File name: Pandora166s1_PhiladelphiaPA_20230901_L2Fit_fwvt1c5d20220925p1-8.txt File generation date: 20230903T012245.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 166 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora166_OF_v5d20210217.txt Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt Level 1 file used: Pandora166s1_PhiladelphiaPA_20230901_L1_smca1c5d20220925p1-8.txt Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE Short location name: PhiladelphiaPA Country of location: United States Location latitude [deg]: 39.9919 Location longitude [deg]: -75.0811 Location altitude [m]: 6 Local noon date: 20230901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: HCHO modification of session 4 "Field cal based on session3" First and last pixel inside fitting window: 1645 1794 Nominal wavelengths inside fitting window [nm]: 492.1120 492.2329 492.3538 492.4746 492.5954 492.7162 492.8370 492.9578 493.0786 493.1993 493.3201 493.4408 493.5615 493.6821 493.8028 493.9234 494.0441 494.1647 494.2853 494.4058 494.5264 494.6469 494.7674 494.8880 495.0084 495.1289 495.2494 495.3698 495.4902 495.6106 495.7310 495.8514 495.9717 496.0921 496.2124 496.3327 496.4530 496.5732 496.6935 496.8137 496.9339 497.0541 497.1743 497.2945 497.4146 497.5348 497.6549 497.7750 497.8951 498.0151 498.1352 498.2552 498.3752 498.4952 498.6152 498.7351 498.8551 498.9750 499.0949 499.2148 499.3347 499.4545 499.5744 499.6942 499.8140 499.9338 500.0536 500.1733 500.2930 500.4128 500.5325 500.6521 500.7718 500.8915 501.0111 501.1307 501.2503 501.3699 501.4895 501.6090 501.7285 501.8480 501.9675 502.0870 502.2065 502.3259 502.4454 502.5648 502.6842 502.8035 502.9229 503.0422 503.1615 503.2809 503.4001 503.5194 503.6387 503.7579 503.8771 503.9963 504.1155 504.2347 504.3538 504.4729 504.5921 504.7112 504.8302 504.9493 505.0683 505.1874 505.3064 505.4254 505.5444 505.6633 505.7823 505.9012 506.0201 506.1390 506.2578 506.3767 506.4955 506.6143 506.7331 506.8519 506.9707 507.0894 507.2082 507.3269 507.4456 507.5643 507.6829 507.8016 507.9202 508.0388 508.1574 508.2760 508.3945 508.5131 508.6316 508.7501 508.8686 508.9870 509.1055 509.2239 509.3423 509.4607 509.5791 509.6975 509.8158 509.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230901T113256.5Z 8644.481210 237 1 7.68 2 78.49 88.81 84.14 260.64 0.00 1 0.00 1 0 15 3.217e-03 3.191e-03 5.463e-04 5.457e-04 2.910704e+03 3.326896e+01 2.039373e+02 -6.000000e+00 1.813954e+02 289.67 -2.00 20.00 -2.00 505.28 0.00e+00 1.057980e-03 1.520830e-05 6.169666e-05 -6.000000e+00 9.137915e-05 289.67 -2.00 20.00 -2.00 500.56 0.00e+00 3.181731e-01 1.066207e-02 2.168456e-02 -6.000000e+00 6.354048e-02 230.42 -2.00 3.49 -2.00 502.14 0.00e+00 4.843 0.002 489.00 513.00 1 3.8350e+00 8.1789e-04 7.3344e-03 -6.0000e+00 4.8752e-03 2.3785e-05 2.1224e-04 6.1213e-04 -6.0000e+00 1.2743e-03 2.0334e-02 8.3715e-05 5.1969e-05 3.0913e-05 -6.0000e+00 3.1421e-04 -3.5790e-03 -1.1938e-04 12 1 1 12 1 1 99.95 19.39 1.55 -0.00358 -0.00300 27 33 1 4 0 274.260 26.21 20.01 19.39 22.49 22.2 974.82 -771 -524 -72 35 178 572 506 583 382 240 186 44 -70 -129 -234 -171 -6 207 177 54 160 154 258 338 286 264 292 28 -411 -601 -575 -614 -257 80 32 92 230 74 -100 -105 -42 -4 85 306 365 383 309 273 125 -196 -569 -738 -856 -607 -328 -177 -62 161 75 243 270 368 417 366 204 173 102 -77 -183 -395 -465 -282 -188 -87 -3 -118 -311 -273 -209 -488 -461 -481 -422 -220 -11 -111 -82 -107 -114 -88 177 295 328 208 362 328 37 -139 -333 -596 -655 -570 -237 3 -169 -216 -194 -353 -217 -75 -146 -45 217 329 370 570 613 618 384 343 184 165 191 317 170 156 264 128 243 194 -51 -212 -90 -287 -284 -27 -76 -6 99 298 130 254 304 307 313 24 -233 -383 -405 -635 -733 -507 -71 35 180 588 517 599 392 243 190 45 -70 -129 -235 -169 -6 213 182 56 167 160 269 353 294 272 305 28 -413 -601 -568 -610 -261 82 33 95 236 76 -103 -107 -43 -4 86 315 378 397 319 278 127 -195 -565 -717 -828 -593 -322 -179 -62 164 76 246 273 375 425 373 206 172 102 -76 -180 -384 -449 -273 -184 -87 -3 -117 -303 -268 -203 -475 -451 -464 -410 -215 -11 -111 -80 -105 -112 -87 175 296 334 208 363 324 36 -135 -321 -567 -624 -540 -232 3 -168 -215 -195 -350 -213 -75 -144 -45 219 336 372 575 621 627 387 348 184 162 188 312 169 155 262 127 240 191 -51 -210 -87 -277 -274 -27 -75 -6 98 298 131 257 309 313 319 24 -232 -380 -395 -619 SQ 20230901T114042.5Z 8644.486603 243 1 51.66 2 77.00 90.06 85.53 261.90 0.00 1 0.00 1 0 15 3.084e-03 3.064e-03 1.398e-03 1.394e-03 2.675239e+03 8.667813e+01 1.888623e+02 -6.000000e+00 1.739000e+02 289.67 -2.00 20.00 -2.00 505.33 0.00e+00 9.421598e-04 3.884528e-05 5.412227e-05 -6.000000e+00 8.759786e-05 289.67 -2.00 20.00 -2.00 500.48 0.00e+00 3.742471e-01 2.739662e-02 1.980362e-02 -6.000000e+00 6.088964e-02 230.42 -2.00 3.49 -2.00 502.10 0.00e+00 4.328 0.001 489.00 513.00 1 7.0394e+00 2.1001e-03 6.5573e-03 -6.0000e+00 4.6722e-03 -1.2683e-03 5.4420e-04 5.5832e-04 -6.0000e+00 1.2206e-03 8.8621e-04 -3.1585e-04 1.3253e-04 2.6689e-05 -6.0000e+00 3.0120e-04 -9.4385e-03 -5.1459e-05 10 0 0 10 0 0 99.68 19.39 1.64 -0.00944 -0.01163 13 2 1 4 0 3973.720 26.21 20.00 19.39 22.64 22.2 976.03 -677 -697 100 35 184 419 511 315 541 200 584 130 -162 -12 -266 -28 -379 -45 484 91 39 -239 393 285 348 195 410 55 -307 -379 -262 -468 13 200 -84 -214 -120 12 -250 -179 61 -303 232 141 213 214 106 38 147 -262 -510 -512 -644 -171 -169 -379 -56 79 -304 181 335 252 279 354 197 122 327 -21 -304 -308 -456 -197 177 -18 -44 -194 188 -97 -522 -489 -201 -360 -160 -454 -78 -222 -196 -216 -144 -153 159 300 506 288 188 305 43 -149 -425 -441 -610 -702 -162 88 90 -207 -369 -370 -86 -66 -141 89 -68 69 412 354 731 367 459 152 231 50 156 92 90 376 120 328 325 154 12 -42 -118 -713 -421 -240 -208 -170 316 389 319 100 228 405 46 231 102 -356 -410 -325 -622 -654 96 35 188 437 541 335 573 210 601 132 -163 -12 -264 -28 -386 -47 513 97 42 -259 422 308 378 212 442 59 -319 -382 -260 -469 13 212 -86 -220 -123 12 -265 -189 65 -304 234 144 220 221 108 39 