File name: Pandora166s1_PhiladelphiaPA_20230703_L2Fit_fout2c5d20220925p1-8.txt File generation date: 20230707T063159.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 166 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora166_OF_v5d20210217.txt Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt Level 1 file used: Pandora166s1_PhiladelphiaPA_20230703_L1_smca1c5d20220925p1-8.txt Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE Short location name: PhiladelphiaPA Country of location: United States Location latitude [deg]: 39.9919 Location longitude [deg]: -75.0811 Location altitude [m]: 6 Local noon date: 20230703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: HCHO modification of session 4 "Field cal based on session3" First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0654 305.2061 305.3468 305.4875 305.6282 305.7689 305.9096 306.0503 306.1910 306.3316 306.4722 306.6129 306.7535 306.8941 307.0347 307.1753 307.3158 307.4564 307.5969 307.7375 307.8780 308.0185 308.1590 308.2995 308.4400 308.5805 308.7209 308.8614 309.0018 309.1422 309.2827 309.4231 309.5635 309.7038 309.8442 309.9846 310.1249 310.2652 310.4056 310.5459 310.6862 310.8265 310.9668 311.1070 311.2473 311.3875 311.5278 311.6680 311.8082 311.9484 312.0886 312.2288 312.3690 312.5091 312.6493 312.7894 312.9295 313.0696 313.2097 313.3498 313.4899 313.6300 313.7700 313.9101 314.0501 314.1901 314.3301 314.4701 314.6101 314.7501 314.8901 315.0300 315.1700 315.3099 315.4498 315.5897 315.7296 315.8695 316.0094 316.1493 316.2891 316.4290 316.5688 316.7086 316.8484 316.9882 317.1280 317.2678 317.4076 317.5473 317.6871 317.8268 317.9665 318.1062 318.2459 318.3856 318.5253 318.6650 318.8046 318.9443 319.0839 319.2235 319.3631 319.5027 319.6423 319.7819 319.9215 320.0610 320.2006 320.3401 320.4796 320.6191 320.7586 320.8981 321.0376 321.1770 321.3165 321.4559 321.5954 321.7348 321.8742 322.0136 322.1530 322.2923 322.4317 322.5711 322.7104 322.8497 322.9891 323.1284 323.2677 323.4069 323.5462 323.6855 323.8247 323.9640 324.1032 324.2424 324.3816 324.5208 324.6600 324.7992 324.9383 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230703T104840.3Z 8584.450466 219 1 50.00 2 78.36 69.70 105.62 245.92 0.00 1 0.00 1 0 25 4.959e-01 2.189e-02 3.289e-01 1.448e-02 5.951109e-01 8.143347e-03 6.518526e-03 -6.000000e+00 2.969007e-01 232.86 -2.00 3.49 -2.00 321.32 0.00e+00 8.905281e-03 3.000045e-03 5.314051e-04 -6.000000e+00 1.299725e-02 288.98 -2.00 20.00 -2.00 320.97 0.00e+00 4.794 0.002 302.00 328.00 3 3.5206e+00 2.4517e-02 5.7727e-02 -6.0000e+00 7.5502e-01 1.5554e-01 3.1973e-02 3.2194e-02 -6.0000e+00 8.2318e-01 -2.8523e-01 3.4520e-02 1.7175e-02 -6.0000e+00 4.7477e-01 1.3141e-01 1.7403e-02 5.4977e-03 -6.0000e+00 1.9671e-01 6.7293e-05 -1.2167e-03 4.5903e-04 6.7934e-05 -6.0000e+00 1.4134e-02 -7.3184e-03 -7.0826e-05 12 9 8 11 8 0 70.82 19.76 0.49 -0.00732 -0.01646 16 3 1 5 0 3124.920 26.51 20.00 19.76 31.63 21.3 1079.09 900000 900000 -132698 16402 -118556 900000 900000 -16193 900000 900000 -123768 -191021 -23034 88728 221111 900000 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3477 2778 225 2998 -823 2122 -3201 1201 2100 1780 3626 -1046 2570 -1764 1736 601 1558 1530 -197 -610 -1615 1299 -389 2804 1122 3442 2448 -1181 -571 -2996 -299 -2457 1377 -1111 -398 2809 -2396 1813 1612 550 -453 -417 -1764 -238 2027 -3428 -1045 -931 -381 -605 -2121 -135 -2354 183 -3985 -960 -1422 -800 -2021 376 2243 -212 2273 -380 777 580 -2109 551 1574 369 223 -556 2646 3492 5057 2700 876 -2485 2354 -750 -430 2204 -1852 1504 -1066 953 -339 -577 -2386 -1872 SS 20230703T115457.5Z 8584.496499 257 1 50.24 2 66.14 79.31 116.94 254.65 0.00 1 0.00 1 0 17 2.692e-02 7.179e-03 1.879e-02 2.847e-03 3.263783e-01 1.457572e-03 3.822670e-03 -6.000000e+00 1.574990e-02 232.86 -2.00 3.49 -2.00 318.82 0.00e+00 7.599914e-04 2.785147e-04 1.073597e-04 -6.000000e+00 6.221674e-04 288.98 -2.00 20.00 -2.00 318.48 0.00e+00 2.454 0.000 302.00 328.00 3 4.0223e+00 3.9729e-03 3.0081e-02 -6.0000e+00 3.9910e-02 2.1847e-02 4.4686e-03 1.7114e-02 -6.0000e+00 4.3313e-02 -8.1331e-03 3.1575e-03 8.4451e-03 -6.0000e+00 2.5363e-02 -4.2701e-03 1.6627e-03 2.4150e-03 -6.0000e+00 1.0453e-02 5.4017e-04 -4.8184e-04 8.5386e-05 2.6662e-05 -6.0000e+00 7.4157e-04 -7.8030e-03 -1.2474e-04 11 9 0 11 8 0 99.01 19.75 0.22 -0.00780 -0.01142 25 5 1 5 0 2009.560 26.41 20.00 19.75 33.11 21.4 1090.52 279 -8462 150 -8299 -13846 -9806 -4512 6165 -11580 477 -11586 -63 2704 4055 141 -2664 -805 -5539 2516 -1220 -658 -123 525 1811 -1663 3673 -1557 -918 3039 2907 4039 1398 3331 -1092 305 -1082 -2742 -669 -775 -510 -2213 -183 -1254 115 -1675 -763 28 -1710 -442 652 1279 428 596 1011 -10 1090 -1027 288 588 6 1475 1406 2498 1252 342 -529 -26 -285 1757 1153 30 1131 105 1000 -712 -203 763 141 547 -1169 -1274 -1712 -1628 -1554 -1454 -516 -837 -76 544 680 1039 1052 1054 1073 1135 41 486 842 275 -205 -285 -1104 -264 335 -1263 -1149 -1021 -1367 -350 221 110 -294 -327 -424 361 757 452 847 154 40 -844 73 150 570 780 -3 324 1739 1096 -30 445 -170 -219 546 -67 -141 -202 213 -183 -455 -154 -580 110 12 -446 8 -431 -686 -452 -210 291 -720 28 -769 -4 186 321 13 -290 -92 -694 307 -161 -88 -16 72 258 -260 568 -255 -142 430 412 608 238 607 -216 57 -200 -559 -156 -216 -165 -799 -68 -489 45 -667 -303 11 -670 -170 252 520 189 280 500 -5 571 -558 155 311 3 792 809 1547 839 233 -344 -16 -171 1099 813 23 909 85 780 -529 -137 468 84 337 -820 -1000 -1485 -1506 -1504 -1491 -558 -952 -89 634 770 1104 1037 969 961 1066 43 555 1052 366 -274 -362 -1317 -296 380 -1553 -1486 -1373 -1921 -510 341 179 -488 -532 -659 523 1039 618 1192 230 62 -1369 117 234 862 1130 -4 437 2317 1554 -46 711 -282 -371 948 -123 -270 -394 424 -366 -900 -295 -1081 201 SS 20230703T120611.0Z 8584.504294 265 1 48.76 2 64.03 80.94 118.91 256.12 0.00 1 0.00 1 0 17 1.121e-02 6.095e-03 1.448e-03 3.400e-04 3.002865e-01 1.739876e-04 3.529434e-03 -6.000000e+00 6.559194e-03 232.86 -2.00 3.49 -2.00 317.98 0.00e+00 6.128152e-04 2.670637e-05 7.846152e-05 -6.000000e+00 2.589399e-04 288.98 -2.00 20.00 -2.00 317.64 0.00e+00 2.269 0.000 302.00 328.00 3 5.2930e-01 4.6741e-04 2.7730e-02 -6.0000e+00 1.6621e-02 1.5430e-02 5.2223e-04 1.5662e-02 -6.0000e+00 1.8035e-02 -1.4076e-02 3.3468e-04 7.6732e-03 -6.0000e+00 1.0561e-02 1.1107e-03 1.6998e-04 2.1662e-03 -6.0000e+00 4.3548e-03 2.2228e-02 -1.3058e-04 1.0021e-05 2.3756e-05 -6.0000e+00 3.0859e-04 -8.3425e-03 -5.5413e-06 12 1 1 12 1 1 94.04 19.75 0.21 -0.00834 -0.00932 760 143 1 5 0 63.850 26.41 19.99 19.75 33.80 21.4 1096.06 -1350 117 -1288 -2538 -4002 -3244 -1372 -1579 -211 -2974 -3382 -3322 -2178 -1078 -478 -253 -468 872 652 1255 116 32 1175 750 527 -12 -256 -1449 -1074 368 931 1407 1545 -965 -3278 -2074 -2337 -1157 -432 -767 -1223 -1104 -586 -771 -66 -248 -770 -289 -1010 148 849 883 1166 1295 863 982 445 -82 215 334 1107 1755 1996 1965 104 -233 -228 -288 1446 977 560 568 273 522 -50 -312 -487 -804 -116 -638 -1272 -1294 -2267 -1598 -940 -687 -215 91 386 303 348 260 170 745 477 184 459 922 -51 -427 -405 -854 -332 143 -944 -1232 -883 -872 -266 294 296 140 197 113 78 462 533 321 383 -27 -381 60 444 353 608 244 382 1367 653 298 -57 -343 -142 95 -131 -294 -109 330 -101 -191 -182 -426 -223 -102 10 -111 -209 -300 -231 -101 -131 -19 -296 -338 -343 -251 -143 -67 -39 -77 149 117 232 22 6 227 154 114 -3 -59 -317 -220 74 197 325 389 -258 -850 -519 -635 -363 -162 -314 -554 -526 -287 -383 -33 -123 -379 -139 -482 71 424 476 667 782 543 632 294 -55 139 215 726 1227 1418 1498 82 -172 -167 -206 1007 773 490 521 252 464 -42 -235 -357 -561 -84 -486 -1105 -1248 -2225 -1638 -1023 -800 -248 109 460 351 398 272 174 733 464 199 552 1156 -69 -579 -517 -1007 -389 170 -1153 -1605 -1200 -1243 -375 440 472 229 312 169 113 628 715 449 540 -41 -595 92 663 507 878 337 501 1770 908 449 -87 -538 -228 158 -218 -520 -198 610 -190 -351 -322 -726 -390 SS 20230703T121123.2Z 8584.507907 268 1 50.13 2 63.04 81.70 119.83 256.80 0.00 1 0.00 1 0 17 1.098e-02 6.126e-03 1.159e-03 2.804e-04 2.902659e-01 1.433325e-04 3.413223e-03 -6.000000e+00 6.429695e-03 232.86 -2.00 3.49 -2.00 317.89 0.00e+00 5.232070e-04 2.135090e-05 7.179204e-05 -6.000000e+00 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