File name: Pandora131s1_Palau_20220828_L2Fit_fwvt1c10d20220801p1-8.txt File generation date: 20250113T184407.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Juergen Fischer Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 131 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora131_OF_v2d20200610.txt Instrument calibration file used: Pandora131s1_CF_v10d20220801.txt Level 1 file used: Pandora131s1_Palau_20220828_L1_smca1c10d20220801p1-8.txt Full location name: Palau Atmospheric Observatory Short location name: Palau Country of location: Palau Location latitude [deg]: 7.3420 Location longitude [deg]: 134.4722 Location altitude [m]: 23 Local noon date: 20220828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1797 Nominal wavelengths inside fitting window [nm]: 492.1164 492.2376 492.3587 492.4799 492.6010 492.7221 492.8432 492.9643 493.0854 493.2064 493.3274 493.4484 493.5694 493.6904 493.8114 493.9323 494.0533 494.1742 494.2951 494.4159 494.5368 494.6576 494.7785 494.8993 495.0201 495.1408 495.2616 495.3823 495.5031 495.6238 495.7445 495.8651 495.9858 496.1064 496.2271 496.3477 496.4683 496.5888 496.7094 496.8299 496.9505 497.0710 497.1914 497.3119 497.4324 497.5528 497.6732 497.7936 497.9140 498.0344 498.1547 498.2751 498.3954 498.5157 498.6360 498.7562 498.8765 498.9967 499.1169 499.2371 499.3573 499.4775 499.5976 499.7178 499.8379 499.9580 500.0781 500.1981 500.3182 500.4382 500.5582 500.6782 500.7982 500.9181 501.0381 501.1580 501.2779 501.3978 501.5177 501.6375 501.7574 501.8772 501.9970 502.1168 502.2366 502.3563 502.4761 502.5958 502.7155 502.8352 502.9548 503.0745 503.1941 503.3138 503.4334 503.5529 503.6725 503.7921 503.9116 504.0311 504.1506 504.2701 504.3895 504.5090 504.6284 504.7478 504.8672 504.9866 505.1060 505.2253 505.3446 505.4640 505.5832 505.7025 505.8218 505.9410 506.0602 506.1794 506.2986 506.4178 506.5370 506.6561 506.7752 506.8943 507.0134 507.1325 507.2515 507.3706 507.4896 507.6086 507.7276 507.8465 507.9655 508.0844 508.2033 508.3222 508.4411 508.5600 508.6788 508.7976 508.9164 509.0352 509.1540 509.2728 509.3915 509.5102 509.6289 509.7476 509.8663 509.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [�C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [�C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [�C], 999=no temperature signal Column 97: Temperature in head sensor [�C], 999=no temperature signal Column 98: Temperature at electronics board 1 [�C], 999=no temperature signal Column 99: Temperature at electronics board 2 [�C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220827T214130.3Z 8274.903822 34 1 5.92 2 79.46 81.32 87.79 78.65 0.00 1 0.00 1 0 22 2.890e-03 2.863e-03 1.100e-04 1.097e-04 1.517047e+04 8.074712e+00 9.786362e+02 -6.000000e+00 1.650367e+02 294.29 -2.00 20.00 -2.00 505.32 0.00e+00 7.029227e-04 