145 -269 -510 -501 -626 -168 -170 -372 -56 80 -307 182 336 254 282 357 198 121 317 -20 -289 -308 -453 -185 168 -17 -43 -187 177 -90 -511 -479 -186 -336 -150 -432 -75 -214 -190 -210 -140 -149 156 298 507 290 187 298 42 -139 -389 -397 -550 -645 -153 86 90 -208 -367 -362 -84 -65 -140 90 -70 71 426 368 762 384 475 155 232 50 155 91 90 375 120 327 323 153 12 -41 -114 -681 -401 -232 -206 -171 321 399 329 98 225 401 46 226 104 -356 -403 -318 SQ 20230901T120854.9Z 8644.506191 259 1 5.89 2 71.61 94.66 90.64 266.41 0.00 1 0.00 1 0 15 2.520e-03 2.505e-03 8.769e-05 8.757e-05 2.003128e+03 5.238203e+00 1.423524e+02 -6.000000e+00 1.420932e+02 289.67 -2.00 20.00 -2.00 505.28 0.00e+00 7.210881e-04 2.437724e-06 4.247553e-05 -6.000000e+00 7.157904e-05 289.67 -2.00 20.00 -2.00 500.51 0.00e+00 1.410380e-01 1.714141e-03 1.492189e-02 -6.000000e+00 4.976474e-02 230.42 -2.00 3.49 -2.00 502.10 0.00e+00 3.128 0.001 489.00 513.00 1 1.0954e-01 1.3151e-04 4.7665e-03 -6.0000e+00 3.8184e-03 4.9197e-03 3.4204e-05 4.1152e-04 -6.0000e+00 9.9784e-04 1.0990e+00 -4.3998e-05 8.3420e-06 2.1255e-05 -6.0000e+00 2.4613e-04 -9.4656e-03 -6.8890e-05 10 0 0 10 0 0 13.74 19.39 1.81 -0.00947 -0.00977 1229 222 1 4 0 4.790 26.21 20.00 19.39 24.74 22.3 993.18 -448 -373 -134 -7 136 454 465 429 394 277 250 96 -164 -207 -242 -247 -65 107 120 17 139 193 130 273 294 257 288 90 -290 -378 -320 -376 -106 196 17 -51 76 1 -187 -158 -97 -12 87 238 245 269 270 166 59 -259 -496 -569 -637 -439 -251 -165 -87 8 52 120 218 237 236 240 169 89 37 -40 -177 -322 -247 -166 -127 83 12 -171 -150 -167 -211 -299 -242 -306 -338 -90 -45 -176 -192 -137 -133 -105 7 211 258 212 289 288 19 -154 -295 -510 -548 -411 -181 -34 -200 -194 -132 -263 -149 -95 -108 -31 155 245 307 482 512 464 316 287 202 107 249 270 81 169 261 156 266 257 -25 -108 -108 -315 -298 -57 -112 -162 32 134 113 204 329 273 263 78 -145 -301 -336 -390 -439 -359 -134 -7 138 470 489 453 415 288 256 97 -164 -204 -246 -244 -65 110 127 17 143 199 134 283 306 267 297 95 -298 -376 -315 -372 -108 205 17 -53 79 1 -189 -164 -100 -12 89 245 255 280 279 169 59 -262 -488 -547 -608 -424 -249 -169 -87 8 52 121 220 241 240 244 170 89 38 -40 -175 -315 -240 -162 -125 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20230901T183948.4Z 8644.777643 454 10 5.92 2 38.80 221.62 141.20 2.85 0.00 1 0.00 1 0 15 2.107e-03 2.096e-03 1.036e-04 1.034e-04 1.073018e+03 6.001936e+00 7.901671e+01 -6.000000e+00 1.188166e+02 289.65 -2.00 20.00 -2.00 505.25 0.00e+00 5.389036e-04 2.875637e-06 3.200447e-05 -6.000000e+00 5.985250e-05 289.65 -2.00 20.00 -2.00 500.44 0.00e+00 -5.474295e-02 2.029309e-03 8.330841e-03 -6.000000e+00 4.160314e-02 230.40 -2.00 3.49 -2.00 502.03 0.00e+00 1.282 0.000 489.00 513.00 1 -4.2334e-01 1.5578e-04 2.1062e-03 -6.0000e+00 3.1923e-03 7.0057e-03 4.0664e-05 2.0259e-04 -6.0000e+00 8.3392e-04 2.4838e+00 -4.4640e-06 9.8479e-06 1.3977e-05 -6.0000e+00 2.0581e-04 -1.1115e-02 -3.7138e-05 10 0 0 10 0 0 20.59 19.65 2.04 -0.01112 -0.01115 1031 186 2 4 