File name: Pandora131s1_Palau_20231112_L2Fit_fout2c11d20221208p1-8.txt File generation date: 20231112T155046.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Katrin Mueller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 131 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora131_OF_v3d20200610.txt Instrument calibration file used: Pandora131s1_CF_v11d20221208.txt Level 1 file used: Pandora131s1_Palau_20231112_L1_smca1c11d20221208p1-8.txt Full location name: Palau Atmospheric Observatory Short location name: Palau Country of location: Palau Location latitude [deg]: 7.3420 Location longitude [deg]: 134.4722 Location altitude [m]: 23 Local noon date: 20231112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: 1st VP, year 2023 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0440 305.1849 305.3259 305.4668 305.6077 305.7486 305.8895 306.0303 306.1712 306.3121 306.4529 306.5937 306.7346 306.8754 307.0162 307.1569 307.2977 307.4385 307.5792 307.7200 307.8607 308.0014 308.1421 308.2828 308.4235 308.5642 308.7048 308.8455 308.9861 309.1268 309.2674 309.4080 309.5486 309.6892 309.8297 309.9703 310.1108 310.2514 310.3919 310.5324 310.6729 310.8134 310.9539 311.0944 311.2348 311.3753 311.5157 311.6561 311.7966 311.9370 312.0774 312.2177 312.3581 312.4985 312.6388 312.7791 312.9195 313.0598 313.2001 313.3404 313.4807 313.6209 313.7612 313.9014 314.0417 314.1819 314.3221 314.4623 314.6025 314.7426 314.8828 315.0230 315.1631 315.3032 315.4434 315.5835 315.7236 315.8636 316.0037 316.1438 316.2838 316.4239 316.5639 316.7039 316.8439 316.9839 317.1239 317.2639 317.4038 317.5438 317.6837 317.8236 317.9636 318.1035 318.2433 318.3832 318.5231 318.6629 318.8028 318.9426 319.0824 319.2223 319.3621 319.5018 319.6416 319.7814 319.9211 320.0609 320.2006 320.3403 320.4800 320.6197 320.7594 320.8991 321.0387 321.1784 321.3180 321.4577 321.5973 321.7369 321.8765 322.0160 322.1556 322.2952 322.4347 322.5743 322.7138 322.8533 322.9928 323.1323 323.2717 323.4112 323.5507 323.6901 323.8295 323.9689 324.1084 324.2477 324.3871 324.5265 324.6659 324.8052 324.9445 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231112T040100.0Z 8716.167361 246 1 3.51 2 31.04 216.34 40.04 237.23 0.00 1 0.00 1 0 17 1.060e-02 8.178e-03 6.635e-03 5.073e-03 1.291674e-01 2.519836e-03 1.407630e-03 -6.000000e+00 5.815899e-03 227.21 -2.00 3.05 -2.00 314.32 0.00e+00 4.645623e-04 2.010857e-04 5.048930e-05 -6.000000e+00 2.707137e-04 294.42 -2.00 20.00 -2.00 313.65 0.00e+00 1.167 0.000 302.00 328.00 3 4.6555e+00 6.4134e-03 1.2892e-02 -6.0000e+00 1.4390e-02 2.6007e-02 7.1213e-03 5.9083e-03 -6.0000e+00 1.5629e-02 5.6149e-03 4.0957e-03 2.8698e-03 -6.0000e+00 9.3757e-03 -4.0605e-03 1.8191e-03 