File name: Pandora131s1_Palau_20220828_L2Fit_fout2c10d20220801p1-8.txt File generation date: 20250113T184043.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Juergen Fischer Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 131 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora131_OF_v2d20200610.txt Instrument calibration file used: Pandora131s1_CF_v10d20220801.txt Level 1 file used: Pandora131s1_Palau_20220828_L1_smca1c10d20220801p1-8.txt Full location name: Palau Atmospheric Observatory Short location name: Palau Country of location: Palau Location latitude [deg]: 7.3420 Location longitude [deg]: 134.4722 Location altitude [m]: 23 Local noon date: 20220828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0225 305.1636 305.3046 305.4457 305.5867 305.7277 305.8687 306.0097 306.1506 306.2916 306.4325 306.5735 306.7144 306.8553 306.9962 307.1371 307.2779 307.4188 307.5596 307.7005 307.8413 307.9821 308.1229 308.2637 308.4045 308.5452 308.6860 308.8267 308.9675 309.1082 309.2489 309.3896 309.5302 309.6709 309.8116 309.9522 310.0928 310.2334 310.3741 310.5146 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1836 313.3240 313.4643 313.6046 313.7449 313.8853 314.0255 314.1658 314.3061 314.4463 314.5866 314.7268 314.8670 315.0072 315.1474 315.2876 315.4278 315.5680 315.7081 315.8482 315.9884 316.1285 316.2686 316.4086 316.5487 316.6888 316.8288 316.9689 317.1089 317.2489 317.3889 317.5289 317.6689 317.8089 317.9488 318.0887 318.2287 318.3686 318.5085 318.6484 318.7883 318.9281 319.0680 319.2079 319.3477 319.4875 319.6273 319.7671 319.9069 320.0467 320.1864 320.3262 320.4659 320.6056 320.7454 320.8851 321.0248 321.1644 321.3041 321.4438 321.5834 321.7230 321.8626 322.0022 322.1418 322.2814 322.4210 322.5606 322.7001 322.8396 322.9792 323.1187 323.2582 323.3976 323.5371 323.6766 323.8160 323.9555 324.0949 324.2343 324.3737 324.5131 324.6525 324.7918 324.9312 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220827T214655.2Z 8274.907584 36 1 51.10 2 78.14 81.45 86.51 78.83 0.00 1 0.00 1 0 25 1.140e-01 4.319e-03 5.897e-02 1.439e-03 5.202415e-01 7.310053e-04 5.229763e-03 -6.000000e+00 6.283377e-02 227.82 -2.00 3.05 -2.00 320.73 0.00e+00 -3.295917e-04 3.119932e-04 5.824336e-04 -6.000000e+00 2.912947e-03 294.29 -2.00 20.00 -2.00 319.96 0.00e+00 4.710 0.000 302.00 328.00 3 5.0967e-01 2.4159e-03 5.2060e-02 -6.0000e+00 1.5572e-01 1.8094e-02 3.1779e-03 2.4211e-02 -6.0000e+00 1.6887e-01 1.5498e-02 2.8899e-03 1.1840e-02 -6.0000e+00 1.0127e-01 -1.5849e-02 1.4427e-03 3.5288e-03 -6.0000e+00 4.4032e-02 1.7463e-03 -3.5246e-04 3.8610e-05 3.1600e-05 -6.0000e+00 2.7415e-03 4.8508e-04 0.0000e+00 