0 5.710 26.41 20.00 19.65 36.84 23.3 1080.94 -394 -261 -132 3 115 391 409 332 346 212 254 64 -123 -132 -194 -158 -72 127 37 -18 108 147 123 215 269 174 256 48 -276 -315 -271 -303 -100 189 -41 -68 77 16 -125 -143 -23 -38 97 184 189 243 228 175 41 -210 -428 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-162 59 133 74 211 272 278 201 33 -144 -255 -247 -329 SQ 20230901T184358.9Z 8644.780542 457 1 5.93 2 39.34 223.02 141.14 4.44 0.00 1 0.00 1 0 15 2.110e-03 2.097e-03 1.038e-04 1.036e-04 1.061899e+03 6.007077e+00 7.795475e+01 -6.000000e+00 1.189347e+02 289.65 -2.00 20.00 -2.00 505.25 0.00e+00 5.243821e-04 2.880327e-06 3.104481e-05 -6.000000e+00 5.991196e-05 289.65 -2.00 20.00 -2.00 500.44 0.00e+00 -5.524150e-02 2.032909e-03 8.232971e-03 -6.000000e+00 4.164396e-02 230.40 -2.00 3.49 -2.00 502.03 0.00e+00 1.292 0.000 489.00 513.00 1 -4.1948e-01 1.5602e-04 2.1080e-03 -6.0000e+00 3.1955e-03 6.9466e-03 4.0764e-05 2.0154e-04 -6.0000e+00 8.3473e-04 2.4714e+00 -3.3859e-05 9.8640e-06 1.3603e-05 -6.0000e+00 2.0601e-04 -1.0864e-02 -3.7670e-05 10 0 0 10 0 0 33.92 19.66 2.03 -0.01086 -0.01110 1024 185 2 4 0 5.750 26.41 20.00 19.66 36.91 23.2 1080.69 -376 -320 -109 -5 114 380 389 342 332 233 245 73 -135 -129 -198 -173 -33 86 76 -24 97 161 102 217 249 216 227 30 -290 -299 -261 -307 -76 173 -39 -60 72 12 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123 168 226 385 431 337 240 239 169 111 229 244 57 143 229 125 253 231 -50 -79 -82 -273 -205 21 -90 -149 47 119 72 190 289 251 220 25 -147 -248 -253 -299 SQ 20230901T184410.9Z 8644.780681 457 3 5.96 2 39.37 223.09 141.13 4.51 0.00 1 0.00 1 0 15 2.121e-03 2.109e-03 1.037e-04 1.035e-04 1.065657e+03 6.006991e+00 7.916490e+01 -6.000000e+00 1.195667e+02 289.65 -2.00 20.00 -2.00 505.25 0.00e+00 5.313968e-04 2.879845e-06 3.153252e-05 -6.000000e+00 6.023038e-05 289.65 -2.00 20.00 -2.00 500.44 0.00e+00 -5.437188e-02 2.032598e-03 8.133546e-03 -6.000000e+00 4.186564e-02 230.40 -2.00 3.49 -2.00 502.03 0.00e+00 1.292 0.000 489.00 513.00 1 -4.1988e-01 1.5600e-04 2.1103e-03 -6.0000e+00 3.2125e-03 6.9257e-03 4.0758e-05 2.0031e-04 -6.0000e+00 8.3918e-04 2.4718e+00 -1.6481e-05 9.8609e-06 1.3867e-05 -6.0000e+00 2.0711e-04 -1.0724e-02 -3.9209e-05 10 0 0 10 0 0 12.48 19.66 2.03 -0.01072 -0.01084 1024 185 2 4 0 5.750 26.41 20.00 19.66 36.91 23.2 1080.69 -354 -297 -105 -18 98 384 400 357 345 234 233 75 -137 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20230901T194549.9Z 8644.823494 488 7 5.99 2 48.69 240.59 137.79 26.63 0.00 1 0.00 1 0 15 2.234e-03 2.225e-03 7.562e-05 7.549e-05 1.280063e+03 4.409814e+00 9.386619e+01 -6.000000e+00 1.259692e+02 289.65 -2.00 20.00 -2.00 505.26 0.00e+00 5.805275e-04 2.096545e-06 3.436708e-05 -6.000000e+00 6.345568e-05 289.65 -2.00 20.00 -2.00 500.46 0.00e+00 -2.833963e-02 1.478669e-03 9.659432e-03 -6.000000e+00 4.410332e-02 230.39 -2.00 3.49 -2.00 502.05 0.00e+00 1.512 0.000 489.00 513.00 1 4.5194e-02 1.1342e-04 2.4531e-03 -6.0000e+00 3.3843e-03 5.6085e-03 2.9604e-05 