File name: Pandora51s1_OldFieldNY_20250815_L2Fit_fwvt1c5d20211018p1-8.txt
File generation date: 20250820T144723.7Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 51
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora51_OF_v5d20190801.txt
Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt
Level 1 file used: Pandora51s1_OldFieldNY_20250815_L1_smca1c5d20211018p1-8.txt
Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044)
Short location name: OldFieldNY
Country of location: USA
Location latitude [deg]: 40.9635
Location longitude [deg]: -73.1402
Location altitude [m]: 3
Local noon date: 20250815
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO
First and last pixel inside fitting window: 1681 1831
Nominal wavelengths inside fitting window [nm]: 492.1009 492.2214 492.3419 492.4623 492.5828 492.7032 492.8236 492.9440 493.0643 493.1847 493.3050 493.4253 493.5456 493.6659 493.7862 493.9064 494.0266 494.1468 494.2670 494.3872 494.5074 494.6275 494.7476 494.8677 494.9878 495.1079 495.2280 495.3480 495.4680 495.5880 495.7080 495.8280 495.9479 496.0679 496.1878 496.3077 496.4276 496.5474 496.6673 496.7871 496.9069 497.0267 497.1465 497.2663 497.3860 497.5057 497.6254 497.7451 497.8648 497.9845 498.1041 498.2237 498.3433 498.4629 498.5825 498.7021 498.8216 498.9411 499.0606 499.1801 499.2996 499.4190 499.5385 499.6579 499.7773 499.8967 500.0160 500.1354 500.2547 500.3740 500.4933 500.6126 500.7318 500.8511 500.9703 501.0895 501.2087 501.3279 501.4470 501.5662 501.6853 501.8044 501.9235 502.0426 502.1616 502.2806 502.3997 502.5187 502.6376 502.7566 502.8755 502.9945 503.1134 503.2323 503.3512 503.4700 503.5889 503.7077 503.8265 503.9453 504.0641 504.1828 504.3016 504.4203 504.5390 504.6577 504.7763 504.8950 505.0136 505.1322 505.2508 505.3694 505.4880 505.6065 505.7250 505.8436 505.9620 506.0805 506.1990 506.3174 506.4358 506.5542 506.6726 506.7910 506.9094 507.0277 507.1460 507.2643 507.3826 507.5009 507.6191 507.7373 507.8555 507.9737 508.0919 508.2101 508.3282 508.4463 508.5645 508.6825 508.8006 508.9187 509.0367 509.1547 509.2727 509.3907 509.5087 509.6266 509.7445 509.8625 509.9804
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250815T110351.7Z 9358.461015 200 1 49.02 2 79.68 80.51 26.56 221.01 0.00 1 0.00 1 0 15 3.526e-03 3.495e-03 8.752e-04 8.731e-04 8.689140e+03 5.900346e+01 5.678382e+02 -6.000000e+00 1.979011e+02 290.25 -2.00 20.00 -2.00 505.33 0.00e+00 1.009124e-03 2.425560e-05 7.002476e-05 -6.000000e+00 9.977984e-05 290.25 -2.00 20.00 -2.00 500.63 0.00e+00 4.351028e-01 1.699126e-02 5.751325e-02 -6.000000e+00 6.888631e-02 231.83 -2.00 3.51 -2.00 502.19 0.00e+00 5.352 0.003 489.00 513.00 1 6.8854e+00 1.3051e-03 9.2262e-03 -6.0000e+00 5.2928e-03 -2.0677e-02 3.3223e-04 1.4262e-03 -6.0000e+00 1.3709e-03 8.7884e-04 1.1948e-04 7.9242e-05 5.8391e-05 -6.0000e+00 3.3758e-04 7.6959e-03 2.7777e-05 10 0 0 10 0 0 99.94 22.18 1.40 0.00770 0.00852 28 6 1 4 0 1750.100 26.83 20.02 22.18 27.71 24.6 1046.84 -812 -412 -176 368 525 705 773 556 547 382 400 -29 -215 -375 -242 -83 33 -45 -84 140 -17 356 237 97 375 348 154 -158 -173 -440 -343 -111 -279 -316 -87 207 185 -86 -28 -51 -182 83 165 61 272 91 241 87 -71 -217 -811 -760 -499 -451 -299 -276 -74 183 450 