File name: Pandora131s1_Palau_20221018_L2Fit_fwvt1c10d20220801p1-8.txt File generation date: 20250113T173142.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Katrin Mueller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 131 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora131_OF_v3d20200610.txt Instrument calibration file used: Pandora131s1_CF_v10d20220801.txt Level 1 file used: Pandora131s1_Palau_20221018_L1_smca1c10d20220801p1-8.txt Full location name: Palau Atmospheric Observatory Short location name: Palau Country of location: Palau Location latitude [deg]: 7.3420 Location longitude [deg]: 134.4722 Location altitude [m]: 23 Local noon date: 20221018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1797 Nominal wavelengths inside fitting window [nm]: 492.1164 492.2376 492.3587 492.4799 492.6010 492.7221 492.8432 492.9643 493.0854 493.2064 493.3274 493.4484 493.5694 493.6904 493.8114 493.9323 494.0533 494.1742 494.2951 494.4159 494.5368 494.6576 494.7785 494.8993 495.0201 495.1408 495.2616 495.3823 495.5031 495.6238 495.7445 495.8651 495.9858 496.1064 496.2271 496.3477 496.4683 496.5888 496.7094 496.8299 496.9505 497.0710 497.1914 497.3119 497.4324 497.5528 497.6732 497.7936 497.9140 498.0344 498.1547 498.2751 498.3954 498.5157 498.6360 498.7562 498.8765 498.9967 499.1169 499.2371 499.3573 499.4775 499.5976 499.7178 499.8379 499.9580 500.0781 500.1981 500.3182 500.4382 500.5582 500.6782 500.7982 500.9181 501.0381 501.1580 501.2779 501.3978 501.5177 501.6375 501.7574 501.8772 501.9970 502.1168 502.2366 502.3563 502.4761 502.5958 502.7155 502.8352 502.9548 503.0745 503.1941 503.3138 503.4334 503.5529 503.6725 503.7921 503.9116 504.0311 504.1506 504.2701 504.3895 504.5090 504.6284 504.7478 504.8672 504.9866 505.1060 505.2253 505.3446 505.4640 505.5832 505.7025 505.8218 505.9410 506.0602 506.1794 506.2986 506.4178 506.5370 506.6561 506.7752 506.8943 507.0134 507.1325 507.2515 507.3706 507.4896 507.6086 507.7276 507.8465 507.9655 508.0844 508.2033 508.3222 508.4411 508.5600 508.6788 508.7976 508.9164 509.0352 509.1540 509.2728 509.3915 509.5102 509.6289 509.7476 509.8663 509.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221017T205215.6Z 8325.869625 195 1 49.95 2 90.02 99.56 19.47 14.54 0.00 1 0.00 1 0 22 1.812e-01 1.557e-01 7.006e-02 6.508e-02 2.854773e+04 5.632499e+03 1.854207e+03 -6.000000e+00 1.033783e+04 294.40 -2.00 20.00 -2.00 505.36 0.00e+00 3.013823e-03 1.853957e-03 9.695750e-05 -6.000000e+00 5.198829e-03 294.40 -2.00 20.00 -2.00 500.02 0.00e+00 4.668201e-01 1.314333e+00 9.223957e-02 -6.000000e+00 3.546299e+00 228.22 -2.00 3.05 -2.00 501.63 0.00e+00 20.183 0.006 489.00 513.00 1 9.0509e+00 1.0076e-01 2.9957e-02 -6.0000e+00 2.7266e-01 1.3209e-01 2.5813e-02 3.2714e-03 -6.0000e+00 7.1158e-02 1.1259e-05 -7.4311e-03 5.1547e-03 1.1550e-04 -6.0000e+00 1.7171e-02 3.8394e-01 -2.7759e-03 12 9 9 12 4 4 99.89 41.45 49.13 0.38394 0.33239 40 9 1 2 0 1241.090 47.02 41.45 34.60 50.75 50.75 20.6 1003.35 -8502 984 28942 14789 6079 -18519 -553 -28690 -1771 -6156 20020 -7022 