File name: Pandora89s1_PaloDuroTX_20250702_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20250703T065619.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20250702_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20250702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250702T140941.1Z 9314.590059 119 1 33.32 2 61.45 80.65 142.90 42.52 0.00 1 0.00 1 0 25 1.123e-02 7.213e-03 2.303e-03 1.027e-03 2.636645e-01 5.257458e-04 2.965114e-03 -6.000000e+00 6.478934e-03 231.64 -2.00 3.36 -2.00 316.50 0.00e+00 4.532011e-04 6.249995e-05 6.829027e-05 -6.000000e+00 2.876011e-04 286.12 -2.00 20.00 -2.00 315.73 0.00e+00 2.082 0.000 302.00 328.00 3 3.6330e+00 1.3803e-03 2.2670e-02 -6.0000e+00 1.6231e-02 2.5322e-02 1.5411e-03 1.3039e-02 -6.0000e+00 1.7563e-02 -9.1914e-03 8.9634e-04 6.3020e-03 -6.0000e+00 1.0447e-02 3.2758e-03 4.2461e-04 1.7550e-03 -6.0000e+00 4.4550e-03 1.5989e-03 7.4629e-04 2.8739e-05 1.9513e-05 -6.0000e+00 3.0205e-04 5.8514e-02 0.0000e+00 12 9 1 12 1 1 99.92 26.45 0.34 0.05851 0.06412 42 8 1 5 0 774.760 34.00 20.00 26.45 29.19 5.9 978.88 848 -939 -2272 -3829 -2192 -2670 -1030 610 -731 -3776 -2161 -720 -240 617 1531 712 1389 2403 1530 638 1554 1617 1544 850 1169 635 -410 -968 -400 1128 952 1368 -1167 -3322 -2955 -2715 -1874 -641 -136 -649 -484 -498 -745 -64 -73 -102 -681 -1325 -509 332 144 830 731 350 1017 519 290 62 -200 793 1118 1614 1923 416 -122 -927 -1251 332 268 439 886 918 898 313 -138 -986 -1579 -1459 -1379 -1313 -755 -1949 -964 -715 45 585 1113 1132 1051 401 166 -498 -567 -705 -340 409 1063 488 79 -378 -952 -1005 -309 -1061 -834 -730 -719 42 692 903 547 530 -81 -670 -313 -558 -367 112 252 213 521 601 363 378 -234 -341 239 30 112 -156 -228 -122 -75 114 307 357 686 442 -18 -269 -744 -805 145 -168 -390 -591 -314 -404 -171 112 -144 -758 -433 -159 -60 161 440 216 434 774 515 221 529 559 564 330 434 238 -158 -348 -140 411 376 538 -489 -1334 -1237 -1134 -901 -340 -79 -415 -323 -321 -487 -41 -50 -69 -453 -867 -331 225 98 596 555 276 763 400 223 50 -160 606 912 1425 1711 377 -109 -769 -1009 278 241 434 864 897 895 293 -124 -800 -1291 -1235 -1236 -1252 -750 -2100 -1021 -808 52 706 1382 1414 1269 473 179 -520 -567 -744 -375 475 1361 641 103 -485 -1132 -1176 -368 -1326 -1051 -959 -990 57 1006 1326 820 767 -114 -912 -397 -738 -482 156 361 314 755 848 515 508 -315 -436 303 39 156 -219 -329 -179 -110 176 480 571 1119 730 -28 -420 -1171 -1234 SS 20250702T141443.5Z 9314.593559 122 1 54.17 2 60.43 81.28 142.23 44.18 0.00 1 0.00 1 0 17 1.028e-02 7.456e-03 5.024e-04 2.790e-04 2.547951e-01 1.433470e-04 2.876311e-03 -6.000000e+00 5.933555e-03 231.64 -2.00 3.36 -2.00 315.92 0.00e+00 4.280428e-04 1.485372e-05 4.543069e-05 -6.000000e+00 2.634182e-04 286.12 -2.00 20.00 -2.00 315.18 0.00e+00 2.017 0.000 302.00 328.00 3 1.7129e+00 3.7345e-04 2.1927e-02 -6.0000e+00 1.4865e-02 1.3772e-02 4.1580e-04 1.2565e-02 -6.0000e+00 1.6085e-02 -1.0912e-02 2.3887e-04 6.0722e-03 -6.0000e+00 9.5681e-03 4.3381e-03 1.0956e-04 1.6873e-03 -6.0000e+00 4.0796e-03 1.1787e-02 7.2535e-04 7.7466e-06 1.9335e-05 -6.0000e+00 2.7665e-04 5.9261e-02 0.0000e+00 11 8 0 10 0 0 99.90 26.42 0.38 0.05926 0.06471 533 57 1 5 0 101.620 34.00 20.01 26.42 29.34 5.9 979.78 612 493 -1735 -2645 -2630 -1409 -251 