2.4028e-04 -6.0000e+00 8.8394e-04 1.5000e+00 -5.3238e-05 7.2161e-06 1.5714e-05 -6.0000e+00 2.1818e-04 -9.7482e-03 -3.7438e-05 10 0 0 10 0 0 76.00 19.72 1.97 -0.00975 -0.01012 1903 344 1 4 0 3.090 26.51 20.00 19.72 37.26 23.1 1081.58 -397 -319 -106 6 118 427 403 370 345 230 240 59 -128 -137 -172 -168 -13 126 70 -3 121 165 101 222 253 212 231 19 -298 -386 -317 -369 -104 151 -13 -50 104 48 -140 -93 -32 -9 103 202 222 238 269 188 64 -239 -449 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-286 -301 -67 -73 -151 -161 -103 -109 -63 57 249 265 197 277 300 25 -133 -291 -503 -532 -384 -183 -73 -248 -201 -137 -257 -108 -102 -124 -18 150 224 278 459 482 412 277 262 192 118 267 255 74 157 234 161 255 243 -48 -115 -107 -309 -252 -15 -101 -146 67 149 91 193 315 268 235 36 -173 -305 -320 -358 -402 -336 -104 -5 149 452 451 418 390 257 248 51 -153 -166 -231 -218 -49 115 86 -4 133 187 153 272 289 252 272 38 -309 -361 -310 -360 -74 178 -1 -44 100 4 -174 -133 -82 -6 117 243 260 266 287 174 33 -263 -467 -539 -593 -387 -231 -165 -89 -22 32 121 224 233 231 218 157 91 43 -55 -206 -304 -227 -148 -120 64 -6 -173 -131 -143 -209 -268 -226 -272 -288 -65 -71 -149 -159 -102 -108 -62 57 252 263 195 281 298 24 -126 -280 -478 -506 -359 -177 -73 -246 -198 -133 -255 -107 -102 -121 -17 151 226 282 467 493 422 281 262 189 115 258 248 72 154 228 157 248 236 -46 -113 -104 -295 -241 -14 -97 -142 67 149 91 194 318 272 239 36 -171 -295 -304 -339 SQ 20230901T212818.3Z 8644.894656 543 2 5.97 2 67.22 261.24 125.03 54.80 0.00 1 0.00 1 0 15 2.380e-03 2.369e-03 7.011e-05 7.000e-05 2.355142e+03 4.231023e+00 1.678313e+02 -6.000000e+00 1.341845e+02 289.64 -2.00 20.00 -2.00 505.27 0.00e+00 7.773052e-04 1.946514e-06 4.564684e-05 -6.000000e+00 6.759433e-05 289.64 -2.00 20.00 -2.00 500.49 0.00e+00 9.251334e-02 1.372912e-03 1.693550e-02 -6.000000e+00 4.697855e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.562 0.000 489.00 513.00 1 -2.5656e-01 1.0530e-04 4.0875e-03 -6.0000e+00 3.6049e-03 3.8911e-03 2.7372e-05 4.3250e-04 -6.0000e+00 9.4153e-04 1.7219e+00 7.9382e-05 6.6837e-06 2.4296e-05 -6.0000e+00 2.3241e-04 -1.0452e-02 -3.0522e-05 10 0 0 10 0 0 24.38 19.80 1.85 -0.01045 -0.00990 2014 364 1 4 0 2.920 26.51 19.99 19.80 37.75 23.1 1085.82 -427 -340 -117 1 122 441 443 400 368 251 235 60 -147 -178 -212 -209 -47 109 77 -14 130 172 137 261 286 228 249 39 -299 -355 -309 -358 -85 178 1 -39 100 -7 -174 -131 -70 -7 118 237 253 274 277 161 41 -273 -459 -539 -603 -386 -235 -150 -98 -22 35 113 221 234 219 202 151 94 38 -57 -197 -307 -225 -155 -110 57 3 -185 -136 -137 -218 -275 -240 -299 -302 -78 -59 -150 -173 -116 -103 -88 61 248 264 182 282 282 33 -152 -287 -493 -508 -389 -179 -69 -227 -194 -138 -244 -113 -81 -118 -24 156 220 290 451 471 408 277 250 190 124 273 256 89 177 231 151 250 230 -40 -106 -110 -316 -235 -38 -109 -147 59 136 99 202 313 266 235 33 -178 -306 -334 -352 -411 -334 -114 1 126 448 458 415 380 257 244 61 -149 -178 -212 -210 -48 110 79 -15 136 180 