File name: Pandora89s1_PaloDuroTX_20250701_L2Fit_fwvt1c2d20241101p1-8.txt File generation date: 20250702T065934.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20250701_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20250701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0559 492.1768 492.2976 492.4185 492.5393 492.6601 492.7809 492.9016 493.0224 493.1431 493.2638 493.3845 493.5052 493.6258 493.7465 493.8671 493.9877 494.1083 494.2289 494.3494 494.4700 494.5905 494.7110 494.8315 494.9520 495.0724 495.1929 495.3133 495.4337 495.5541 495.6745 495.7948 495.9152 496.0355 496.1558 496.2761 496.3963 496.5166 496.6368 496.7570 496.8773 496.9974 497.1176 497.2378 497.3579 497.4780 497.5981 497.7182 497.8383 497.9583 498.0783 498.1983 498.3183 498.4383 498.5583 498.6782 498.7982 498.9181 499.0380 499.1578 499.2777 499.3975 499.5174 499.6372 499.7570 499.8767 499.9965 500.1162 500.2360 500.3557 500.4754 500.5950 500.7147 500.8343 500.9539 501.0735 501.1931 501.3127 501.4323 501.5518 501.6713 501.7908 501.9103 502.0298 502.1492 502.2686 502.3880 502.5074 502.6268 502.7462 502.8655 502.9849 503.1042 503.2235 503.3427 503.4620 503.5812 503.7005 503.8197 503.9389 504.0580 504.1772 504.2963 504.4155 504.5346 504.6536 504.7727 504.8918 505.0108 505.1298 505.2488 505.3678 505.4868 505.6057 505.7247 505.8436 505.9625 506.0813 506.2002 506.3190 506.4379 506.5567 506.6755 506.7943 506.9130 507.0318 507.1505 507.2692 507.3879 507.5065 507.6252 507.7438 507.8625 507.9811 508.0996 508.2182 508.3368 508.4553 508.5738 508.6923 508.8108 508.9293 509.0477 509.1661 509.2845 509.4029 509.5213 509.6397 509.7580 509.8763 509.9947 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250701T134935.5Z 9313.576105 110 1 52.57 2 65.42 78.10 135.46 43.60 0.00 1 0.00 1 0 15 9.349e-03 9.080e-03 7.845e-04 7.831e-04 3.692115e+03 4.903072e+01 2.783080e+02 -6.000000e+00 5.256960e+02 286.03 -2.00 20.00 -2.00 505.28 0.00e+00 7.727078e-04 2.166069e-05 4.604715e-05 -6.000000e+00 2.639046e-04 286.03 -2.00 20.00 -2.00 500.50 0.00e+00 2.443739e-01 1.545091e-02 2.263916e-02 -6.000000e+00 1.853545e-01 231.65 -2.00 3.36 -2.00 502.08 0.00e+00 2.388 0.000 489.00 513.00 1 6.9967e+00 1.1850e-03 3.7675e-03 -6.0000e+00 1.4222e-02 -3.4286e-03 3.0451e-04 5.9886e-04 -6.0000e+00 3.6878e-03 1.2821e-03 2.3282e-03 7.5816e-05 3.4909e-05 -6.0000e+00 9.3830e-04 5.2337e-02 2.1380e-04 12 8 8 10 0 0 97.36 26.51 2.51 0.05234 0.06849 15 2 1 4 0 3504.190 34.00 20.00 26.51 29.12 5.9 978.50 -1036 -490 -445 29 497 424 483 332 219 401 -187 -215 -136 -310 -418 10381 -288 -315 -292 -103 -272 -99 -65 98 -13 41 -40 -551 -119 -549 -953 -291 -366 -531 -294 97 -126 -334 -205 -395 -202 -341 79 231 265 391 366 210 -215 -46 -499 -1018 -857 -486 -343 -511 -238 -36 -55 136 190 28 202 187 -118 -39 -346 -248 -277 -314 -315 -224 -132 -35 -382 156 -156 511 128 -136 -218 -79 107 239 101 -185 -20 -59 -360 -319 -203 165 131 29 152 329 -101 -147 -342 -536 -795 -741 -377 -389 -286 -399 -450 -466 -100 -187 -252 -28 195 376 586 617 725 624 186 215 120 337 280 388 449 473 447 427 391 168 253 -284 -330 -4 -209 -207 -347 -178 328 36 2 57 131 739 290 50 -51 -260 -58 -90 900000 -1005 -486 -445 30 519 440 506 349 228 411 -195 -221 -137 -311 -421 10041 -292 -329 -309 -110 -289 -105 -70 102 -14 43 -42 -571 -123 -554 -963 -297 -376 -549 -308 100 -130 -349 -212 -408 -209 -348 81 239 276 406 375 218 -218 -46 -493 -996 -840 -485 -343 -526 -241 -37 -56 138 193 29 206 189 -119 -39 -346 -245 -270 -304 -305 -218 -130 -35 -381 152 -150 495 123 -132 -208 -76 103 233 100 -184 -20 -59 -360 -313 -201 165 132 29 149 322 -97 -138 -323 -504 -738 -708 -363 -385 -286 -398 -443 -454 -97 -184 -252 -27 194 375 587 622 731 628 185 211 119 330 275 382 443 468 441 420 384 165 245 -271 -312 -4 -198 -200 -334 -174 323 36 2 58 132 743 292 49 -49 -248 -56 -87 900000 SQ 20250701T135332.8Z 9313.578852 112 1 54.57 2 64.63 78.59 134.93 44.72 0.00 1 0.00 1 0 15 2.879e-03 2.877e-03 5.042e-04 5.034e-04 3.466276e+03 3.130228e+01 2.536052e+02 -6.000000e+00 1.619047e+02 286.03 -2.00 20.00 -2.00 505.28 0.00e+00 6.284021e-04 1.392102e-05 4.299574e-05 -6.000000e+00 8.127894e-05 286.03 -2.00 20.00 -2.00 500.50 0.00e+00 2.392353e-01 9.935005e-03 2.285637e-02 -6.000000e+00 5.709142e-02 231.65 -2.00 3.36 -2.00 502.08 0.00e+00 2.319 0.000 489.00 513.00 1 6.2354e+00 7.6219e-04 3.6704e-03 -6.0000e+00 4.3804e-03 -3.2328e-03 1.9578e-04 5.8359e-04 -6.0000e+00 1.1360e-03 2.7771e-03 3.3251e-03 4.8772e-05 3.1783e-05 -6.0000e+00 2.8902e-04 5.1595e-02 2.1161e-04 10 0 0 10 0 0 99.47 26.51 2.48 0.05159 0.07466 36 4 1 4 0 1515.600 34.00 19.99 26.51 29.25 5.9 979.05 -590 -177 -149 180 626 626 590 427 413 419 101 -145 -61 -265 -266 -49 49 11 -41 119 155 145 199 208 252 282 95 -373 -87 -359 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-137 -21 199 226 600 552 492 279 194 -27 119 314 308 278 354 562 369 316 349 163 85 -127 -254 -231 -55 -106 -213 -136 272 117 178 310 283 403 68 -104 -167 -313 -301 -295 900000 SQ 20250701T135801.4Z 9313.581961 115 1 55.26 2 63.73 79.15 134.31 45.97 0.00 1 0.00 1 0 15 7.072e-03 6.923e-03 6.706e-04 6.693e-04 3.422098e+03 4.166555e+01 2.575890e+02 -6.000000e+00 3.976543e+02 286.03 -2.00 20.00 -2.00 505.27 0.00e+00 7.415713e-04 1.850741e-05 4.533193e-05 -6.000000e+00 1.996307e-04 286.03 -2.00 20.00 -2.00 500.48 0.00e+00 2.424025e-01 1.321872e-02 2.120303e-02 -6.000000e+00 1.402270e-01 231.65 -2.00 3.36 -2.00 502.06 0.00e+00 2.246 0.000 489.00 513.00 1 6.7783e+00 1.0135e-03 3.5504e-03 -6.0000e+00 1.0759e-02 -3.3588e-03 2.6068e-04 5.5663e-04 -6.0000e+00 2.7903e-03 1.6256e-03 2.9562e-03 6.4781e-05 3.3269e-05 -6.0000e+00 7.0989e-04 5.1744e-02 2.0842e-04 12 8 8 10 0 0 99.40 26.50 2.51 0.05174 0.07225 21 2 1 4 0 2630.840 34.00 20.00 26.50 29.32 5.9 979.38 -857 -472 -438 136 446 437 331 369 369 295 75 -77 -103 -247 -398 7542 -107 -163 -327 -10 -241 -83 61 32 102 93 -159 -361 -252 -470 -831 -311 -235 -465 -232 18 -61 -274 -201 -317 -262 -107 311 328 331 594 353 185 -325 -285 -670 -787 -831 -479 -186 -439 -330 -10 -37 140 238 -35 202 27 -74 -132 -376 -329 -236 -359 -408 -262 -56 -100 -61 77 25 245 16 -42 -212 135 207 325 -43 -253 -10 -40 -258 -272 -143 107 157 124 32 201 -155 -182 -219 -542 -716 -577 -385 -409 -317 -421 -367 -346 -192 -175 -192 1 173 387 696 556 506 463 242 147 137 354 359 381 238 585 479 320 312 196 8 51 -206 -130 -59 -233 -320 -162 311 73 -30 191 266 621 138 37 -11 -165 -287 -208 900000 -836 -471 -442 140 459 458 351 392 387 306 77 -79 -104 -250 -404 7350 -110 -172 -342 -10 -253 -87 63 34 107 97 -165 -377 -254 -466 -826 -313 -244 -487 -245 19 -64 -282 -204 -322 -268 -110 323 344 349 622 366 189 -334 -284 -652 -774 -820 -470 -188 -446 -339 -10 -37 143 244 -37 208 28 -75 -132 -371 -328 -232 -350 -398 -257 -55 -98 -60 76 25 234 15 -40 -204 131 202 320 -42 -248 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