File name: Pandora89s1_PaloDuroTX_20250420_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20250630T154145.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v1d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20250420_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20250420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250420T132530.4Z 9241.559380 216 1 29.99 2 75.19 85.88 62.37 191.38 0.00 1 0.00 1 0 25 2.349e-01 8.132e-03 2.741e-02 1.078e-03 6.318904e-01 5.575896e-04 6.928382e-03 -6.000000e+00 1.347653e-01 228.90 -2.00 3.36 -2.00 320.02 0.00e+00 2.266523e-03 1.857991e-04 1.161283e-03 -6.000000e+00 5.847282e-03 279.14 -2.00 20.00 -2.00 319.45 0.00e+00 3.837 0.001 302.00 328.00 3 1.5685e+00 1.6231e-03 4.6664e-02 -6.0000e+00 3.3623e-01 3.6419e-02 2.0074e-03 3.1842e-02 -6.0000e+00 3.6443e-01 -7.0695e-02 1.8806e-03 1.7064e-02 -6.0000e+00 2.1633e-01 3.0211e-02 9.7048e-04 6.0159e-03 -6.0000e+00 9.2711e-02 1.7128e-03 3.0896e-05 2.8249e-05 6.3036e-05 -6.0000e+00 6.3103e-03 2.4075e-02 0.0000e+00 11 8 0 10 0 0 94.67 25.42 0.44 0.02407 0.02431 139 139 1 5 0 215.700 33.25 20.00 25.42 11.25 5.9 850.45 -86927 -78725 -73312 -67218 -92453 -85356 -86431 -73522 -61343 -66798 -65366 -57292 -43560 -30302 -17349 -17818 -19336 -12601 -7740 -10432 -17253 -14082 -11483 -11596 -13263 -12521 -12750 -18526 -13272 -7244 -5140 -574 -2925 -5302 -9092 -8837 -4253 -2981 1064 3274 782 2010 1311 1752 2253 1140 760 508 912 1184 1916 1513 2438 1786 2003 975 -14 -93 91 253 1332 1881 3379 1767 790 3 -976 375 680 1100 1429 899 1051 308 -878 -1463 -3478 -2408 -2086 -1454 -884 -1659 -1586 -823 -265 707 1044 1604 1583 860 365 -541 -1285 -1001 -886 -104 894 653 129 -311 -1269 -1236 -628 -1227 -1207 -681 -719 52 845 838 732 532 160 -661 -541 -447 -169 256 217 197 686 848 608 537 -24 -568 276 2 -53 -153 -320 -266 -258 -222 181 192 847 508 114 -80 -701 -850 -996 -927 -833 -664 -1118 -1014 -1172 -1005 -826 -1004 -1052 -1042 -889 -688 -425 -506 -620 -415 -259 -374 -666 -540 -467 -516 -642 -625 -629 -935 -659 -392 -328 -41 -239 -440 -752 -778 -416 -353 148 514 137 369 251 339 442 231 159 101 190 270 489 427 745 590 689 352 -5 -33 32 89 501 794 1463 842 376 1 -465 189 391 657 904 576 644 190 -491 -750 -1778 -1310 -1327 -999 -695 -1359 -1381 -756 -242 674 1029 1586 1527 838 331 -468 -1113 -940 -891 -112 1100 844 171 -396 -1574 -1374 -717 -1411 -1479 -869 -921 72 1205 1331 1184 873 256 -1062 -820 -666 -260 415 352 321 1075 1345 934 788 -37 -821 396 4 -86 -272 -580 -504 -489 -449 369 402 1791 1086 238 -164 -1361 -1649 SS 20250420T133500.1Z 9241.565973 219 1 29.96 2 73.25 87.20 62.76 193.68 0.00 1 0.00 1 0 17 1.240e-01 7.857e-03 7.003e-03 4.591e-04 5.578672e-01 2.346241e-04 6.167895e-03 -6.000000e+00 7.113951e-02 