143 274 301 240 261 41 -300 -359 -309 -360 -84 183 1 -42 104 -7 -178 -133 -71 -7 122 248 267 289 290 166 41 -270 -457 -526 -584 -379 -229 -150 -100 -22 36 116 227 241 226 208 154 94 37 -56 -191 -304 -222 -153 -106 56 3 -181 -131 -134 -212 -266 -234 -284 -289 -75 -58 -148 -171 -115 -102 -87 61 251 261 181 285 281 32 -145 -277 -469 -483 -364 -173 -69 -224 -191 -134 -242 -111 -80 -115 -24 156 222 294 460 481 417 281 249 187 120 263 248 87 173 226 147 243 223 -39 -104 -106 -303 -225 -37 -104 -143 58 136 100 203 316 270 238 34 -176 -295 -317 -334 SQ 20230901T212824.3Z 8644.894726 543 3 5.97 2 67.24 261.26 125.02 54.82 0.00 1 0.00 1 0 15 2.395e-03 2.385e-03 7.019e-05 7.007e-05 2.352671e+03 4.236029e+00 1.681347e+02 -6.000000e+00 1.350218e+02 289.64 -2.00 20.00 -2.00 505.27 0.00e+00 7.849157e-04 1.948747e-06 4.616968e-05 -6.000000e+00 6.801606e-05 289.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.660810e-02 1.374616e-03 1.686264e-02 -6.000000e+00 4.727133e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.564 0.000 489.00 513.00 1 -2.5600e-01 1.0543e-04 4.0914e-03 -6.0000e+00 3.6274e-03 3.8080e-03 2.7402e-05 4.3125e-04 -6.0000e+00 9.4739e-04 1.7197e+00 7.4662e-05 6.6900e-06 2.4475e-05 -6.0000e+00 2.3386e-04 -1.0514e-02 -2.9631e-05 10 0 0 10 0 0 28.51 19.80 1.85 -0.01051 -0.01000 2014 364 1 4 0 2.920 26.51 19.99 19.80 37.75 23.1 1085.82 -439 -335 -113 -5 132 435 452 400 366 260 238 53 -162 -184 -228 -196 -52 109 80 1 138 177 127 254 277 249 266 46 -301 -361 -307 -355 -83 165 3 -40 88 2 -182 -133 -54 -11 114 235 247 267 274 158 42 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-105 -299 -235 -37 -97 -149 62 140 99 206 322 282 241 36 -181 -300 -314 -339 SQ 20230901T212830.3Z 8644.894795 543 4 5.97 2 67.26 261.28 125.00 54.84 0.00 1 0.00 1 0 15 2.387e-03 2.376e-03 7.022e-05 7.010e-05 2.364227e+03 4.240563e+00 1.692090e+02 -6.000000e+00 1.345490e+02 289.64 -2.00 20.00 -2.00 505.27 0.00e+00 7.819545e-04 1.949039e-06 4.595332e-05 -6.000000e+00 6.777794e-05 289.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.392572e-02 1.375431e-03 1.685676e-02 -6.000000e+00 4.710633e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.566 0.000 489.00 513.00 1 -2.5529e-01 1.0547e-04 4.0927e-03 -6.0000e+00 3.6147e-03 3.8444e-03 2.7420e-05 4.3212e-04 -6.0000e+00 9.4409e-04 1.7184e+00 9.0998e-05 6.6866e-06 2.4510e-05 -6.0000e+00 2.3304e-04 -1.0552e-02 -3.0175e-05 10 0 0 10 0 0 27.74 19.80 1.85 -0.01055 -0.00992 2014 364 1 4 0 2.920 26.51 19.99 19.80 37.75 23.1 1085.82 -426 -326 -107 -5 127 446 447 401 372 250 232 58 -163 -178 -222 -208 -37 106 86 4 126 187 117 256 276 238 265 35 -294 -359 -294 -358 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419 279 256 180 119 245 244 80 175 230 148 249 223 -53 -99 -101 -284 -245 -40 -99 -126 60 141 102 201 326 270 234 40 -164 -298 -311 -333 SQ 20230901T212836.4Z 8644.894865 543 5 5.94 2 67.28 261.29 124.99 54.87 0.00 1 0.00 1 0 15 2.394e-03 2.384e-03 7.025e-05 7.013e-05 2.366275e+03 4.242671e+00 1.694474e+02 -6.000000e+00 1.349803e+02 289.64 -2.00 20.00 -2.00 505.27 0.00e+00 7.791952e-04 1.949858e-06 4.586188e-05 -6.000000e+00 6.799521e-05 289.