File name: Pandora51s1_OldFieldNY_20250413_L2Fit_fout2c5d20211018p1-8.txt
File generation date: 20250414T045759.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 51
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora51_OF_v5d20190801.txt
Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt
Level 1 file used: Pandora51s1_OldFieldNY_20250413_L1_smca1c5d20211018p1-8.txt
Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044)
Short location name: OldFieldNY
Country of location: USA
Location latitude [deg]: 40.9635
Location longitude [deg]: -73.1402
Location altitude [m]: 3
Local noon date: 20250413
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO
First and last pixel inside fitting window: 257 399
Nominal wavelengths inside fitting window [nm]: 305.1342 305.2748 305.4155 305.5562 305.6968 305.8375 305.9781 306.1187 306.2593 306.3999 306.5405 306.6810 306.8216 306.9621 307.1027 307.2432 307.3837 307.5242 307.6647 307.8052 307.9457 308.0861 308.2266 308.3670 308.5074 308.6478 308.7882 308.9286 309.0690 309.2094 309.3497 309.4901 309.6304 309.7707 309.9110 310.0513 310.1916 310.3319 310.4722 310.6124 310.7527 310.8929 311.0331 311.1733 311.3135 311.4537 311.5939 311.7340 311.8742 312.0143 312.1545 312.2946 312.4347 312.5748 312.7149 312.8549 312.9950 313.1350 313.2751 313.4151 313.5551 313.6951 313.8351 313.9751 314.1151 314.2550 314.3950 314.5349 314.6748 314.8147 314.9546 315.0945 315.2344 315.3743 315.5141 315.6540 315.7938 315.9336 316.0734 316.2132 316.3530 316.4928 316.6326 316.7723 316.9120 317.0518 317.1915 317.3312 317.4709 317.6106 317.7503 317.8899 318.0296 318.1692 318.3088 318.4484 318.5880 318.7276 318.8672 319.0068 319.1463 319.2859 319.4254 319.5649 319.7044 319.8439 319.9834 320.1229 320.2624 320.4018 320.5413 320.6807 320.8201 320.9595 321.0989 321.2383 321.3777 321.5170 321.6564 321.7957 321.9351 322.0744 322.2137 322.3530 322.4922 322.6315 322.7708 322.9100 323.0492 323.1885 323.3277 323.4669 323.6061 323.7452 323.8844 324.0235 324.1627 324.3018 324.4409 324.5800 324.7191 324.8582 324.9973
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250413T143236.1Z 9234.605973 350 1 8.02 2 44.32 125.68 136.75 295.63 0.00 1 0.00 1 0 17 9.742e-03 6.128e-03 4.463e-03 2.088e-03 2.505722e-01 1.113665e-03 3.041461e-03 -6.000000e+00 5.890290e-03 228.43 -2.00 3.51 -2.00 316.29 0.00e+00 2.317847e-04 1.249519e-04 4.700553e-05 -6.000000e+00 2.564597e-04 280.13 -2.00 20.00 -2.00 315.66 0.00e+00 1.396 0.000 302.00 328.00 3 4.2929e+00 2.8932e-03 1.9189e-02 -6.0000e+00 1.4657e-02 3.2964e-02 3.2183e-03 1.2876e-02 -6.0000e+00 1.5843e-02 -6.4298e-03 1.8690e-03 6.3447e-03 -6.0000e+00 9.4189e-03 -1.3866e-03 8.7326e-04 1.7847e-03 -6.0000e+00 4.0033e-03 1.2832e-03 -1.9864e-04 6.5426e-05 2.4508e-05 -6.0000e+00 3.0049e-04 1.3636e-02 -2.8952e-05 12 1 1 12 1 1 98.51 22.07 0.18 0.01364 0.01214 9 14 1 5 0 800.700 26.73 20.00 22.07 13.50 22.2 967.71 -1929 -3141 -1714 -4552 -2734 -499 1492 -979 -1478 -1934 -197 1679 1076 311 698 -1476 580 -491 845 221 1158 1189 833 1459 65 591 -955 158 1152 1096 1515 -1047 249 -2067 -850 -1327 373 -160 -652 -383 -1082 -1006 -927 -1038 -451 352 -1081 -132 363 821 1745 671 947 728 1328 