273 463 509 343 369 299 66 31 -67 -539 -377 -384 -331 -203 -314 -363 -268 -110 -307 -355 -456 -624 -633 -419 -391 -123 -404 -254 103 -139 24 294 178 63 8 134 58 322 -135 -532 -583 -740 -266 -299 -379 -388 -281 -161 44 -11 -65 -105 61 251 251 665 767 703 608 410 268 121 277 201 238 178 107 181 193 256 920 -351 -199 -163 -127 -66 -165 -84 162 199 323 478 270 230 271 179 178 -291 -486 -424 -332 -447 -759 -392 -174 374 513 702 782 567 554 382 395 -28 -207 -358 -231 -80 33 -45 -87 145 -18 369 247 101 393 365 161 -163 -173 -428 -332 -108 -278 -327 -92 219 194 -90 -29 -52 -187 85 172 65 290 98 256 91 -73 -218 -794 -728 -474 -434 -296 -282 -77 192 470 285 483 534 362 389 313 68 31 -68 -538 -370 -375 -325 -202 -316 -368 -270 -108 -298 -342 -437 -602 -616 -411 -387 -123 -409 -257 103 -140 24 282 173 62 8 129 58 310 -127 -490 -529 -673 -245 -287 -359 -381 -278 -159 42 -11 -63 -103 61 251 253 672 778 720 628 424 274 121 273 196 233 175 106 180 192 253 903 -346 -193 -156 -120 -63 -158 -82 162 202 332 495 283 230 271 179 177 -287 -496 -424 -331 -448
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SQ 20250815T112149.7Z 9358.473491 209 1 6.31 2 76.33 83.35 28.85 228.44 0.00 1 0.00 1 0 15 2.538e-03 2.532e-03 9.084e-05 9.072e-05 6.909363e+03 5.935010e+00 4.640108e+02 -6.000000e+00 1.424179e+02 290.25 -2.00 20.00 -2.00 505.31 0.00e+00 8.151146e-04 2.522691e-06 5.763386e-05 -6.000000e+00 7.180924e-05 290.25 -2.00 20.00 -2.00 500.62 0.00e+00 3.048291e-01 1.759655e-03 4.504746e-02 -6.000000e+00 4.959769e-02 231.83 -2.00 3.51 -2.00 502.19 0.00e+00 4.129 0.001 489.00 513.00 1 7.2986e-01 1.3500e-04 7.1712e-03 -6.0000e+00 3.8105e-03 -1.9613e-02 3.4555e-05 1.1253e-03 -6.0000e+00 9.8756e-04 5.0092e-01 6.3722e-04 8.2765e-06 5.0180e-05 -6.0000e+00 2.4303e-04 1.1756e-02 -3.0006e-05 10 0 0 10 0 0 0.43 22.17 1.31 0.01176 0.01618 1099 249 1 4 0 5.280 26.83 19.98 22.17 27.80 24.9 1048.72 -215 -183 -26 403 512 592 553 456 478 379 212 49 -217 -288 -178 80 67 -135 -72 29 102 212 205 154 215 290 96 -184 -120 -253 -104 91 -48 -249 -117 76 -1 -57 -85 -109 -151 1 62 82 68 95 90 -25 -223 -342 -519 -500 -336 -296 -283 -309 -162 16 178 279 216 176 183 126 96 122 57 -146 -225 -254 -286 -89 -51 -243 -312 -251 -133 -196 -308 -351 -456 -339 -171 -243 -257 -219 -193 -153 -152 -35 101 33 -35 62 131 169 159 -172 -430 -534 -469 -255 -313 -467 -363 -288 -165 -8 -38 -110 -96 -37 111 321 498 622 574 414 382 255 249 402 325 159 189 177 166 330 358 137 67 51 -27 7 49 -70 -65 62 183 171 160 192 241 223 128 -65 -185 -204 -196 -229 -216 -201 -175 -26 396 513 606 576 478 498 389 216 50 -214 -282 -174 79 67 -140 -76 30 104 217 210 158 222 300 98 -186 -122 -251 -102 90 -49 -253 -122 79 -1 -59 -85 -110 -152 1 63 85 72 99 94 -26 -225 -350 -516 -486 -325 -289 -285 -309 -165 16 183 284 221 181 189 130 98 123 57 -143 -219 -254 -284 -88 -50 -239 -310 -247 -128 -194 -301 -342 -447 -336 -163 -235 -252 -217 -191 -151 -150 -34 101 33 -36 64 132 166 152 -167 -407 -498 -437 -242 -296 -462 -357 -286 -162 -8 -38 -110 -94 -36 112 323 503 631 588 427 393 260 248 395 316 155 186 174 164 325 352 135 66 49 -27 7 48 -69 -63 61 184 175 165 192 242 226 130 -66 -184 -205 -194 -225 -213
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