 -1225 -420 3960 4616 5637 1730 151 -149 -3822 -6250 -10238 -7361 -4426 -4008 -3241 2094 2088 1618 3629 3379 4877 3859 4128 4447 790 -2272 -2264 -744 -5576 -1578 -5710 -3920 940 -2144 -3599 -4199 -4060 -4344 -5298 -8008 -3921 -3677 -1505 -1291 -1315 -2303 -2182 -3142 -1300 1717 311 2458 2831 414 -182 -233 -3728 -3985 -4616 -7088 -5268 -217 -140 1374 82 -3082 -1833 -1980 -819 -707 1604 3673 5290 6952 7606 7236 7559 3090 4193 1433 1378 1149 3787 5690 3229 852 3337 1562 795 511 1164 -932 -2300 -2808 814 3313 2063 2075 4234 1271 3013 4154 3168 2503 502 -820 624 -1308 -6385 -1075 -1428 1695 SQ 20240917T122648.3Z 9026.518615 237 2 9.82 2 82.09 92.33 107.43 271.46 0.00 1 0.00 1 0 239 3.830e-02 3.795e-02 1.203e-02 1.140e-02 7.679498e+02 6.944446e+02 1.028049e+02 -6.000000e+00 2.212927e+03 293.32 -2.00 20.00 -2.00 504.75 0.00e+00 6.121861e-03 3.150695e-04 4.356365e-04 -6.000000e+00 1.101632e-03 293.32 -2.00 20.00 -2.00 499.04 0.00e+00 -3.041181e+00 2.355728e-01 5.562173e-02 -6.000000e+00 7.520425e-01 228.40 -2.00 3.24 -2.00 500.67 0.00e+00 6.777 0.004 489.00 513.00 1 7.9751e+00 1.8174e-02 1.4335e-02 -6.0000e+00 5.7935e-02 2.8976e-01 4.7983e-03 6.4837e-04 -6.0000e+00 1.4914e-02 2.9435e-04 3.9340e-02 1.0945e-03 1.5844e-04 -6.0000e+00 3.9002e-03 -2.6327e-02 12 8 8 10 0 0 39.93 26.83 0.91 -0.02633 0.24655 523 58 1 4 0 18.760 34.25 20.01 26.83 31.92 39.2 1012.59 -2132 1295 4137 5116 7344 6372 6176 4177 2598 -166 -1109 -2435 -3988 -3146 -759 -1534 2517 483 1281 1777 3270 1048 2330 1497 1905 887 -1120 -5291 -5896 -6275 -4659 -2976 -499 2197 1203 -485 -471 -3489 -490 465 567 1718 4506 4614 1490 2765 592 -2664 -6387 -7466 -8277 -7607 -3160 -2587 -561 344 4177 1384 830 5403 5521 1298 4671 2163 1002 -1046 -1446 -4816 -4063 -3715 -2261 -1169 -2860 -1800 -1906 -3870 -5003 -5082 -6570 -5489 -3685 -1546 -2828 -2537 -1149 -3581 -4225 -773 813 -569 1995 1910 5174 2406 1486 -2688 -4597 -7266 -8018 -5458 -4217 -1399 2139 1656 -1471 -1292 -4765 -4482 1862 1193 5820 3018 7935 7576 6313 8158 6632 2638 6734 1259 1184 2844 6501 3420 5003 3999 3456 2486 1125 2309 175 1299 -4379 918 1224 364 177 2652 4937 5948 6336 2538 4228 2752 -31 -319 -3744 -4152 -3302 -2409 110 -2737 1656 5262 6549 9296 8156 7845 4981 3082 -198 -1308 -2859 -4710 -3686 -876 -1813 2903 572 1501 2066 3734 1225 2695 1744 2193 1014 -1267 -6028 -6626 -7078 -5256 -3397 -569 2449 1341 -542 -520 -3936 -537 509 628 1901 4894 5015 1660 3000 643 -2912 -7031 -8109 -8967 -8246 -3355 -2808 -609 374 4371 1485 895 5586 5711 1396 4809 2248 1035 -1085 -1483 -5029 -4169 -3799 -2293 -1182 -2955 -1827 -1903 -3871 -4997 -5047 -6627 -5502 -3640 -1500 -2795 -2509 -1119 -3557 -4208 -744 776 -558 1934 1866 4868 2296 1403 -2574 -4357 -6902 -7583 -5055 -3929 -1298 1946 1509 -1363 -1175 -4440 -3933 1653 1021 5134 2607 6567 6310 5325 6720 5476 2225 5347 1039 968 2286 5047 2734 3923 3152 2721 1965 890 1770 134 966 -3409 679 914 278 137 2004 3645 4337 4594 1909 3111 2028 -23 -230 -2720 -2991 -2366 -1733 78 SQ 20240917T122658.2Z 9026.518729 237 3 9.82 2 82.06 92.35 107.46 271.48 0.00 1 0.00 1 0 22 3.779e-02 3.789e-02 1.211e-02 1.147e-02 9.950314e+02 7.144591e+02 9.660127e+01 -6.000000e+00 2.183557e+03 293.32 -2.00 20.00 -2.00 504.74 0.00e+00 6.267313e-03 3.193811e-04 4.176735e-04 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