File name: Pandora221s1_Palawan_20241209_L2Fit_fwvt1c3d20240201p1-8.txt File generation date: 20241210T001425.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 221 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora221_OF_v3d20220412.txt Instrument calibration file used: Pandora221s1_CF_v3d20240201.txt Level 1 file used: Pandora221s1_Palawan_20241209_L1_smca1c3d20240201p1-8.txt Full location name: Department of Environment and Natural Resources - Provincial Environmental Manag Short location name: Palawan Country of location: Philippines Location latitude [deg]: 9.7915 Location longitude [deg]: 118.7340 Location altitude [m]: 56 Local noon date: 20241209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0602 492.1816 492.3030 492.4243 492.5457 492.6671 492.7884 492.9097 493.0310 493.1523 493.2735 493.3948 493.5160 493.6372 493.7584 493.8796 494.0008 494.1219 494.2430 494.3641 494.4852 494.6063 494.7274 494.8484 494.9694 495.0905 495.2115 495.3324 495.4534 495.5743 495.6953 495.8162 495.9371 496.0579 496.1788 496.2996 496.4205 496.5413 496.6621 496.7828 496.9036 497.0243 497.1451 497.2658 497.3864 497.5071 497.6278 497.7484 497.8690 497.9896 498.1102 498.2308 498.3514 498.4719 498.5924 498.7129 498.8334 498.9539 499.0743 499.1948 499.3152 499.4356 499.5560 499.6763 499.7967 499.9170 500.0373 500.1576 500.2779 500.3982 500.5184 500.6387 500.7589 500.8791 500.9992 501.1194 501.2396 501.3597 501.4798 501.5999 501.7200 501.8400 501.9601 502.0801 502.2001 502.3201 502.4401 502.5600 502.6800 502.7999 502.9198 503.0397 503.1596 503.2794 503.3993 503.5191 503.6389 503.7587 503.8785 503.9982 504.1179 504.2377 504.3574 504.4771 504.5967 504.7164 504.8360 504.9556 505.0752 505.1948 505.3144 505.4339 505.5534 505.6730 505.7925 505.9119 506.0314 506.1508 506.2703 506.3897 506.5091 506.6285 506.7478 506.8672 506.9865 507.1058 507.2251 507.3444 507.4636 507.5829 507.7021 507.8213 507.9405 508.0596 508.1788 508.2979 508.4171 508.5362 508.6552 508.7743 508.8934 509.0124 509.1314 509.2504 509.3694 509.4883 509.6073 509.7262 509.8451 509.9640 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241209T000204.5Z 9109.001441 92 1 51.41 2 66.17 120.45 155.52 78.38 0.00 1 0.00 1 0 15 3.225e-03 3.208e-03 8.432e-04 8.412e-04 8.611106e+03 5.735274e+01 5.709425e+02 -6.000000e+00 1.827853e+02 294.08 -2.00 20.00 -2.00 505.28 0.00e+00 5.148800e-04 2.366086e-05 4.281987e-05 -6.000000e+00 9.232760e-05 294.08 -2.00 20.00 -2.00 500.40 0.00e+00 2.172515e-01 1.635694e-02 4.877366e-02 -6.000000e+00 6.252498e-02 225.76 -2.00 3.06 -2.00 502.00 0.00e+00 2.457 0.000 489.00 513.00 1 7.3596e+00 1.2582e-03 5.5188e-03 -6.0000e+00 4.8121e-03 7.7008e-03 3.2190e-04 1.2066e-03 -6.0000e+00 1.2477e-03 8.4966e-04 1.3555e-03 7.3835e-05 5.2884e-05 -6.0000e+00 3.0008e-04 9.7317e-03 -3.5378e-05 10 0 0 10 0 0 99.94 23.48 1.20 0.00973 0.01913 31 5 1 4 0 1658.330 26.00 19.99 23.48 31.19 6.0 1023.58 -929 -550 -211 -185 313 558 421 709 282 264 112 -80 -225 -555 -432 -465 -77 -23 122 213 209 -111 31 300 199 417 451 213 -305 -369 -310 -426 29 68 163 264 191 -66 -221 -194 13 16 152 420 471 448 537 170 48 -332 -492 -615 -759 -351 -249 -136 -48 208 389 44 323 294 350 213 272 8 -65 -168 -165 -101 -498 -211 -117 139 -39 -75 -363 -32 -296 -545 -578 -457 -286 -120 -229 -128 -139 -187 55 132 199 281 617 529 394 254 -21 -248 -679 -843 -314 -235 -142 52 82 23 -238 -204 -182 -330 -9 -21 185 253 380 397 339 393 521 226 22 111 107 164 186 180 177 74 320 100 112 -104 -274 -404 -116 185 -74 40 295 45 36 294 340 301 71 -250 -322 -542 -501 -423 -904 -542 -215 -190 321 582 447 758 302 278 117 -82 -233 -569 -441 -479 -79 -24 127 224 220 -117 33 316 211 441 474 221 -316 -370 -315 -426 29 70 172 280 200 -69 -227 -203 13 17 158 440 497 473 561 176 49 -337 -484 -607 -745 -349 -248 -140 -49 214 397 44 329 302 360 218 275 8 -66 -167 -163 -98 -483 -206 -115 138 -39 -75 -354 -31 -287 -529 -551 -439 -276 -118 -227 -127 -138 -185 54 130 198 277 611 519 387 243 -21 -231 -620 -784 -285 -220 -136 51 81 23 -233 -197 -175 -322 -9 -20 186 254 374 394 339 393 516 225 22 107 103 159 181 175 172 72 309 97 107 -100 -260 -382 -110 175 -72 40 287 44 36 293 340 301 71 -246 -310 -524 -480 -407 SQ 20241209T022252.7Z 9109.099221 187 1 1.61 2 40.02 144.92 122.44 87.97 0.00 1 0.00 1 0 15 3.944e-03 3.947e-03 2.884e-03 2.878e-03 4.968337e+03 1.857924e+02 3.318477e+02 -6.000000e+00 2.235558e+02 294.08 -2.00 20.00 -2.00 505.26 0.00e+00 4.667746e-04 8.067080e-05 3.542233e-05 -6.000000e+00 1.129316e-04 294.08 -2.00 20.00 -2.00 500.39 0.00e+00 1.608644e-01 5.591476e-02 3.097236e-02 -6.000000e+00 7.642915e-02 225.75 -2.00 3.06 -2.00 501.99 0.00e+00 1.304 0.000 489.00 513.00 1 5.8938e+00 4.3009e-03 3.3090e-03 -6.0000e+00 5.8830e-03 1.3119e-02 1.1079e-03 7.3656e-04 -6.0000e+00 1.5242e-03 4.3793e-03 1.2391e-04 2.5741e-04 3.1972e-05 -6.0000e+00 3.6700e-04 8.3589e-03 1.8145e-05 12 9 1 12 1 1 999.00 23.49 1.11 0.00836 0.00922 1 10 1 4 0 802.200 26.00 20.00 23.49 31.31 6.1 1023.81 -870 -1017 -70 -141 591 432 595 299 1038 309 51 -625 -319 -271 -407 -102 -129 162 -129 69 82 11 833 257 119 725 821 -96 -256 -261 -565 -717 47 -17 220 -132 486 67 7 -58 -383 -189 197 188 907 -231 156 503 -198 -222 -681 -420 -728 -1015 -266 -249 214 52 187 110 527 52 -26 148 260 497 -9 -165 -279 -145 -535 365 343 -237 -293 196 -45 80 -511 -75 -255 -403 38 -95 -77 -350 -401 -483 -426 5 360 485 424 425 289 -84 -16 -522 -804 -563 -522 329 75 -385 470 28 138 -488 -564 -300 -248 259 283 79 164 682 335 353 6 444 -213 205 371 30 480 64 -38 44 222 202 662 89 -340 -159 422 -127 -189 220 249 339 -320 381 -354 -111 317 274 -126 -573 -725 -332 -853 -1015 -71 -145 617 453 625 317 1088 327 53 -649 -330 -276 -414 -104 -131 169 -136 73 87 11 879 273 126 771 867 -101 -265 -266 -570 -730 48 -18 231 -139 511 70 7 -59 -393 -195 205 195 940 -242 161 520 -202 -224 -679 -415 -716 -999 -263 -255 219 53 192 112 536 53 -27 152 264 503 -9 -163 -277 -142 -524 357 339 -235 -292 193 -44 77 -489 -71 -245 -391 37 -92 -76 -347 -397 -478 -421 5 358 481 425 422 282 -82 -16 -492 -755 -521 -487 312 72 -378 466 27 135 -472 -553 -292 -245 258 280 79 164 682 333 356 6 434 -209 198 357 29 466 62 -37 43 215 194 636 85 -320 -149 394 -122 -182 215 242 332 -317 377 -349 -110 310 268 -120 -548 -687 -315 SQ 20241209T022735.2Z 9109.102491 190 1 2.00 2 39.36 146.27 121.33 88.16 0.00 1 0.00 1 0 15 3.055e-03 3.037e-03 1.105e-03 1.103e-03 4.587070e+03 7.047451e+01 3.089290e+02 -6.000000e+00 1.731752e+02 294.08 -2.00 20.00 -2.00 505.26 0.00e+00 3.766068e-04 3.093706e-05 2.795155e-05 -6.000000e+00 8.747964e-05 294.08 -2.00 20.00 -2.00 500.41 0.00e+00 5.429465e-02 2.137174e-02 2.851888e-02 -6.000000e+00 5.921109e-02 225.75 -2.00 3.06 -2.00 502.01 0.00e+00 1.292 0.000 489.00 513.00 1 4.7698e+00 1.6438e-03 3.1007e-03 -6.0000e+00 4.5576e-03 1.0783e-02 4.2358e-04 6.8295e-04 -6.0000e+00 1.1810e-03 1.3633e-02 5.9660e-04 9.8717e-05 2.9930e-05 -6.0000e+00 2.8430e-04 8.5161e-03 8.7128e-06 12 1 1 12 1 1 5.13 23.49 1.14 0.00852 0.01265 7 33 1 4 0 249.590 26.00 20.00 23.49 31.62 6.1 1027.49 -693 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