File name: Pandora131s1_Palau_20250723_L2Fit_fout2c11d20221208p1-8.txt
File generation date: 20250723T152149.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c11p1-8
Local principal investigator: Katrin Mueller
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 131
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora131_OF_v3d20200610.txt
Instrument calibration file used: Pandora131s1_CF_v11d20221208.txt
Level 1 file used: Pandora131s1_Palau_20250723_L1_smca1c11d20221208p1-8.txt
Full location name: Palau Atmospheric Observatory
Short location name: Palau
Country of location: Palau
Location latitude [deg]: 7.3420
Location longitude [deg]: 134.4722
Location altitude [m]: 23
Local noon date: 20250723
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method)
Data caveats: 1st VP, year 2023
First and last pixel inside fitting window: 228 370
Nominal wavelengths inside fitting window [nm]: 305.0440 305.1849 305.3259 305.4668 305.6077 305.7486 305.8895 306.0303 306.1712 306.3121 306.4529 306.5937 306.7346 306.8754 307.0162 307.1569 307.2977 307.4385 307.5792 307.7200 307.8607 308.0014 308.1421 308.2828 308.4235 308.5642 308.7048 308.8455 308.9861 309.1268 309.2674 309.4080 309.5486 309.6892 309.8297 309.9703 310.1108 310.2514 310.3919 310.5324 310.6729 310.8134 310.9539 311.0944 311.2348 311.3753 311.5157 311.6561 311.7966 311.9370 312.0774 312.2177 312.3581 312.4985 312.6388 312.7791 312.9195 313.0598 313.2001 313.3404 313.4807 313.6209 313.7612 313.9014 314.0417 314.1819 314.3221 314.4623 314.6025 314.7426 314.8828 315.0230 315.1631 315.3032 315.4434 315.5835 315.7236 315.8636 316.0037 316.1438 316.2838 316.4239 316.5639 316.7039 316.8439 316.9839 317.1239 317.2639 317.4038 317.5438 317.6837 317.8236 317.9636 318.1035 318.2433 318.3832 318.5231 318.6629 318.8028 318.9426 319.0824 319.2223 319.3621 319.5018 319.6416 319.7814 319.9211 320.0609 320.2006 320.3403 320.4800 320.6197 320.7594 320.8991 321.0387 321.1784 321.3180 321.4577 321.5973 321.7369 321.8765 322.0160 322.1556 322.2952 322.4347 322.5743 322.7138 322.8533 322.9928 323.1323 323.2717 323.4112 323.5507 323.6901 323.8295 323.9689 324.1084 324.2477 324.3871 324.5265 324.6659 324.8052 324.9445
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250722T222934.9Z 9334.937209 100 1 51.71 2 68.53 71.27 47.13 57.63 0.00 1 0.00 1 0 17 1.012e-02 4.869e-03 2.306e-03 3.989e-04 3.084875e-01 1.938442e-04 3.203463e-03 -6.000000e+00 5.547779e-03 227.47 -2.00 3.05 -2.00 318.52 0.00e+00 1.157049e-04 4.027877e-05 8.594545e-05 -6.000000e+00 2.583769e-04 294.28 -2.00 20.00 -2.00 317.55 0.00e+00 2.707 0.000 302.00 328.00 3 4.8669e-01 5.3086e-04 3.0073e-02 -6.0000e+00 1.3736e-02 2.1817e-02 6.1317e-04 1.3996e-02 -6.0000e+00 1.4926e-02 4.3683e-03 4.0108e-04 6.7798e-03 -6.0000e+00 8.9502e-03 -6.1396e-03 2.1108e-04 1.8855e-03 -6.0000e+00 3.8745e-03 1.5543e-02 -8.6362e-05 1.0666e-05 1.7917e-05 -6.0000e+00 2.4390e-04 1.9801e-02 0.0000e+00 10 0 0 10 0 0 98.69 17.98 0.17 0.01980 0.01915 889 194 1 8 0 55.410 20.00 17.98 36.37 26.21 26.11 30.0 1017.08 -1749 -2770 -2101 -4189 -3890 -4331 -1453 -705 245 -1163 -1967 -1852 -1075 -128 -419 -815 -1102 -843 -725 -23 -201 -509 244 178 83 -429 -543 -1025 -1293 -397 709 1227 1497 -235 -2091 -2672 -1744 -817 51 10 -209 -220 -564 -759 -486 -509 -537 -632 -723 -185 586 599 577 761 560 689 587 664 545 514 823 1218 1385 1617 748 -6 -566 -568 384 777 395 113 -84 331 192 -106 -326 -662 -292 -146 -322 -691 -1491 -1581 -1073 -642 -168 14 406 634 722 468 195 498 690 479 526 677 494 -33 -427 -960 -887 -329 -542 -731 -804 -815 -369 -60 180 122 226 60 -185 -174 -54 27 -16 -25 -5 34 161 320 609 597 398 542 618 618 503 119 -174 -138 -42 -69 -39 -21 13 -23 -40 -373 -560 -94 -167 -129 -247 -200 -213 -75 -42 16 -83 -138 -134 -89 -12 -47 -103 -146 -117 -105 -4 -31 -77 38 30 15 -81 -102 -181 -213 -64 123 235 317 -53 -437 -542 -385 -213 16 4 -86 -95 -230 -341 -217 -229 -238 -275 -311 -80 269 299 307 393 299 377 330 370 296 301 496 729 911 1148 538 -4 -347 -371 249 582 325 97 -72 270 146 -72 -217 -422 -198 -105 -262 -628 -1456 -1610 -1168 -691 -191 16 472 707 803 474 181 450 674 525 643 854 668 -44 -528 -1167 -1013 -392 -659 -938 -1078 -1143 -545 -95 283 195 374 91 -261 -230 -72 38 -25 -40 -8 55 249 475 858 802 544 752 865 942 810 196 -292 -243 -73 -127 -73 -41 24 -42 -73 -643 -1017
SS 20250722T235922.0Z 9334.999560 129 1 39.65 2 47.52 69.46 30.21 42.80 0.00 1 0.00 1 0 17 7.418e-03 5.310e-03 1.435e-03 6.981e-04 1.714150e-01 3.379482e-04 1.818630e-03 -6.000000e+00 4.067876e-03 227.47 -2.00 3.05 -2.00 316.42 0.00e+00 1.201605e-04 4.083131e-05 2.557636e-05 -6.000000e+00 1.894238e-04 294.28 -2.00 20.00 -2.00 315.50 0.00e+00 1.478 0.000 302.00 328.00 3 1.3379e+00 8.8223e-04 1.6481e-02 -6.0000e+00 1.0072e-02 2.5261e-02 9.9254e-04 7.7373e-03 -6.0000e+00 1.0944e-02 4.7101e-03 5.7265e-04 3.7623e-03 -6.0000e+00 6.5623e-03 -5.2710e-03 2.7279e-04 1.0452e-03 -6.0000e+00 2.8414e-03 2.7389e-02 7.2122e-05 1.8395e-05 1.1073e-05 -6.0000e+00 1.7878e-04 1.8307e-02 0.0000e+00 12 1 1 12 1 1 99.99 17.98 0.16 0.01831 0.01885 301 84 3 8 0 127.890 20.00 17.98 39.88 26.21 26.11 30.1 1025.72 -126 -1041 -1223 -2582 -2410 -2119 451 969 1687 616 -672 -612 -416 326 568 -115 -423 -26 271 778 654 367 661 578 36 173 -108 -470 -688 105 1002 1318 1487 229 -1702 -1802 -1387 -245 233 76 -312 -246 -613 -991 -552 -728 -600 -609 -692 -180 556 601 647 763 529 731 586 669 524 390 588 1003 1365 1441 506 -271 -700 -925 236 770 302 23 -116 199 106 -102 -553 -813 -388 -238 -484 -898 -1606 -1585 -999 -653 -80 84 334 514 505 193 -93 293 503 489 645 693 553 87 -337 -798 -890 -275 -520 -659 -741 -714 -376 89 290 250 336 96 -226 -289 -128 60 18 91 50 187 230 393 695 626 375 531 584 597 464 105 -267 -177 -91 -96 -60 -68 57 -67 -38 -367 -594 -25 -225 -267 -524 -463 -379 83 203 358 137 -159 -143 -107 85 167 -37 -137 -9 91 269 231 127 229 211 14 69 -43 -190 -255 37 363 508 616 98 -672 -682 -569 -117 122 46 -206 -168 -429 -698 -384 -506 -403 -393 -429 -109 351 406 458 564 399 558 457 517 396 293 453 830 1218 1360 475 -229 -535 -676 183 685 294 23 -118 195 97 -83 -442 -606 -299 -208 -430 -880 -1672 -1710 -1152 -809 -105 104 448 663 599 207 -89 294 486 520 755 896 759 118 -421 -912 -970 -315 -659 -879 -1031 -1030 -563 129 439 380 482 138 -294 -353 -157 77 25 136 77 284 339 553 924 792 443 626 739 806 654 150 -384 -265 -145 -161 -95 -110 93 -107 -64 -592 -941
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