File name: Pandora131s1_Palau_20250625_L2Fit_fout2c11d20221208p1-8.txt File generation date: 20250625T151423.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Katrin Mueller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 131 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora131_OF_v3d20200610.txt Instrument calibration file used: Pandora131s1_CF_v11d20221208.txt Level 1 file used: Pandora131s1_Palau_20250625_L1_smca1c11d20221208p1-8.txt Full location name: Palau Atmospheric Observatory Short location name: Palau Country of location: Palau Location latitude [deg]: 7.3420 Location longitude [deg]: 134.4722 Location altitude [m]: 23 Local noon date: 20250625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: 1st VP, year 2023 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0440 305.1849 305.3259 305.4668 305.6077 305.7486 305.8895 306.0303 306.1712 306.3121 306.4529 306.5937 306.7346 306.8754 307.0162 307.1569 307.2977 307.4385 307.5792 307.7200 307.8607 308.0014 308.1421 308.2828 308.4235 308.5642 308.7048 308.8455 308.9861 309.1268 309.2674 309.4080 309.5486 309.6892 309.8297 309.9703 310.1108 310.2514 310.3919 310.5324 310.6729 310.8134 310.9539 311.0944 311.2348 311.3753 311.5157 311.6561 311.7966 311.9370 312.0774 312.2177 312.3581 312.4985 312.6388 312.7791 312.9195 313.0598 313.2001 313.3404 313.4807 313.6209 313.7612 313.9014 314.0417 314.1819 314.3221 314.4623 314.6025 314.7426 314.8828 315.0230 315.1631 315.3032 315.4434 315.5835 315.7236 315.8636 316.0037 316.1438 316.2838 316.4239 316.5639 316.7039 316.8439 316.9839 317.1239 317.2639 317.4038 317.5438 317.6837 317.8236 317.9636 318.1035 318.2433 318.3832 318.5231 318.6629 318.8028 318.9426 319.0824 319.2223 319.3621 319.5018 319.6416 319.7814 319.9211 320.0609 320.2006 320.3403 320.4800 320.6197 320.7594 320.8991 321.0387 321.1784 321.3180 321.4577 321.5973 321.7369 321.8765 322.0160 322.1556 322.2952 322.4347 322.5743 322.7138 322.8533 322.9928 323.1323 323.2717 323.4112 323.5507 323.6901 323.8295 323.9689 324.1084 324.2477 324.3871 324.5265 324.6659 324.8052 324.9445 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250624T230957.3Z 9306.965247 72 1 33.23 2 58.43 67.01 53.69 59.74 0.00 1 0.00 1 0 17 6.390e-02 1.912e-02 3.965e-02 1.157e-02 2.268280e-01 5.616596e-03 2.306712e-03 -6.000000e+00 3.504687e-02 227.53 -2.00 3.05 -2.00 317.78 0.00e+00 -6.527431e-03 9.066449e-04 2.365970e-04 -6.000000e+00 1.634456e-03 294.65 -2.00 20.00 -2.00 316.75 0.00e+00 1.902 0.000 302.00 328.00 3 6.5639e+00 1.5041e-02 2.1687e-02 -6.0000e+00 8.6772e-02 -2.7107e-03 1.7174e-02 1.3374e-02 -6.0000e+00 9.4282e-02 9.0519e-03 1.0368e-02 5.6319e-03 -6.0000e+00 5.6545e-02 -1.1976e-03 5.2055e-03 5.5758e-03 -6.0000e+00 2.4486e-02 9.1034e-05 -3.7733e-05 3.1365e-04 3.9280e-05 -6.0000e+00 1.5403e-03 1.9404e-02 0.0000e+00 12 9 9 12 9 1 99.99 17.99 1.21 0.01940 0.01912 8 3 4 8 0 3691.470 20.00 17.99 37.00 26.21 26.11 26.2 1020.36 -12869 3534 3493 746 -18951 -1040 -18783 23347 -2501 15366 4829 30202 -3857 -3801 16632 5425 -2124 -8152 6873 4151 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-3052 -175 -1056 -2440 -888 -2373 -1373 -816 887 -299 1692 -423 1218 1386 -57 552 705 1966 -1344 1488 -993 -695 -1799 -748 611 -398 -202 -244 -17 -953 -777 64 782 142 458 1848 -1633 -759 1051 615 -2087 1514 -47 -361 -417 554 1502 489 -103 457 1356 -150 -348 1822 -2142 606 -1267 2034 541 668 478 788 410 -2882 -1845 SS 20250624T234736.8Z 9306.991398 88 1 12.01 2 49.87 65.50 46.00 56.80 0.00 1 0.00 1 0 17 1.939e-02 8.940e-03 1.697e-02 7.464e-03 1.796502e-01 3.631447e-03 1.868731e-03 -6.000000e+00 1.063635e-02 227.53 -2.00 3.05 -2.00 316.66 0.00e+00 1.404313e-04 4.607719e-04 4.625776e-05 -6.000000e+00 4.959894e-04 294.65 -2.00 20.00 -2.00 315.72 0.00e+00 1.548 0.000 302.00 328.00 3 4.5539e+00 9.5107e-03 1.7231e-02 -6.0000e+00 2.6335e-02 1.4949e-02 1.0720e-02 8.0188e-03 -6.0000e+00 2.8612e-02 1.2989e-02 6.2154e-03 3.8973e-03 -6.0000e+00 1.7160e-02 -1.0034e-02 2.9882e-03 1.0860e-03 -6.0000e+00 7.4319e-03 1.0100e-03 -1.6557e-04 1.9702e-04 1.0936e-05 -6.0000e+00 4.6738e-04 1.8456e-02 0.0000e+00 12 9 1 12 1 1 99.98 18.00 0.51 0.01846 0.01721 4 5 3 8 0 2400.000 20.00 18.00 39.09 26.21 26.11 26.1 1025.07 -3252 -2311 -561 -403 8910 -7489 6609 3698 2558 3316 -1964 -1047 4970 -2959 -3986 -492 -580 -1448 -1104 1916 2411 -2419 763 2645 3008 -2239 -1950 -376 -4867 -1563 6128 329 2815 1515 -3535 -3520 -2042 -1615 681 199 580 -695 -265 422 -990 -1833 675 -1279 -1014 987 1252 1324 -58 758 436 546 22 767 97 234 1105 2801 2438 1250 506 -475 -1586 -1252 125 207 1086 325 310 587 -487 248 -928 1095 353 -1117 -668 -1215 -1905 -2618 -1958 -267 -689 -397 622 1141 931 -60 242 142 183 418 398 1694 495 -436 -702 -1007 -526 -1444 -89 -117 -566 -261 -763 488 -294 411 885 -341 -838 993 504 746 -334 -294 -236 354 -232 763 312 629 836 -391 732 -554 -251 691 421 457 67 -118 -309 785 -360 90 -433 -196 -955 -597 -453 -109 -73 1293 -1195 976 639 500 669 -401 -210 1039 -751 -1143 -147 -177 -454 -356 621 796 -819 253 908 1086 -878 -756 -134 -1679 -504 1915 116 1040 580 -1299 -1245 -772 -707 348 117 364 -455 -176 281 -664 -1240 436 -815 -625 592 782 880 -41 550 323 411 17 584 73 175 843 2246 2099 1143 462 -401 -1240 -940 99 184 1031 321 306 564 -448 206 -708 775 260 -928 -608 -1201 -1981 -2823 -2227 -318 -865 -510 793 1411 1083 -65 239 136 184 454 468 2132 659 -575 -875 -1172 -588 -1698 -112 -154 -769 -364 -1104 732 -460 