8.9918e-04 -6.0000e+00 4.0708e-03 1.4676e-03 -2.0935e-04 1.2903e-04 1.0205e-05 -6.0000e+00 2.5518e-04 5.0665e-03 0.0000e+00 12 9 1 12 1 1 999.00 18.06 0.26 0.00507 0.00349 1 6 1 8 0 1752.830 20.00 18.06 38.29 26.21 26.11 36.4 1021.76 1624 -2596 -358 -1222 -2827 -2202 12 1648 722 1938 -2351 -618 -2775 -122 26 -901 -291 949 1449 1450 1384 1307 1157 461 875 563 2279 186 -218 1697 -487 781 2412 2079 -2227 -2928 -1056 -321 -1040 -864 -663 -913 -1177 -1932 -157 0 -125 -751 -2054 -651 1435 1016 726 1205 1017 291 525 712 160 120 1687 723 733 1151 273 -1509 -659 -434 -558 604 825 -175 -579 549 236 690 -78 -617 -964 -215 -907 -201 -827 -1495 -1630 -390 321 -685 355 834 711 563 270 -204 855 16 424 975 570 395 286 -1228 -2208 81 -463 -911 -1009 -660 -471 486 259 488 83 337 77 -225 -171 430 -409 -25 -32 331 -605 373 925 649 149 1008 932 1001 956 -149 250 -1209 106 27 -137 -29 14 -504 -167 -504 -345 673 -1172 -160 -521 -1092 -796 4 653 314 862 -1043 -264 -1278 -60 14 -504 -163 530 822 839 815 758 670 276 542 357 1422 112 -124 916 -271 446 1427 1256 -1299 -1651 -618 -207 -763 -696 -561 -790 -1034 -1710 -137 0 -107 -627 -1682 -520 1156 855 629 1068 913 264 482 652 145 108 1535 690 732 1186 281 -1474 -598 -379 -504 589 850 -186 -618 573 239 652 -69 -519 -821 -196 -887 -207 -882 -1633 -1854 -461 391 -857 443 1020 833 622 279 -204 873 17 483 1171 712 489 341 -1401 -2460 91 -556 -1132 -1284 -856 -623 659 360 679 113 435 95 -264 -200 514 -513 -32 -43 443 -802 480 1151 788 175 1165 1116 1241 1212 -192 320 -1591 144 38 -194 -42 20 -724 -235 -699 -472 SS 20231112T040543.4Z 8716.170642 249 1 4.89 2 31.75 218.02 41.02 238.08 0.00 1 0.00 1 0 17 7.595e-03 6.288e-03 2.315e-03 1.777e-03 1.307840e-01 8.844816e-04 1.411493e-03 -6.000000e+00 4.168464e-03 227.21 -2.00 3.05 -2.00 314.29 0.00e+00 2.720990e-04 7.036975e-05 1.816537e-05 -6.000000e+00 1.940210e-04 294.42 -2.00 20.00 -2.00 313.62 0.00e+00 1.175 0.000 302.00 328.00 3 3.4824e+00 2.2514e-03 1.2987e-02 -6.0000e+00 1.0314e-02 2.4704e-02 2.4981e-03 5.9170e-03 -6.0000e+00 1.1202e-02 4.8033e-03 1.4385e-03 2.8832e-03 -6.0000e+00 6.7198e-03 -4.1620e-03 6.3850e-04 8.3268e-04 -6.0000e+00 2.9178e-03 4.6949e-03 -1.0458e-04 4.5293e-05 9.8144e-06 -6.0000e+00 1.8289e-04 4.7446e-03 0.0000e+00 12 1 1 12 1 1 97.76 18.05 0.19 0.00474 0.00396 9 22 1 8 0 488.430 19.99 18.05 38.78 26.21 26.11 36.4 1025.59 -268 -440 -676 -914 -2153 -2111 -946 1635 1363 575 -1138 -711 -561 5 1061 129 -295 -26 952 896 1047 369 483 1095 763 147 -170 87 -663 -66 558 1435 1931 334 -1801 -2020 -1366 -726 -215 202 -390 -186 -671 -904 -733 -240 -615 -517 -864 -407 295 931 736 448 606 420 382 481 292 225 701 957 1016 1600 759 20 -566 -1147 -174 619 436 90 4 253 109 -116 -560 -1048 -284 -248 -372 -764 -1627 -1770 -1093 -817 -33 -23 599 466 658 317 87 260 351 554 549 436 974 289 -306 -706 -1118 -475 -444 -858 -748 -734 -426 -212 449 28 696 144 -135 -254 -198 168 -200 196 153 152 61 361 798 856 603 354 532 684 798 282 -373 -108 -154 -99 -330 55 -59 -128 -33 -598 -671 -116 -193 -298 -399 -814 -785 -361 642 604 250 -512 -308 -262 2 569 71 -164 -14 536 519 620 214 279 656 482 92 -105 53 -390 -36 310 835 1122 202 -1074 -1137 -822 -478 -161 165 -330 -162 -600 -812 -651 -212 -526 -421 -709 -323 241 764 633 402 552 388 359 449 267 203 649 901 1030 1626 769 19 -509 -1027 -154 597 441 95 4 261 111 -110 -500 -861 -235 -231 -368 -791 -1716 -1931 -1214 -979 -40 -29 747 564 766 348 89 262 351 605 629 526 1195 351 -362 -799 -1261 -533 -526 -1080 -938 -954 -571 -287 631 39 929 185 -163 -297 -229 204 -251 255 207 204 80 470 980 1045 720 417 635 868 1005 360 -480 -143 -208 -136 -466 79 -87 -183 -46 -838 -918 SS 20231112T041148.6Z 8716.174868 252 1 49.21 2 32.70 220.07 42.29 239.11 0.00 1 0.00 1 0 17 7.651e-03 5.873e-03 1.807e-03 1.134e-03 1.301737e-01 5.566367e-04 1.397382e-03 -6.000000e+00 4.199348e-03 227.21 -2.00 3.05 -2.00 315.37 0.00e+00 2.303167e-04 5.379111e-05 1.471604e-05 -6.000000e+00 1.954598e-04 294.42 -2.00 20.00 -2.00 314.56 0.00e+00 1.188 0.000 302.00 328.00 3 4.4407e+00 1.4335e-03 1.3082e-02 -6.0000e+00 1.0391e-02 1.6066e-02 1.6010e-03 5.8945e-03 -6.0000e+00 1.1285e-02 8.9546e-03 9.1645e-04 2.8691e-03 -6.0000e+00 6.7696e-03 -6.2806e-03 4.1858e-04 8.1999e-04 -6.0000e+00 2.9394e-03 1.7850e-03 -3.7660e-05 2.9474e-05 9.1213e-06 -6.0000e+00 1.8425e-04 4.7855e-03 0.0000e+00 10 0 0 10 0 0 98.71 18.05 0.18 0.00479 0.00450 47 10 1 8 0 1046.720 20.00 18.05 39.57 26.21 26.11 36.7 1030.69 108 -656 -423 -1342 -3177 -2596 -465 829 1461 1266 -344 -868 264 57 -120 82 -247 -26 386 831 976 86 902 231 322 77 -304 68 -573 353 717 1465 1676 890 -1540 -2223 -1254 -787 -146 108 -194 -225 -677 -983 -701 -496 -324 -375 -911 -234 211 641 891 734 568 360 558 457 475 360 539 1134 857 1460 801 -40 -813 -1096 -207 526 170 39 -34 409 133 -153 -384 -1085 -626 -315 -369 -700 -1484 -1564 -918 -634 -6 50 264 647 662 160 -21 169 456 427 455 827 822 239 -263 -775 -1199 -525 -594 -649 -850 -844 -409 5 333 510 404 59 -495 -513 -432 -62 -65 215 255 190 214 403 601 817 321 398 797 689 564 213 -225 -218 -50 142 -4 -30 -145 48 -171 -463 -847 33 -214 -139 -415 -869 -656 -120 237 463 418 -111 -272 88 21 -49 36 -109 -12 175 385 463 40 418 112 163 41 -159 33 -261 151 312 666 805 441 -718 -993 -593 -425 -92 77 -148 -177 -545 -796 -563 -397 -253 -282 -664 -166 154 491 709 604 475 305 480 392 401 302 463 1025 824 1458 798 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