File name: Pandora51s1_OldFieldNY_20250320_L2Fit_fwvt1c5d20211018p1-8.txt
File generation date: 20250321T050728.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 51
Spectrometer number: 1
Processing software version used: BlickP v1.8.74
Instrument operation file used: Pandora51_OF_v5d20190801.txt
Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt
Level 1 file used: Pandora51s1_OldFieldNY_20250320_L1_smca1c5d20211018p1-8.txt
Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044)
Short location name: OldFieldNY
Country of location: USA
Location latitude [deg]: 40.9635
Location longitude [deg]: -73.1402
Location altitude [m]: 3
Local noon date: 20250320
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO
First and last pixel inside fitting window: 1681 1831
Nominal wavelengths inside fitting window [nm]: 492.1009 492.2214 492.3419 492.4623 492.5828 492.7032 492.8236 492.9440 493.0643 493.1847 493.3050 493.4253 493.5456 493.6659 493.7862 493.9064 494.0266 494.1468 494.2670 494.3872 494.5074 494.6275 494.7476 494.8677 494.9878 495.1079 495.2280 495.3480 495.4680 495.5880 495.7080 495.8280 495.9479 496.0679 496.1878 496.3077 496.4276 496.5474 496.6673 496.7871 496.9069 497.0267 497.1465 497.2663 497.3860 497.5057 497.6254 497.7451 497.8648 497.9845 498.1041 498.2237 498.3433 498.4629 498.5825 498.7021 498.8216 498.9411 499.0606 499.1801 499.2996 499.4190 499.5385 499.6579 499.7773 499.8967 500.0160 500.1354 500.2547 500.3740 500.4933 500.6126 500.7318 500.8511 500.9703 501.0895 501.2087 501.3279 501.4470 501.5662 501.6853 501.8044 501.9235 502.0426 502.1616 502.2806 502.3997 502.5187 502.6376 502.7566 502.8755 502.9945 503.1134 503.2323 503.3512 503.4700 503.5889 503.7077 503.8265 503.9453 504.0641 504.1828 504.3016 504.4203 504.5390 504.6577 504.7763 504.8950 505.0136 505.1322 505.2508 505.3694 505.4880 505.6065 505.7250 505.8436 505.9620 506.0805 506.1990 506.3174 506.4358 506.5542 506.6726 506.7910 506.9094 507.0277 507.1460 507.2643 507.3826 507.5009 507.6191 507.7373 507.8555 507.9737 508.0919 508.2101 508.3282 508.4463 508.5645 508.6825 508.8006 508.9187 509.0367 509.1547 509.2727 509.3907 509.5087 509.6266 509.7445 509.8625 509.9804
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250320T143134.2Z 9210.605257 355 1 48.49 2 52.89 130.86 98.87 241.25 0.00 1 0.00 1 0 15 2.519e-03 2.522e-03 8.281e-04 8.252e-04 1.103966e+03 4.588353e+01 7.748279e+01 -6.000000e+00 1.345349e+02 277.58 -2.00 20.00 -2.00 505.25 0.00e+00 5.188153e-04 2.211627e-05 3.364520e-05 -6.000000e+00 6.907779e-05 277.58 -2.00 20.00 -2.00 500.39 0.00e+00 3.806704e-02 1.616136e-02 1.093045e-02 -6.000000e+00 4.933210e-02 226.55 -2.00 3.51 -2.00 501.98 0.00e+00 1.653 0.000 489.00 513.00 1 7.4844e+00 1.2372e-03 2.6525e-03 -6.0000e+00 3.7728e-03 6.0776e-03 3.2157e-04 2.6139e-04 -6.0000e+00 9.8205e-04 8.6091e-04 5.1037e-04 7.7508e-05 1.5081e-05 -6.0000e+00 2.4124e-04 1.2910e-02 -1.2286e-04 10 0 0 10 0 0 99.85 22.11 1.50 0.01291 0.01645 20 5 1 4 0 2423.650 26.83 20.00 22.11 14.08 22.2 969.98 -197 -287 -141 181 657 422 553 478 462 252 229 -96 -362 -342 -150 -76 68 -86 -236 78 -37 355 148 -31 68 255 237 -178 -62 -175 -19 82 -57 -338 -173 -54 270 -2 7 -63 -197 106 227 172 241 -50 211 6 -159 -185 -585 -606 -348 -318 -75 -316 21 -167 216 266 141 95 306 28 64 42 0 -143 -213 -298 -208 -141 62 -14 -562 -291 -17 21 -133 -176 -204 -133 -100 -284 -99 -463 -341 -29 -285 -46 27 155 -139 82 237 27 11 -154 -260 -370 -332 -82 -304 -451 -269 -215 -102 78 -75 -43 -160 31 122 219 574 490 500 418 322 287 176 318 235 160 262 210 299 129 490 -517 -134 141 -68 43 76 -36 -176 114 -111 -130 244 210 356 320 25 1 -119 -196 -285 -61 -252 -191 -284 -144 181 669 439 585 509 489 263 236 -98 -363 -339 -148 -76 68 -89 -251 83 -40 380 158 -34 73 275 254 -188 -64 -174 -19 81 -57 -354 -186 -58 288 -2 8 -65 -204 111 239 183 259 -54 225 6 -165 -187 -575 -581 -329 -304 -74 -321 22 -174 225 276 146 99 320 29 67 43 0 -142 -210 -290 -201 -136 61 -14 -564 -290 -17 20 -126 -167 -194 -128 -97 -278 -98 -464 -342 -29 -285 -46 27 150 -137 81 233 26 10 -151 -248 -347 -310 -77 -296 -431 -264 -211 -99 74 -70 -40 -154 30 121 219 576 495 507 425 325 286 172 307 225 154 253 203 288 125 471 -502 -129 133 -63 39 69 -33 -165 109 -108 -128 241 208 354 320 25 1 -117 -189 -268 -56 -235
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SQ 20250320T144612.6Z 9210.615423 361 1 50.11 2 50.85 134.73 101.24 243.35 0.00 1 0.00 1 0 15 2.657e-03 2.649e-03 9.994e-04 9.963e-04 1.118616e+03 5.494550e+01 7.852131e+01 -6.000000e+00 1.419216e+02 277.58 -2.00 20.00 -2.00 505.23 0.00e+00 4.257639e-04 2.663810e-05 2.719609e-05 -6.000000e+00 7.287022e-05 277.58 -2.00 20.00 -2.00 500.41 0.00e+00 7.009212e-02 1.937664e-02 1.034444e-02 -6.000000e+00 5.204006e-02 226.55 -2.00 3.51 -2.00 502.00 0.00e+00 1.581 0.000 489.00 513.00 1 7.8056e+00 1.4793e-03 2.5035e-03 -6.0000e+00 3.9799e-03 2.9040e-03 3.8717e-04 2.5421e-04 -6.0000e+00 1.0360e-03 6.3020e-04 8.5372e-04 9.3421e-05 1.4310e-05 -6.0000e+00 2.5448e-04 1.3275e-02 -1.2467e-04 10 0 0 10 0 0 96.65 22.11 1.46 0.01328 0.01920 17 4 1 4 0 2947.070 26.83 20.00 22.11 14.99 22.2 975.90 -230 -333 -108 284 660 225 551 294 346 421 273 83 -274 -390 -10 75 18 -222 -146 -138 85 380 130 -21 234 459 195 -155 4 -184 -276 44 -51 -321 -186 -43 203 -172 137 -32 -257 -125 127 74 153 113 130 304 -328 -387 -383 -575 -58 -273 -69 -505 -40 -143 223 259 87 323 74 -19 127 207 86 -105 -316 -202 -180 -210 206 -34 -282 -362 34 -145 -375 -122 -416 -225 -48 -307 -279 -508 -80 -276 -19 -25 186 166 -100 181 66 28 124 -153 -367 -320 -182 -29 -224 -636 -171 -480 17 53 -99 125 -124 -28 104 207 364 534 647 278 293 237 103 270 456 351 36 275 289 421 299 -718 -117 32 -149 -85 89 -25 226 -149 109 -39 416 422 97 324 -250 37 -361 -188 -189 -26 -55 -222 -328 -110 298 666 233 577 310 363 435 278 83 -289 -407 -10 79 18 -229 -154 -147 91 402 138 -23 250 490 207 -163 4 -182 -270 43 -51 -334 -198 -46 215 -181 142 -33 -265 -130 132 79 163 120 137 317 -338 -388 -372 -547 -55 -259 -67 -509 -41 -148 230 267 90 335 77 -20 131 210 86 -103 -309 -194 -172 -202 199 -34 -280 -358 33 -138 -355 -115 -394 -215 -46 -298 -275 -505 -80 -275 -18 -25 187 169 -103 188 68 28 123 -149 -349 -298 -169 -27 -217 -640 -166 -470 17 53 -98 124 -125 -27 102 206 362 534 649 280 293 234 100 258 432 334 35 263 276 402 285 -691 -112 29 -145 -82 85 -24 210 -142 105 -38 407 415 96 322 -250 37 -354 -180 -176 -24 -51
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