File name: Pandora89s1_PaloDuroTX_20250829_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20250830T065457.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20250829_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20250829 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250829T193607.6Z 9372.816754 314 1 54.31 2 28.14 206.20 79.33 128.18 0.00 1 0.00 1 0 17 9.023e-03 7.628e-03 6.440e-04 5.073e-04 1.453996e-01 2.623558e-04 1.668549e-03 -6.000000e+00 5.168444e-03 229.71 -2.00 3.36 -2.00 314.24 0.00e+00 2.198571e-04 1.982504e-05 1.394165e-05 -6.000000e+00 2.318660e-04 286.81 -2.00 20.00 -2.00 313.66 0.00e+00 1.134 0.000 302.00 328.00 3 3.8370e+00 6.7009e-04 1.2337e-02 -6.0000e+00 1.2884e-02 3.1086e-02 7.4176e-04 7.1115e-03 -6.0000e+00 1.3962e-02 -7.9323e-03 4.2571e-04 3.4592e-03 -6.0000e+00 8.3226e-03 1.1277e-03 1.8516e-04 9.6017e-04 -6.0000e+00 3.5639e-03 3.7406e-03 7.5928e-04 1.4011e-05 1.2570e-05 -6.0000e+00 2.4265e-04 6.2348e-02 0.0000e+00 11 9 0 11 8 0 99.95 26.46 0.46 0.06235 0.06805 195 21 1 5 0 278.460 34.00 19.97 26.46 31.99 5.9 996.20 780 781 -1534 -1694 -1509 -610 511 1036 -172 -1364 -927 -755 -50 830 390 876 817 1375 1408 760 812 1173 852 767 810 131 -104 -588 210 501 806 877 -1291 -2710 -2975 -2975 -1832 -833 -475 -648 -416 -601 -559 -42 -461 -424 -588 -1228 -457 308 293 724 715 542 1052 566 282 88 23 626 1029 1490 1747 352 -181 -978 -1061 421 249 548 973 919 1237 536 -125 -861 -1630 -1218 -1307 -1155 -1065 -1813 -885 -474 40 541 1033 1219 1023 648 -14 -343 -443 -594 -360 448 1133 526 136 -290 -970 -1047 -539 -1218 -891 -800 -667 65 607 862 555 520 33 -616 -600 -717 -290 105 224 143 489 381 185 388 -283 -262 324 94 123 -22 -147 -289 117 -9 296 484 708 423 103 -148 -665 -942 361 364 -678 -706 -586 -244 207 462 -81 -630 -420 -367 -25 455 216 492 464 796 834 460 483 700 531 497 508 82 -65 -335 121 293 461 531 -812 -1601 -1807 -1828 -1207 -610 -381 -536 -355 -526 -491 -36 -397 -354 -496 -999 -361 250 252 646 631 490 956 523 261 80 21 577 958 1482 1738 349 -172 -890 -969 375 239 574 1012 961 1309 536 -119 -773 -1442 -1033 -1230 -1147 -1102 -1912 -963 -526 48 647 1271 1507 1221 747 -16 -357 -456 -605 -398 516 1363 645 164 -345 -1122 -1148 -610 -1450 -1072 -1003 -869 84 817 1160 750 696 43 -759 -718 -850 -342 132 292 185 656 501 232 479 -334 -305 371 114 150 -28 -191 -378 150 -13 407 682 1020 595 148 -207 -905 -1308 SS 20250829T195400.1Z 9372.829168 329 1 22.84 2 29.99 214.45 76.62 131.21 0.00 1 0.00 1 0 17 9.473e-03 7.809e-03 2.155e-03 1.584e-03 1.482386e-01 8.164263e-04 1.702343e-03 -6.000000e+00 5.426253e-03 229.70 -2.00 3.36 -2.00 314.64 0.00e+00 3.834324e-04 6.636413e-05 2.457294e-05 -6.000000e+00 2.434364e-04 286.81 -2.00 20.00 -2.00 314.01 0.00e+00 1.154 0.000 302.00 328.00 3 5.0465e+00 2.0951e-03 1.2575e-02 -6.0000e+00 1.3526e-02 3.4770e-02 2.3222e-03 7.2738e-03 -6.0000e+00 1.4659e-02 -7.6571e-03 1.3309e-03 3.5325e-03 -6.0000e+00 8.7378e-03 4.5976e-04 5.8479e-04 9.9177e-04 -6.0000e+00 3.7417e-03 1.0871e-03 8.1384e-04 4.4056e-05 1.2831e-05 -6.0000e+00 2.5476e-04 6.2448e-02 0.0000e+00 12 9 1 12 9 1 99.98 26.43 0.26 0.06245 0.06856 17 5 1 5 0 1268.630 34.00 20.00 26.43 33.03 5.8 1001.67 1054 809 -2055 -1120 -693 -1527 201 1452 -218 -1169 -849 -425 -124 873 308 285 1638 1138 1048 254 1347 1286 842 1224 1199 25 -479 -1168 -67 1170 241 995 -1544 -3235 -3005 -2463 -1876 -1184 -600 -458 -539 -784 -749 264 -496 -319 -324 -1290 -735 127 153 722 659 706 1080 266 324 -29 167 665 1059 1555 1850 420 77 -894 -999 680 164 691 1089 861 1090 783 -483 -1182 -1370 -1117 -1698 -1519 -848 -1762 -792 -438 138 790 1070 932 981 578 -236 -613 -850 -511 -547 510 1065 493 98 -207 -861 -1084 -551 -1146 -808 -736 -555 160 710 986 620 610 99 -645 -682 -819 -430 78 177 2 353 606 423 241 -327 -194 175 111 27 -293 -106 -383 61 269 304 508 633 544 301 -273 -684 -938 417 323 -783 -403 -232 -535 76 552 -88 -461 -329 -177 -57 441 155 146 841 601 568 141 727 698 478 719 724 15 -272 -610 -36 632 127 551 -893 -1761 -1701 -1381 -1205 -834 -455 -376 -458 -683 -655 227 -426 -265 -258 -993 -591 104 124 610 581 636 978 246 298 -27 150 611 969 1519 1894 430 72 -813 -866 605 155 711 1168 929 1137 767 -459 -1011 -1166 -965 -1527 -1516 -863 -1920 -890 -494 166 944 1318 1157 1174 678 -268 -630 -882 -513 -599 572 1306 607 119 -250 -969 -1230 -645 -1388 -1032 -924 -725 216 946 1365 862 853 128 -809 -796 -949 -517 100 233 3 476 796 532 304 -394 -233 207 131 34 -381 -140 -511 79 368 438 710 906 788 427 -399 -974 -1308 SS 20250829T195756.3Z 9372.831902 332 1 54.44 2 30.46 216.14 76.04 131.90 0.00 1 0.00 1 0 17 9.205e-03 7.751e-03 7.628e-04 5.907e-04 1.489313e-01 3.055881e-04 1.716148e-03 -6.000000e+00 5.273054e-03 229.70 -2.00 3.36 -2.00 314.33 0.00e+00 1.976943e-04 2.350506e-05 1.691741e-05 -6.000000e+00 2.365673e-04 286.81 -2.00 20.00 -2.00 313.73 0.00e+00 1.160 0.000 302.00 328.00 3 4.1070e+00 7.8092e-04 1.2639e-02 -6.0000e+00 1.3144e-02 3.0759e-02 8.6399e-04 7.3064e-03 -6.0000e+00 1.4245e-02 -7.3766e-03 4.9616e-04 3.5595e-03 -6.0000e+00 8.4911e-03 7.9302e-04 2.1677e-04 9.8705e-04 -6.0000e+00 3.6360e-03 2.7695e-03 7.7401e-04 1.6287e-05 1.3231e-05 -6.0000e+00 2.4757e-04 6.2535e-02 0.0000e+00 11 9 0 11 8 0 99.99 26.43 0.45 0.06253 0.06835 105 11 1 5 0 518.400 34.00 20.00 26.43 32.99 5.9 1001.55 426 549 -1763 -1590 -1669 -1063 661 1110 -358 -1309 -644 -452 117 862 766 880 1105 1119 1345 684 1200 1462 907 782 840 296 -195 -783 206 663 659 960 -1325 -2870 -2815 -2812 -1921 -971 -529 -668 -588 -686 -636 26 -502 -388 -608 -1221 -442 265 130 852 808 658 1176 593 244 83 55 576 1065 1550 1810 226 -40 -719 -1154 295 175 582 968 1029 1121 573 -109 -911 -1577 -1279 -1396 -1115 -861 -1823 -964 -494 129 580 1046 1275 987 580 16 -498 -524 -602 -351 463 1096 589 114 -338 -920 -1057 -679 -1192 -867 -700 -624 161 672 1004 558 546 -113 -600 -626 -835 -363 17 245 15 426 448 178 442 -339 -294 359 46 144 -73 -82 -203 90 127 265 546 724 415 109 -246 -695 -932 187 242 -738 -625 -613 -403 273 468 -160 -573 -276 -208 60 450 429 502 637 619 762 395 679 831 539 484 535 188 -116 -456 114 372 387 595 -802 -1742 -1643 -1771 -1295 -727 -432 -561 -511 -610 -568 23 -440 -330 -495 -1012 -356 220 108 735 727 606 1035 532 219 77 50 516 1009 1494 1830 228 -39 -668 -1026 270 172 593 1028 1095 1156 584 -106 -797 -1358 -1117 -1282 -1079 -867 -1966 -1073 -559 150 705 1256 1536 1200 684 18 -532 -529 -629 -380 522 1291 737 141 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