821 178 82 414 942 1002 1567 1004 294 -574 -270 563 606 1066 118 -268 61 -10 46 -566 3 -71 -28 315 -965 -1244 -2064 -1692 -1536 -742 -572 -303 -197 87 125 376 421 673 1021 624 587 680 28 -346 -491 -561 -140 219 -146 -842 -746 -281 -306 8 128 81 -51 222 -22 398 777 915 522 -116 -289 -202 169 126 305 277 569 938 964 159 102 -173 -296 85 -6 -86 -354 -31 180 -129 -268 -252 -524 900000 -357 -612 -320 -800 -440 -80 254 -189 -306 -410 -42 375 261 86 205 -472 189 -168 293 79 412 427 312 547 26 235 -371 59 412 400 586 -428 105 -872 -357 -561 175 -86 -382 -250 -733 -705 -660 -740 -319 243 -739 -87 246 550 1227 489 724 562 1044 659 144 66 328 752 840 1362 908 274 -517 -233 473 517 959 115 -270 63 -10 45 -526 2 -59 -23 270 -908 -1226 -2162 -1869 -1746 -871 -692 -381 -244 108 151 428 450 696 1060 679 686 832 36 -458 -627 -686 -164 259 -177 -1072 -972 -372 -424 11 187 119 -76 321 -31 520 999 1192 702 -164 -415 -293 240 177 418 369 721 1185 1221 210 139 -246 -421 123 -9 -132 -555 -50 291 -208 -420 -389 -807 900000
SS 20250413T143652.2Z 9234.608937 354 1 2.55 2 43.67 126.87 137.45 296.66 0.00 1 0.00 1 0 17 9.995e-03 6.732e-03 4.081e-03 2.123e-03 2.455563e-01 1.135578e-03 3.014083e-03 -6.000000e+00 6.042181e-03 228.43 -2.00 3.51 -2.00 315.99 0.00e+00 9.184598e-05 1.192759e-04 4.196019e-05 -6.000000e+00 2.631585e-04 280.13 -2.00 20.00 -2.00 315.38 0.00e+00 1.381 0.000 302.00 328.00 3 3.2927e+00 2.9407e-03 1.8928e-02 -6.0000e+00 1.5035e-02 1.8990e-02 3.2674e-03 1.2670e-02 -6.0000e+00 1.6253e-02 -4.9613e-03 1.8855e-03 6.2493e-03 -6.0000e+00 9.6625e-03 -4.0041e-05 8.6739e-04 1.7509e-03 -6.0000e+00 4.1056e-03 3.5956e-03 -3.5459e-04 6.6313e-05 2.4731e-05 -6.0000e+00 3.0832e-04 1.5315e-02 -3.4624e-05 12 9 1 12 1 1 62.80 22.07 0.18 0.01532 0.01265 8 39 1 5 0 282.180 26.73 20.00 22.07 13.98 22.6 973.12 -1905 -3415 -2319 -5072 -550 -1383 368 1195 -1399 -2059 -1894 1033 830 813 -884 101 933 -164 1056 224 1040 838 1837 -276 429 -135 -1081 -25 1167 1041 589 1815 59 -2091 -1647 -696 89 -299 -543 -777 -598 -610 -795 -239 -188 -90 -601 -727 51 748 1394 624 1078 813 680 421 455 130 703 899 1251 1405 1347 781 -1024 -127 114 765 1196 -83 -589 -403 51 136 -656 92 527 185 294 -977 -1320 -1911 -1910 -1052 -1186 -736 -318 -530 -174 -75 -39 435 1116 1302 799 722 508 187 -505 -803 -257 -178 479 -72 -832 -937 -253 -674 136 279 194 18 146 677 458 886 515 167 -121 -607 -597 165 482 454 499 457 1044 1267 451 -100 -130 -25 356 124 -171 -254 -189 -97 -373 -458 -371 -283 900000 -418 -735 -516 -1061 -103 -264 75 267 -319 -482 -448 255 231 256 -293 35 334 -62 404 88 409 334 752 -114 182 -58 -453 -11 460 419 253 823 27 -945 -717 -313 45 -167 -337 -513 -420 -443 -588 -176 -137 -65 -425 -503 35 520 1020 463 838 659 564 356 387 110 583 755 1048 1263 1232 733 -938 -112 96 651 1107 -82 -595 -414 51 135 -601 80 441 155 252 -904 -1299 -2049 -2077 -1202 -1392 -877 -393 -666 -214 -90 -45 478 1146 1344 890 851 611 243 -649 -1035 -320 -208 570 -87 -1043 -1236 -335 -903 190 397 285 26 208 920 601 1118 662 218 -169 -860 -853 229 672 604 653 570 1314 1637 600 -136 -184 -34 508 179 -261 -390 -297 -155 -592 -706 -572 -423 900000
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