214 -929 -2162 -1903 -1151 -217 861 781 1028 1376 1473 1876 1097 1162 1837 1291 1061 1093 301 -274 -783 -15 433 736 1363 -1435 -2906 -3119 -3136 -1932 -834 -536 -633 -367 -540 -539 231 -192 -446 -634 -1193 -475 323 230 770 774 640 1008 617 156 -9 -66 692 1091 1642 1838 317 -192 -827 -1036 363 256 477 1001 933 1067 409 -159 -864 -1808 -1265 -1363 -1163 -1048 -1863 -1169 -525 36 555 965 1363 1072 715 20 -486 -484 -534 -395 428 1024 471 17 -373 -1110 -994 -434 -1027 -907 -775 -601 110 702 918 627 471 8 -610 -543 -669 -193 154 242 145 509 557 290 430 -269 -293 314 65 68 -70 -193 -204 63 38 283 494 707 412 32 -178 -793 -981 148 123 -417 -568 -534 -296 -58 55 -238 -556 -494 -330 -66 295 277 381 525 585 768 435 484 773 542 470 503 140 -121 -321 -6 180 330 621 -697 -1342 -1477 -1520 -1017 -495 -339 -440 -254 -386 -390 165 -137 -315 -436 -844 -333 226 173 583 618 508 812 509 129 -8 -53 568 918 1438 1717 290 -169 -703 -889 311 240 474 1001 936 1032 385 -146 -746 -1485 -1070 -1248 -1111 -1069 -1981 -1249 -597 42 665 1157 1638 1285 821 21 -518 -494 -574 -437 506 1260 603 22 -460 -1348 -1168 -505 -1272 -1153 -998 -810 149 986 1324 920 668 11 -810 -693 -848 -255 210 335 206 714 783 391 565 -349 -371 394 85 92 -98 -276 -289 93 58 439 765 1119 661 50 -277 -1195 -1480 SS 20250702T141944.2Z 9314.597040 125 1 43.64 2 59.41 81.91 141.55 45.78 0.00 1 0.00 1 0 17 9.837e-03 7.390e-03 4.532e-04 2.571e-04 2.483510e-01 1.322124e-04 2.808073e-03 -6.000000e+00 5.676930e-03 231.64 -2.00 3.36 -2.00 315.84 0.00e+00 3.562223e-04 1.347636e-05 4.822163e-05 -6.000000e+00 2.520381e-04 286.12 -2.00 20.00 -2.00 315.11 0.00e+00 1.957 0.000 302.00 328.00 3 1.3892e+00 3.4405e-04 2.1311e-02 -6.0000e+00 1.4222e-02 1.4165e-02 3.8278e-04 1.2249e-02 -6.0000e+00 1.5390e-02 -1.0956e-02 2.1978e-04 5.9220e-03 -6.0000e+00 9.1545e-03 3.9287e-03 1.0049e-04 1.6362e-03 -6.0000e+00 3.9030e-03 1.7358e-02 7.3640e-04 7.1485e-06 1.9219e-05 -6.0000e+00 2.6469e-04 5.9638e-02 0.0000e+00 12 9 1 12 1 1 99.98 26.41 0.38 0.05964 0.06517 793 106 1 5 0 54.950 34.00 20.00 26.41 29.63 5.9 982.73 839 826 -1502 -1935 -2270 -1140 165 633 -647 -1981 -1429 -1185 -76 933 659 956 1203 1124 1921 1094 1202 1586 1204 910 1034 220 -463 -864 -71 298 647 1132 -1392 -3046 -3102 -3133 -1847 -890 -472 -647 -376 -525 -526 155 -268 -465 -649 -1255 -534 263 186 663 738 594 986 563 115 4 -17 646 1153 1664 1830 308 -114 -791 -1033 338 286 587 983 960 1089 366 -136 -958 -1722 -1134 -1389 -1126 -1000 -1853 -1100 -514 20 569 981 1415 1061 704 96 -363 -390 -540 -364 434 1007 472 -40 -353 -1083 -1029 -447 -1101 -941 -775 -660 77 667 914 612 466 7 -580 -553 -609 -217 120 247 132 484 555 237 374 -327 -327 307 11 56 -75 -245 -206 95 122 235 525 742 403 39 -216 -732 -910 210 212 -372 -426 -473 -247 39 168 -170 -523 -379 -348 -25 326 238 360 467 454 796 467 507 677 512 408 481 103 -206 -380 -30 133 291 548 -676 -1490 -1467 -1517 -970 -528 -311 -448 -271 -374 -379 110 -191 -326 -463 -880 -371 190 138 518 581 484 816 457 94 3 -14 544 993 1489 1681 287 -102 -685 -868 295 262 570 996 974 1067 349 -122 -810 -1437 -974 -1241 -1086 -1028 -1983 -1181 -587 24 684 1178 1703 1277 811 105 -389 -400 -562 -403 513 1235 602 -51 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