228.90 -2.00 3.36 -2.00 319.30 0.00e+00 1.564941e-03 6.196753e-05 6.887633e-04 -6.000000e+00 3.086644e-03 279.14 -2.00 20.00 -2.00 318.70 0.00e+00 3.417 0.001 302.00 328.00 3 4.1273e-01 6.5400e-04 4.1217e-02 -6.0000e+00 1.7749e-01 1.6485e-02 7.6674e-04 2.7658e-02 -6.0000e+00 1.9237e-01 -4.9027e-02 6.2932e-04 1.4128e-02 -6.0000e+00 1.1419e-01 2.2722e-02 3.3541e-04 4.5381e-03 -6.0000e+00 4.8940e-02 8.4872e-03 6.3247e-05 1.2158e-05 4.4113e-05 -6.0000e+00 3.3310e-03 2.4064e-02 0.0000e+00 11 9 0 11 8 0 90.11 25.43 0.36 0.02406 0.02454 583 583 1 5 0 51.370 33.25 19.99 25.43 11.47 6.0 853.35 -40399 -38312 -39531 -45150 -46127 -49830 -42114 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787 140 -505 -848 -1656 -1375 -1364 -1123 -808 -1778 -1630 -892 -277 545 890 1533 1499 952 446 -426 -804 -997 -925 -92 1134 739 80 -421 -1378 -1401 -678 -1352 -1642 -1022 -898 42 1216 1422 1203 873 324 -589 -767 -533 -168 256 375 275 890 1306 831 723 -54 -781 619 212 -1 23 -592 -315 -258 -217 211 301 1594 810 -35 -271 -1300 -1559 SS 20250420T134527.8Z 9241.573238 226 1 7.54 2 71.10 88.67 63.28 196.18 0.00 1 0.00 1 0 17 6.494e-02 7.596e-03 1.916e-02 1.818e-03 4.897801e-01 9.248630e-04 5.473045e-03 -6.000000e+00 3.725656e-02 228.90 -2.00 3.36 -2.00 318.88 0.00e+00 1.244910e-03 2.121943e-04 4.992191e-04 -6.000000e+00 1.616551e-03 279.14 -2.00 20.00 -2.00 318.25 0.00e+00 3.051 0.000 302.00 328.00 3 2.1170e+00 2.5321e-03 3.6521e-02 -6.0000e+00 9.2952e-02 2.4642e-02 2.9157e-03 2.4258e-02 -6.0000e+00 1.0075e-01 -3.7434e-02 2.2009e-03 1.2197e-02 -6.0000e+00 5.9805e-02 1.7147e-02 1.1763e-03 3.7597e-03 -6.0000e+00 2.5630e-02 2.2687e-03 1.3541e-04 4.9240e-05 3.7452e-05 -6.0000e+00 1.7445e-03 2.4194e-02 0.0000e+00 12 9 1 12 1 1 99.99 25.41 0.35 0.02419 0.02521 49 199 1 5 0 150.770 33.25 20.00 25.41 12.25 6.0 860.06 -17840 -25073 -17812 -19128 -18338 -21700 -25165 -18785 -23351 -21967 -25539 -19831 -5164 -1199 963 -3166 -1233 2155 -1164 1684 11 573 773 -540 1308 -1597 -1805 -3162 -1410 -1272 -169 -492 218 -3589 -3377 -3815 -1963 -1377 -1068 -518 -111 654 723 -163 1179 327 -32 -14 -260 1452 1196 1138 1137 697 813 715 492 373 -67 235 746 2025 2318 1146 394 449 -1861 -586 397 342 1091 871 955 255 -458 -1485 -2659 -1817 -1508 -1358 -1211 -1764 -1080 -866 -2 557 833 1643 1382 782 68 -289 -984 -875 -851 197 812 578 19 -504 -941 -1381 -528 -1163 -1570 -891 -492 108 763 911 766 495 377 -288 -690 -322 -117 162 140 75 586 875 519 428 -8 -552 435 211 123 24 -351 -260 1 -223 -88 280 792 505 20 -202 -719 -857 -462 -760 -502 -498 -445 -569 -767 -613 -877 -845 -1068 -917 -253 -69 64 -246 -102 185 -109 159 1 56 81 -62 156 -203 -224 -377 -166 -165 -25 -83 37 -612 -603 -661 -386 -327 -306 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