641 1329 -485 -1110 1234 630 968 -465 -434 -355 527 -340 1074 424 822 1036 -490 960 -774 -361 996 611 684 105 -194 -518 1327 -619 152 -716 -315 -1520 SS 20250625T000553.6Z 9307.004092 93 1 3.75 2 45.77 64.34 42.37 54.79 0.00 1 0.00 1 0 17 7.154e-03 5.696e-03 1.529e-03 1.048e-03 1.666336e-01 5.188715e-04 1.779393e-03 -6.000000e+00 3.923990e-03 227.53 -2.00 3.05 -2.00 314.95 0.00e+00 1.884827e-04 4.635193e-05 2.538321e-05 -6.000000e+00 1.829822e-04 294.65 -2.00 20.00 -2.00 314.19 0.00e+00 1.431 0.000 302.00 328.00 3 1.8745e+00 1.3289e-03 1.5970e-02 -6.0000e+00 9.7154e-03 2.7095e-02 1.4824e-03 7.4989e-03 -6.0000e+00 1.0556e-02 3.2859e-03 8.4949e-04 3.6554e-03 -6.0000e+00 6.3307e-03 -4.4363e-03 3.8171e-04 1.0335e-03 -6.0000e+00 2.7418e-03 1.6908e-02 -3.9591e-05 2.6857e-05 1.1851e-05 -6.0000e+00 1.7243e-04 1.8487e-02 0.0000e+00 12 1 1 12 1 1 99.89 18.00 0.16 0.01849 0.01819 31 92 1 8 0 116.750 20.00 18.00 39.23 26.21 26.11 26.1 1023.36 -259 -867 -714 -2274 -2216 -1832 -510 1490 1378 21 -886 -721 -212 201 468 258 72 47 740 922 803 443 791 665 465 71 16 -168 -488 352 927 1533 1957 421 -1517 -1186 -1054 -416 -45 14 -266 -526 -529 -1175 -630 -529 -835 -599 -810 -314 263 486 707 586 467 443 539 428 419 170 617 974 988 1438 364 -108 -762 -717 128 461 459 -31 95 276 205 -137 -317 -538 -336 -216 -373 -749 -1472 -1648 -1091 -700 -325 40 369 557 654 414 355 689 514 385 588 666 542 172 -206 -775 -784 -383 -580 -752 -969 -792 -491 -94 245 162 233 -123 -302 -154 -32 202 73 63 31 148 335 342 680 826 528 631 733 611 610 125 -203 -90 -98 -133 -127 -65 -77 -159 -139 -359 -724 -88 -318 -263 -781 -654 -545 -158 476 495 8 -321 -257 -83 82 214 127 34 22 358 460 410 221 395 349 259 41 9 -89 -253 173 469 822 1049 234 -776 -619 -559 -258 -31 11 -208 -426 -439 -982 -520 -434 -666 -457 -629 -238 208 388 589 510 414 378 468 369 372 150 560 897 934 1434 361 -102 -682 -612 116 455 469 -33 101 284 207 -123 -268 -449 -291 -199 -366 -767 -1603 -1774 -1256 -826 -405 49 450 683 773 463 372 689 545 427 683 815 675 219 -244 -879 -890 -435 -695 -952 -1225 -1037 -667 -130 352 232 316 -160 -372 -186 -38 255 96 85 42 204 446 454 854 1031 617 772 914 778 807 167 -275 -121 -140 -193 -188 -99 -117 -238 -201 -522 -1034 SS 20250625T001146.8Z 9307.008181 96 1 1.49 2 44.46 63.89 41.22 54.04 0.00 1 0.00 1 0 17 8.804e-03 6.730e-03 4.620e-03 3.156e-03 1.660851e-01 1.558747e-03 1.774637e-03 -6.000000e+00 4.829166e-03 227.53 -2.00 3.05 -2.00 314.97 0.00e+00 -3.518338e-05 1.399294e-04 5.043074e-05 -6.000000e+00 2.251851e-04 294.65 -2.00 20.00 -2.00 314.21 0.00e+00 1.399 0.000 302.00 328.00 3 2.9812e+00 3.9924e-03 1.5675e-02 -6.0000e+00 1.1957e-02 2.5564e-02 4.4523e-03 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