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.498059e-02 1.376013e-03 1.684686e-02 -6.000000e+00 4.725725e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.568 0.000 489.00 513.00 1 -2.5480e-01 1.0552e-04 4.0945e-03 -6.0000e+00 3.6263e-03 3.8176e-03 2.7431e-05 4.3228e-04 -6.0000e+00 9.4711e-04 1.7170e+00 8.6212e-05 6.6888e-06 2.4514e-05 -6.0000e+00 2.3379e-04 -1.0390e-02 -3.1034e-05 10 0 0 10 0 0 29.22 19.80 1.85 -0.01039 -0.00979 2014 364 1 4 0 2.920 26.51 19.99 19.80 37.75 23.1 1085.82 -434 -334 -105 0 134 437 444 413 389 253 231 60 -158 -179 -215 -214 -46 118 90 6 130 181 123 246 278 229 259 22 -312 -364 -300 -353 -88 170 -15 -54 84 15 -170 -128 -49 -2 116 234 248 265 260 169 43 -274 -477 -556 -599 -397 -238 -169 -94 -23 32 107 230 232 219 227 147 92 24 -50 -202 -310 -229 -155 -119 70 -15 -181 -120 -143 -195 -273 -241 -311 -320 -83 -49 -142 -150 -102 -100 -84 50 241 262 211 282 281 33 -140 -283 -497 -524 -391 -177 -74 -234 -209 -155 -244 -109 -75 -124 -25 131 218 296 465 475 394 283 262 187 119 238 251 83 172 239 155 263 240 -56 -108 -106 -314 -240 -42 -98 -138 59 134 103 199 322 271 237 33 -164 -305 -323 -348 -418 -329 -103 0 138 460 458 428 402 258 241 62 -160 -180 -215 -216 -47 119 93 6 136 190 129 259 293 241 271 23 -314 -367 -300 -355 -88 175 -16 -57 88 16 -174 -130 -50 -2 120 245 261 280 272 175 43 -271 -475 -542 -580 -389 -239 -169 -96 -24 32 109 236 238 226 234 150 92 24 -49 -196 -307 -226 -153 -115 68 -15 -177 -115 -140 -189 -265 -235 -295 -307 -80 -48 -140 -148 -100 -98 -84 50 244 259 209 286 279 32 -133 -273 -472 -498 -365 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-153 -113 -107 -77 47 244 253 179 290 271 25 -132 -270 -472 -495 -360 -176 -61 -247 -198 -131 -252 -110 -60 -118 -27 144 230 307 478 482 406 285 265 186 114 244 250 83 172 237 157 256 217 -51 -114 -96 -303 -228 -41 -103 -137 67 144 105 196 319 286 235 33 -175 -290 -308 -339 SQ 20230901T212848.4Z 8644.895004 543 7 5.94 2 67.32 261.33 124.96 54.91 0.00 1 0.00 1 0 15 2.383e-03 2.373e-03 7.030e-05 7.018e-05 2.366250e+03 4.244195e+00 1.688103e+02 -6.000000e+00 1.343685e+02 289.64 -2.00 20.00 -2.00 505.26 0.00e+00 7.870287e-04 1.949325e-06 4.621555e-05 -6.000000e+00 6.768692e-05 289.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.695889e-02 1.375046e-03 1.696003e-02 -6.000000e+00 4.704254e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.572 0.000 489.00 513.00 1 -2.5427e-01 1.0542e-04 4.1046e-03 -6.0000e+00 3.6098e-03 3.8137e-03 2.7433e-05 4.3346e-04 -6.0000e+00 9.4280e-04 1.7147e+00 5.5678e-05 6.6923e-06 2.4352e-05 -6.0000e+00 2.3273e-04 -1.0564e-02 -2.9266e-05 10 0 0 10 0 0 19.17 19.80 1.85 -0.01056 -0.01018 2014 364 1 4 0 2.920 26.51 19.99 19.80 37.75 23.1 1085.82 -419 -344 -110 -13 121 436 439 421 374 257 237 40 -156 -169 -228 -214 -39 116 86 3 