3.093860e-06 6.950020e-05 -6.000000e+00 8.293422e-05 294.29 -2.00 20.00 -2.00 500.47 0.00e+00 5.368285e-01 2.146188e-03 8.135475e-02 -6.000000e+00 5.626023e-02 227.82 -2.00 3.05 -2.00 502.06 0.00e+00 5.251 0.000 489.00 513.00 1 4.8643e-01 1.6492e-04 1.0329e-02 -6.0000e+00 4.3314e-03 4.1276e-03 4.1853e-05 2.0727e-03 -6.0000e+00 1.1208e-03 5.3176e-01 2.3987e-04 9.3241e-06 8.1146e-05 -6.0000e+00 2.7317e-04 1.1166e-03 -1.7589e-05 10 0 0 10 0 0 -3.16 18.27 1.34 0.00112 0.00278 760 218 2 2 0 7.460 20.00 18.27 34.92 26.21 26.11 13.6 981.28 -420 -262 81 183 271 580 584 502 385 181 136 12 -124 -74 -218 -160 -19 281 270 95 152 221 239 363 272 125 179 68 -270 -465 -457 -505 -69 238 50 -44 -41 -191 -287 -206 -151 -67 107 185 195 220 146 40 -146 -330 -617 -710 -796 -458 -125 -17 93 167 80 127 277 360 348 361 190 91 -159 -211 -318 -440 -374 -467 -260 57 65 -69 -188 -177 -178 -269 -188 -127 -139 -120 -316 -438 -132 -165 -173 -90 0 275 429 327 286 103 -37 -45 -428 -745 -689 -616 -176 6 -32 -38 -147 -269 -153 -92 -93 70 184 259 342 535 650 457 279 103 -10 -91 159 267 161 173 140 15 264 297 -21 -37 -92 -238 62 233 127 165 339 124 153 207 193 166 273 137 -168 -413 -457 -386 -407 -261 80 187 282 593 605 523 399 185 142 12 -127 -75 -220 -163 -20 288 282 101 160 234 253 385 290 133 189 71 -273 -475 -462 -518 -70 250 52 -45 -44 -200 -298 -213 -156 -70 113 190 202 227 149 41 -149 -329 -623 -702 -787 -460 -124 -17 97 174 84 132 288 363 352 377 196 93 -159 -208 -311 -426 -360 -454 -256 56 65 -68 -181 -173 -174 -261 -183 -120 -133 -116 -310 -433 -130 -161 -168 -88 0 273 424 318 269 97 -34 -40 -390 -676 -634 -565 -170 6 -32 -38 -146 -264 -150 -91 -94 68 179 252 334 527 649 459 279 102 -10 -89 154 261 159 170 138 15 259 290 -20 -36 -87 -225 59 227 122 160 334 125 155 211 197 169 276 137 -166 -400 -439 -373 SQ 20220827T214136.8Z 8274.903898 34 2 6.33 2 79.44 81.32 87.77 78.66 0.00 1 0.00 1 0 22 2.913e-03 2.880e-03 1.099e-04 1.096e-04 1.515782e+04 8.071605e+00 9.738722e+02 -6.000000e+00 1.663526e+02 294.29 -2.00 20.00 -2.00 505.32 0.00e+00 6.993887e-04 3.090224e-06 6.955487e-05 -6.000000e+00 8.359547e-05 294.29 -2.00 20.00 -2.00 500.46 0.00e+00 5.340742e-01 2.144243e-03 8.120737e-02 -6.000000e+00 5.670883e-02 227.82 -2.00 3.05 -2.00 502.06 0.00e+00 5.239 0.000 489.00 513.00 1 4.8429e-01 1.6478e-04 1.0307e-02 -6.0000e+00 4.3659e-03 4.1260e-03 4.1832e-05 2.0626e-03 -6.0000e+00 1.1297e-03 5.3396e-01 2.4940e-04 9.3517e-06 7.7834e-05 -6.0000e+00 2.7535e-04 9.5306e-04 -1.6605e-05 10 0 0 10 0 0 -7.65 18.27 1.34 0.00095 0.00268 760 218 2 2 0 7.460 20.00 18.27 34.92 26.21 26.11 13.6 981.96 -418 -264 95 183 296 544 571 507 385 174 140 20 -116 -84 -216 -137 -9 277 261 79 181 207 250 345 257 122 171 73 -253 -476 -486 -507 -89 253 36 -36 -47 -187 -295 -223 -146 -88 143 171 234 238 157 52 -151 -333 -599 -710 -821 -491 -129 -14 56 180 99 129 270 367 357 345 170 95 -172 -202 -319 -460 -385 -453 -256 55 75 -65 -162 -181 -179 -264 -210 -138 -146 -115 -334 -442 -158 -170 -163 -98 5 290 405 332 263 115 -37 -65 -452 -749 -676 -632 -190 11 -44 -38 -167 -283 -145 -79 -95 87 195 266 368 546 651 453 292 125 19 -84 138 281 154 167 121 -4 249 306 -14 -47 -77 -248 65 239 132 170 346 130 144 212 201 182 231 156 -155 -399 -468 -407 -406 -263 94 187 309 558 594 530 401 179 142 20 -119 -85 -219 -140 -9 285 274 84 192 219 265 367 275 130 182 76 -256 -488 -493 -503 -91 266 37 -37 -50 -197 -306 -231 -152 -92 152 177 243 247 161 55 -155 -333 -584 -704 -814 -476 -129 -15 58 188 103 134 282 371 362 348 176 97 -173 -200 -313 -447 -373 -442 -253 54 75 -64 -156 -178 -175 -257 -205 -131 -140 -112 -329 -438 -156 -167 -159 -96 5 288 402 323 247 108 -34 -58 -414 -682 -599 -582 -177 11 -44 -38 -166 -278 -143 -78 -92 85 191 260 360 539 652 457 292 123 18 -83 134 276 152 165 120 -4 245 300 -14 -45 -73 -234 63 234 127 166 343 131 146 216 199 180 235 157 -153 -387 -451 -395 SQ 20220827T214143.3Z 8274.903973 34 3 6.18 2 79.41 81.32 87.74 78.66 0.00 1 0.00 1 0 22 2.909e-03 2.879e-03 1.097e-04 1.094e-04 1.513528e+04 8.045992e+00 9.728588e+02 -6.000000e+00 1.660986e+02 294.29 -2.00 20.00 -2.00 505.31 0.00e+00 6.978536e-04 3.083461e-06 6.949309e-05 -6.000000e+00 8.346831e-05 294.29 -2.00 20.00 -2.00 500.46 0.00e+00 5.305309e-01 2.137861e-03 8.107731e-02 -6.000000e+00 5.662462e-02 227.82 -2.00 3.05 -2.00 502.05 0.00e+00 5.227 0.000 489.00 513.00 1 4.8247e-01 1.6430e-04 1.0288e-02 -6.0000e+00 4.3594e-03 4.1868e-03 4.1710e-05 2.0601e-03 -6.0000e+00 1.1281e-03 5.3601e-01 3.1053e-04 9.3230e-06 7.7623e-05 -6.0000e+00 2.7494e-04 1.0332e-03 -1.9505e-05 10 0 0 10 0 0 -12.58 18.27 1.34 0.00103 0.00319 760 218 2 2 0 7.460 20.00 18.27 34.92 26.21 26.11 13.6 981.96 -416 -253 69 191 299 551 598 513 395 161 114 5 -126 -67 -223 -144 -4 289 244 88 162 210 248 356 253 119 172 81 -258 -485 -492 -500 -87 253 69 -44 -36 -185 -303 -229 -171 -64 138 182 222 236 146 49 -147 -303 -595 -700 -835 -502 -136 -23 72 158 115 115 280 381 350 347 162 71 -149 -220 -333 -433 -388 -461 -241 66 67 -72 -162 -184 -186 -250 -196 -129 -131 -108 -324 -430 -133 -163 -175 -97 -25 280 398 326 282 106 -69 -19 -446 -753 -677 -635 -177 -1 -41 -24 -162 -300 -146 -89 -92 99 214 270 337 537 630 462 290 111 -5 -78 150 267 158 192 120 5 265 308 -24 -34 -70 -255 45 207 108 179 369 120 157 230 192 180 242 146 -162 -406 -452 -391 -405 -252 69 195 313 566 623 537 411 166 116 5 -129 -68 -226 -147 -5 298 256 94 171 223 263 379 272 127 183 84 -262 -497 -500 -497 -89 267 71 -45 -38 -194 -316 -238 -178 -68 146 188 231 244 150 51 -152 -303 -580 -695 -828 -488 -136 -24 76 166 120 120 282 386 355 350 168 72 -150 -219 -327 -421 -376 -450 -239 66 67 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