File name: Pandora89s1_PaloDuroTX_20250821_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20250822T065657.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20250821_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20250821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250821T124309.3Z 9364.529969 95 1 55.06 2 84.56 79.26 64.07 81.17 0.00 1 0.00 1 0 17 8.714e-01 5.427e-02 3.795e-01 2.034e-02 9.176421e-01 1.254919e-02 9.636897e-03 -6.000000e+00 5.301830e-01 230.21 -2.00 3.36 -2.00 322.38 0.00e+00 -8.026971e-03 8.049899e-03 3.458211e-03 -6.000000e+00 3.137527e-02 287.32 -2.00 20.00 -2.00 321.90 0.00e+00 9.219 0.012 302.00 328.00 3 1.4632e+00 5.4815e-02 9.8005e-02 -6.0000e+00 1.3261e+00 1.5001e+00 6.4863e-02 5.7676e-02 -6.0000e+00 1.4492e+00 -1.8482e+00 4.4049e-02 2.3425e-02 -6.0000e+00 8.5350e-01 6.7561e-01 2.2592e-02 9.3243e-03 -6.0000e+00 3.6953e-01 1.1984e-05 -1.0095e-05 5.9727e-04 1.0246e-04 -6.0000e+00 2.4405e-02 6.6072e-02 0.0000e+00 12 8 8 10 0 0 -23.02 26.41 1.78 0.06607 0.06600 23 2 1 5 0 2393.790 34.00 20.00 26.41 26.94 6.0 959.95 900000 -6562 -66477 900000 900000 -46878 -27634 900000 900000 217072 900000 900000 208345 262124 900000 -7802 900000 900000 -46134 -37300 900000 25612 900000 11417 900000 900000 318836 237618 197599 900000 -67959 900000 347197 60202 900000 900000 -71173 25618 161831 900000 109946 11532 73942 900000 100086 900000 900000 378515 62441 123293 57581 140939 40569 87422 900000 67783 85416 46297 72939 143260 57779 9173 123654 7110 24924 55697 19116 39728 -3435 8157 36774 17261 16952 39426 -6463 14355 144739 11716 47628 -4704 12332 14957 40547 11173 25283 25417 6270 -51400 4694 -15757 994 -12896 1966 9679 13943 -2401 3597 -791 8267 72 6043 6019 -4072 4684 -4257 1097 -7970 6898 1508 -1388 -3154 -442 1925 -5767 1651 -6868 -1156 -1545 658 510 5013 1304 7689 3334 4702 153 -1499 -701 3216 -595 833 -334 -1229 1196 -1590 -1034 1031 1517 2457 -112 -3769 -859 900000 -291 -4591 900000 900000 -1927 -1000 900000 900000 4283 900000 900000 4111 5172 900000 -436 900000 900000 -3641 -2514 900000 842 900000 532 900000 900000 6291 4688 3899 900000 -6826 900000 6850 1728 900000 900000 -8425 1378 3193 900000 3352 931 3050 900000 2872 900000 900000 7468 2800 3317 3305 3792 3202 4547 900000 4498 4596 3405 3794 3597 3627 1053 5101 995 2861 4695 2434 4560 -696 1770 6167 3406 3077 5056 -1148 1926 5426 1895 6484 -1281 3285 4308 9600 3770 7832 8174 2487 -35900 1787 -6839 345 -5089 714 3762 6162 -1473 2427 -618 5953 53 3732 3325 -2466 2800 -2948 764 -6620 5552 1487 -1622 -4107 -579 2446 -7646 1973 -9079 -1519 -2161 929 705 6281 1631 8784 3861 5242 175 -1857 -1012 5216 -1132 1712 -746 -2992 3079 -4046 -2671 2649 3858 6461 -280 -9042 -1916 SS 20250821T125537.7Z 9364.538631 98 1 54.36 2 82.04 80.99 61.62 82.75 0.00 1 0.00 1 0 17 5.688e-01 9.443e-03 2.164e-01 2.818e-03 7.602773e-01 1.538827e-03 8.320128e-03 -6.000000e+00 3.276698e-01 230.21 -2.00 3.36 -2.00 321.41 0.00e+00 2.654985e-04 8.327735e-04 4.129834e-03 -6.000000e+00 1.491890e-02 287.32 -2.00 20.00 -2.00 320.84 0.00e+00 6.748 0.005 302.00 328.00 3 1.2967e+00 5.6458e-03 7.4133e-02 -6.0000e+00 8.1893e-01 4.5600e-02 8.4070e-03 4.8123e-02 -6.0000e+00 8.8849e-01 -1.6992e-01 8.9801e-03 2.3237e-02 -6.0000e+00 5.2903e-01 7.0650e-02 4.1453e-03 6.1870e-03 -6.0000e+00 2.2554e-01 1.9242e-04 3.4556e-04 7.4685e-05 1.0016e-04 -6.0000e+00 1.5334e-02 6.5679e-02 0.0000e+00 12 8 8 10 0 0 16.28 26.42 0.63 0.06568 0.06828 111 12 1 5 0 489.680 34.00 20.00 26.42 27.29 6.0 962.47 -261218 -149169 -105833 -240207 -193291 -241681 -181567 -186255 -125380 -156490 -103120 900000 -92340 -81198 -9259 -31385 -2456 900000 -2869 -26074 -105480 1001 -22848 -28641 -5030 96256 -32403 2344 17419 46832 -52362 -35111 11394 -49091 -8220 71907 -40837 8773 11165 814 1535 -1167 -497 537 -4707 15978 8171 -4251 3209 1396 286 6237 3136 5267 10004 -606 4231 3825 -6072 8002 3242 1790 7760 -2417 1557 -836 -2361 2300 789 726 2721 1785 2150 -1831 -2144 -2680 -1153 -1729 129 -643 -762 -1005 1608 -397 1445 1700 2312 -2627 1667 452 -391 -1319 -1898 -1697 -1300 171 568 554 503 -1164 -730 -1049 -1646 -1150 -967 -1179 -580 435 1269 1472 642 735 -387 -1190 -477 -638 -408 102 -161 339 1049 543 1016 395 60 -464 294 -202 -74 -592 -249 -609 -117 29 13 491 667 530 386 -83 -940 -634 -2544 -522 -291 -1920 -965 -2173 -1043 -1302 -532 -977 -438 900000 -600 -608 -42 -204 -13 900000 -19 -221 -2002 8 -251 -370 -55 397 -472 24 167 412 -1525 -1022 228 -1753 -194 849 -1795 294 448 42 85 -70 -31 33 -316 900 523 -329 252 127 30 687 395 700 1341 -94 629 554 -949 1119 526 340 1597 -591 363 -201 -605 629 256 263 1013 665 753 -607 -639 -755 -329 -566 50 -298 -373 -548 911 -247 942 1164 1621 -1938 1137 291 -240 -795 -1205 -1225 -1098 153 586 630 576 -1272 -713 -1015 -1606 -1106 -983 -1271 -672 552 1677 2187 1032 1198 -622 -1836 -704 -952 -638 169 -276 572 1677 841 1516 571 84 -635 421 -333 -130 -1157 -523 -1267 -259 69 29 1175 1621 1289 898 -192 -2068 -1341 SS 20250821T131137.7Z 9364.549742 103 1 54.16 2 78.79 83.21 58.47 84.80 0.00 1 0.00 1 0 17 2.511e-01 8.903e-03 1.707e-02 8.379e-04 5.900452e-01 4.333300e-04 6.494436e-03 -6.000000e+00 1.440542e-01 230.21 -2.00 3.36 -2.00 320.01 0.00e+00 1.989407e-03 1.489763e-04 1.402954e-03 -6.000000e+00 6.467795e-03 287.31 -2.00 20.00 -2.00 319.30 0.00e+00 4.966 0.002 302.00 328.00 3 8.7737e-01 1.2875e-03 5.3173e-02 -6.0000e+00 3.5946e-01 -8.5439e-03 1.5816e-03 3.0211e-02 -6.0000e+00 3.8941e-01 -7.2014e-02 1.3906e-03 1.5370e-02 -6.0000e+00 2.3210e-01 3.3672e-02 7.1512e-04 4.7909e-03 -6.0000e+00 9.9289e-02 1.4939e-03 4.4305e-04 2.2407e-05 5.6504e-05 -6.0000e+00 6.7549e-03 6.5035e-02 0.0000e+00 11 8 0 10 0 0 12.23 26.42 0.47 0.06504 0.06836 368 40 1 5 0 147.160 34.00 20.00 26.42 28.24 6.0 970.29 -96879 -84587 -82114 -91956 -105011 -90101 -92154 -75190 -50856 -78536 -70113 -46644 -32256 -29749 -12710 -18199 -12444 -24459 -6984 -5201 -13518 -6818 -2439 -8789 -4962 -4957 -9452 -11556 -6199 -4508 -4281 -2074 -3830 -7522 -6910 -4287 -4626 -2057 895 443 1405 78 897 2469 2118 1439 1824 260 -51 1689 1957 2510 2577 2532 2945 1311 1373 761 -290 2284 1729 3309 3419 983 603 -719 -871 569 275 791 1253 870 1037 -521 -1375 -2197 -3382 -2940 -1929 -1549 -1105 -1827 -1238 -547 246 705 1523 1380 1517 883 -59 -894 -1240 -888 -689 278 987 379 -158 -616 -1220 -1251 -807 -1418 -1108 -825 -643 425 912 1070 675 542 -48 -628 -574 -586 -201 128 90 270 830 961 504 610 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