128 181 119 257 284 238 258 22 -301 -360 -294 -360 -76 164 -5 -51 92 8 -170 -135 -62 -3 116 236 229 267 267 169 53 -267 -464 -547 -595 -390 -233 -152 -90 -17 33 124 218 229 207 218 143 83 32 -58 -207 -308 -224 -155 -108 75 -7 -190 -144 -131 -194 -284 -232 -300 -311 -82 -71 -144 -152 -117 -110 -60 50 254 260 201 278 280 27 -138 -291 -498 -517 -388 -182 -70 -237 -198 -147 -250 -106 -79 -113 -25 127 227 295 465 489 410 279 263 182 121 249 257 84 168 239 162 256 238 -50 -104 -101 -303 -246 -45 -114 -145 57 130 104 205 315 255 231 37 -174 -304 -318 -347 -403 -338 -108 -14 126 459 453 437 387 262 246 42 -158 -170 -227 -216 -40 118 89 3 134 189 125 269 299 250 270 23 -302 -363 -293 -362 -78 168 -5 -53 96 8 -173 -137 -63 -3 120 246 241 282 279 174 53 -263 -461 -533 -576 -382 -234 -152 -92 -18 34 127 223 236 214 225 146 83 31 -56 -200 -305 -220 -153 -105 73 -7 -186 -138 -128 -188 -276 -226 -295 -297 -79 -69 -142 -150 -115 -109 -59 50 256 257 199 282 278 27 -131 -280 -472 -491 -363 -175 -70 -234 -195 -148 -248 -104 -78 -110 -25 127 229 299 473 499 419 283 262 178 118 240 249 82 164 233 157 249 231 -48 -102 -98 -290 -235 -44 -109 -142 57 130 105 206 318 259 234 37 -172 -293 -301 -328 SQ 20230901T212854.3Z 8644.895073 543 8 5.98 2 67.34 261.35 124.94 54.93 0.00 1 0.00 1 0 15 2.389e-03 2.378e-03 7.031e-05 7.019e-05 2.372071e+03 4.245636e+00 1.690585e+02 -6.000000e+00 1.346681e+02 289.64 -2.00 20.00 -2.00 505.26 0.00e+00 7.923734e-04 1.949664e-06 4.654334e-05 -6.000000e+00 6.783787e-05 289.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.433221e-02 1.375307e-03 1.704083e-02 -6.000000e+00 4.714745e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.574 0.000 489.00 513.00 1 -2.5427e-01 1.0544e-04 4.1114e-03 -6.0000e+00 3.6179e-03 3.8881e-03 2.7438e-05 4.3469e-04 -6.0000e+00 9.4490e-04 1.7144e+00 5.3692e-05 6.6934e-06 2.4434e-05 -6.0000e+00 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20230901T213355.0Z 8644.898553 546 7 5.93 2 68.29 262.21 124.17 56.04 0.00 1 0.00 1 0 15 2.413e-03 2.401e-03 7.117e-05 7.105e-05 2.444856e+03 4.303249e+00 1.748752e+02 -6.000000e+00 1.360153e+02 289.64 -2.00 20.00 -2.00 505.27 0.00e+00 8.028359e-04 1.976112e-06 4.713681e-05 -6.000000e+00 6.851650e-05 289.64 -2.00 20.00 -2.00 500.48 0.00e+00 1.083173e-01 1.393886e-03 1.734323e-02 -6.000000e+00 4.761901e-02 230.39 -2.00 3.49 -2.00 502.07 0.00e+00 2.679 0.000 489.00 513.00 1 -2.4507e-01 1.0686e-04 4.2603e-03 -6.0000e+00 3.6541e-03 3.6285e-03 2.7812e-05 4.4627e-04 -6.0000e+00 9.5435e-04 1.6712e+00 4.7956e-05 6.7839e-06 2.5287e-05 -6.0000e+00 2.3558e-04 -1.0868e-02 -2.7223e-05 10 0 0 10 0 0 12.85 19.80 1.84 -0.01087 -0.01053 1954 353 1 4 0 3.010 26.51 19.99 19.80 37.49 23.2 1084.18 -429 -327 -112 5 112 456 451 414 400 250 241 48 -157 -182 -224 -198 -53 110 83 13 144 183 131 251 272 229 264 33 -306 -365 -309 -365 -78 166 -1 -53 89 -3 -158 -135 -70 -18 120 243 229 274 274 169 45 -266 -486 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