10 0 0 10 0 0 85.09 18.27 0.20 0.00049 -0.00216 332 72 2 8 0 148.090 20.00 18.27 35.33 26.32 26.21 13.7 985.61 -9212 -45331 15335 -66533 -24970 -65716 -45056 -16684 -32477 -19094 -23401 -14303 -24014 -5950 -11849 -569 -13977 -6390 -1375 -7736 888 -4908 251 -7421 -2149 -491 3920 -2446 -9129 -4299 -4181 -2161 -3794 -521 -5403 -6918 -3305 -3641 93 -1319 -198 217 512 -862 -722 188 -599 1498 -1110 751 -1456 54 -262 -93 548 40 783 565 173 -436 926 743 1339 2119 1679 691 -244 100 -70 956 275 212 96 299 496 56 13 -1005 -213 20 -399 -345 -1337 -1564 -854 -448 -89 287 533 1120 981 776 697 104 820 335 627 417 477 170 -332 -762 -966 -301 -772 -791 -1005 -822 -654 -132 243 187 383 183 -13 -351 -45 58 -220 -74 -172 -82 -75 388 402 645 -23 322 536 421 631 152 -225 -313 -105 0 -137 63 47 95 19 -173 -364 -47 -359 80 -713 -175 -595 -392 -129 -315 -180 -239 -141 -313 -81 -213 -11 -344 -159 -35 -226 25 -147 7 -258 -79 -19 151 -97 -368 -166 -183 -110 -228 -34 -351 -433 -215 -259 8 -141 -24 28 70 -122 -103 27 -88 218 -170 117 -254 10 -56 -21 133 10 208 151 45 -112 238 208 421 744 631 252 -85 35 -26 416 135 111 50 149 229 23 5 -370 -84 9 -217 -214 -921 -1137 -658 -370 -78 260 483 980 801 586 490 73 624 294 628 477 603 218 -402 -829 -953 -297 -841 -919 -1221 -1054 -900 -201 374 304 619 283 -20 -516 -66 89 -360 -119 -279 -140 -122 614 610 939 -32 447 830 735 1105 280 -430 -633 -228 0 -323 150 113 224 43 -364 -735 SS 20220827T215351.1Z 8274.912397 39 1 51.17 2 76.44 81.62 84.88 79.04 0.00 1 0.00 1 0 25 6.087e-02 4.613e-03 2.403e-02 9.508e-04 4.648916e-01 4.772769e-04 4.714427e-03 -6.000000e+00 3.356184e-02 227.82 -2.00 3.05 -2.00 320.29 0.00e+00 2.287670e-04 1.753216e-04 4.662037e-04 -6.000000e+00 1.555882e-03 294.29 -2.00 20.00 -2.00 319.46 0.00e+00 4.160 0.000 302.00 328.00 3 4.0878e-01 1.4839e-03 4.6101e-02 -6.0000e+00 8.3173e-02 2.1019e-02 1.8629e-03 2.1563e-02 -6.0000e+00 9.0197e-02 1.3086e-02 1.5758e-03 1.0478e-02 -6.0000e+00 5.4089e-02 -1.4461e-02 8.1085e-04 3.2119e-03 -6.0000e+00 2.3521e-02 3.4333e-03 -2.6383e-04 2.5628e-05 2.8246e-05 -6.0000e+00 1.4642e-03 4.3589e-05 0.0000e+00 10 0 0 10 0 0 16.29 18.28 0.17 0.00004 -0.00194 498 109 2 8 0 98.770 20.00 18.28 36.24 26.32 26.21 13.8 991.43 -32785 -14182 -20211 -31465 -12292 -28659 -2599 -19425 2940 -15180 -4207 -11611 -14014 546 -10554 2655 -9056 -1109 -7625 -602 134 -3042 -2450 -2885 696 -4981 666 -887 -1198 -1983 -658 1549 118 1765 -3209 -2197 -5838 -479 -1824 86 -488 -743 -714 -1245 346 -1644 315 -780 -960 -96 -621 1080 -371 737 -36 773 319 1000 416 240 1131 415 1783 1791 1558 542 -635 -573 -238 720 351 469 -54 678 400 -99 -101 -785 -425 -337 -27 -745 -1141 -1641 -1199 -619 -227 422 492 1093 927 929 331 566 575 548 552 572 679 207 -191 -848 -1082 -777 -790 -683 -895 -718 -651 -4 141 252 336 150 -192 -263 -28 -145 -140 -88 -206 -149 -68 299 435 700 125 500 458 624 515 163 -198 -171 -99 -51 -58 19 53 97 -12 -246 -390 -370 -158 -259 -448 -130 -333 -27 -255 36 -247 -63 -194 -284 12 -313 82 -346 -42 -334 -26 6 -141 -115 -148 38 -310 40 -52 -67 -111 -41 110 10 144 -286 -183 -542 -50 -220 12 -80 -132 -133 -238 65 -322 61 -153 -192 -20 -138 263 -100 211 -11 243 105 329 134 76 359 144 685 768 708 237 -263 -234 -104 365 200 282 -33 391 215 -48 -44 -361 -190 -177 -16 -518 -872 -1322 -1026 -568 -220 423 494 1061 840 774 256 428 473 514 589 692 834 258 -243 -972 -1131 -819 -914 -842 -1155 -974 -871 -6 225 423 556 236 -281 -392 -42 -207 -213 -144 -341 -239 -106 447 674 1039 175 702 713 1000 895 297 -372 -338 -209 -114 -134 42 116 223 -26 -509 -778 SS 20220827T215925.0Z 8274.916261 41 1 51.35 2 75.07 81.75 83.56 79.20 0.00 1 0.00 1 0 25 3.420e-02 4.612e-03 1.345e-02 7.458e-04 4.280004e-01 3.725078e-04 4.406674e-03 -6.000000e+00 1.885505e-02 227.82 -2.00 3.05 -2.00 319.94 0.00e+00 1.967644e-06 1.217402e-04 4.482132e-04 -6.000000e+00 8.740861e-04 294.29 -2.00 20.00 -2.00 319.07 0.00e+00 3.804 0.000 302.00 328.00 3 3.8957e-01 1.1165e-03 4.2258e-02 -6.0000e+00 4.6727e-02 1.9386e-02 1.3658e-03 1.9886e-02 -6.0000e+00 5.0672e-02 9.9906e-03 1.0941e-03 9.6185e-03 -6.0000e+00 3.0387e-02 -1.1790e-02 5.7152e-04 2.8133e-03 -6.0000e+00 1.3214e-02 5.1279e-03 -1.8901e-04 2.0179e-05 2.6972e-05 -6.0000e+00 8.2259e-04 -1.4854e-04 0.0000e+00 10 0 0 10 0 0 4.69 18.28 0.16 -0.00015 -0.00157 616 134 2 8 0 79.720 20.00 18.28 37.06 26.32 26.21 13.8 996.30 -15231 -4281 -13301 -7912 -12239 -13642 -11823 -14325 -946 -10889 -8089 -9229 -4152 -5212 -1589 -623 -2508 1268 -3434 155 -797 893 -2578 12 -1698 -444 -753 -2585 -451 -2092 115 -173 999 -126 -1877 -2360 -2916 -871 -1419 -169 -751 -857 -770 -1189 -417 -897 -35 -800 -621 -1125 214 449 476 704 282 773 470 905 190 550 646 786 1169 1721 1196 130 -83 -772 136 571 609 222 1 379 138 91 -312 -688 -336 -288 -242 -732 -1088 -1631 -1014 -695 -3 169 613 940 1028 875 339 585 575 642 514 592 666 106 -281 -935 -961 -693 -486 -783 -999 -797 -567 -61 35 254 199 192 -111 -216 -127 -75 -114 -171 -148 -187 -54 227 486 649 288 418 562 659 602 294 -171 -160 -138 -79 -128 53 86 27 -2 -241 -426 -227 -67 -245 -137 -197 -207 -187 -270 -18 -254 -187 -222 -111 -172 -61 -28 -125 65 -181 8 -45 54 -164 1 -117 -32 -56 -206 -33 -154 9 -16 95 -13 -190 -247 -329 -104 -212 -30 -153 -187 -175 -278 -97 -212 -8 -189 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