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-6679 6123 1398 -5673 6733 22637 13169 13492 -6636 -7959 23751 18616 -7778 -30952 -39457 -1404 13190 -5163 21159 13015 -19905 22845 -23419 8121 4384 8600 -15594 11006 22243 22005 -6069 -5433 29481 -6240 2604 9175 -6688 -17618 24717 -9984 -1556 11263 6708 13722 13018 -12389 1574 4560 -2534 16175 22921 24826 21297 -15675 -11737 -10278 18612 -8487 15276 23385 19240 -23949 -542 9934 24343 -1171 -10291 -4320 -16562 17647 21393 1002 -10556 22114 742 -2254 3778 13389 -8558 12762 -28494 -18629 11118 -4884 1599 12178 6529 -2069 15842 -15869 -6004 -15357 -17275 -22303 11816 -2804 16825 -9987 25797 9895 8848 8175 1594 -12242 13063 -697 13579 -4615 -21079 -22133 30885 14 6326 -13930 4512 9615 10391 -15390 -5305 32898 SQ 20221017T205853.8Z 8325.874234 201 1 49.21 2 88.40 99.78 19.11 10.23 0.00 1 0.00 1 0 15 6.075e-02 5.865e-02 2.379e-02 2.340e-02 1.142466e+04 1.774572e+03 7.973482e+02 -6.000000e+00 3.469933e+03 294.40 -2.00 20.00 -2.00 505.32 0.00e+00 3.418924e-03 6.608979e-04 2.500102e-04 -6.000000e+00 1.743963e-03 294.40 -2.00 20.00 -2.00 500.14 0.00e+00 2.220659e+00 4.719563e-01 6.136147e-02 -6.000000e+00 1.187220e+00 228.22 -2.00 3.05 -2.00 501.77 0.00e+00 16.972 0.004 489.00 513.00 1 8.3603e+00 3.6345e-02 2.5350e-02 -6.0000e+00 9.1334e-02 8.2589e-02 9.1790e-03 1.9395e-03 -6.0000e+00 2.3743e-02 3.2772e-05 7.3585e-04 2.0756e-03 1.0235e-04 -6.0000e+00 5.7560e-03 8.1269e-02 -7.4740e-04 12 9 9 12 12 4 99.83 41.45 7.47 0.08127 0.08637 37 8 1 2 0 1329.770 47.02 41.45 34.61 50.75 50.75 20.4 1003.37 -2042 3565 3751 1785 6400 -390 -5778 2016 10036 -6225 1342 -551 1358 -450 3686 -8648 1731 -1032 -464 5645 1278 5311 397 -6027 -11092 -1510 -1225 -5748 8619 2092 1438 -5662 -1022 -367 -4202 2801 3562 7014 1431 767 1162 949 242 -2955 5934 -4799 7013 -9248 3781 5564 7979 -1094 15157 -410 388 2235 -6067 4324 -8709 4875 -3299 10477 7561 -3812 8597 -5153 2217 -5612 -8824 -4851 -13896 -2978 5556 2190 -3184 5869 -5812 8350 5601 260 -797 -4315 13882 -182 -2337 -1623 3271 -2489 6131 -646 10534 4529 -2159 -7733 -413 5444 -5850 18164 -9221 4557 5133 -235 10435 -14514 -162 -7496 4338 3175 11791 -5319 -1733 4627 -1633 608 -3432 5193 805 418 10465 -5708 854 -3348 -980 -7321 4399 -5650 2282 7151 1879 -109 -5107 4607 -7036 15027 -11739 4266 -1178 3844 -696 -4420 3974 16645 5250 498 5608 -2475 -4504 -9599 3121 840 -1986 3364 3655 1829 6423 -426 -6746 2194 10058 -7178 1415 -583 1390 -463 3630 -9643 1778 -1116 -509 5883 1388 5545 436 -7066 -13714 -1702 -1369 -6599 8383 2098 1430 -6081 -1081 -399 -4837 3017 3767 7084 1508 810 1226 1013 263 -3357 6234 -5591 7235 -10983 3882 5465 7442 -1088 12816 -409 395 2303 -6881 4458 -10143 4971 -3644 10191 7574 -4240 8390 -5638 2221 -5975 -9562 -4993 -15475 -2995 5203 2144 -3287 5478 -5938 7315 4986 243 -752 -4228 11498 -174 -2301 -1592 3045 -2424 5448 -614 9053 4176 -2136 -7978 -386 4662 -5427 13113 -8488 3623 4066 -201 8399 -15476 -154 -7658 3915 2862 9767 -5246 -1677 4266 -1610 588 -3468 4868 796 417 9412 -5892 811 -3258 -929 -7417 4006 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