File name: Pandora166s1_PhiladelphiaPA_20240323_L2Fit_fout2c6d20231015p1-8.txt
File generation date: 20241031T043113.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora166_OF_v5d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v6d20231015.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20240323_L1_smca1c6d20231015p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20240323
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0440 305.1847 305.3255 305.4662 305.6069 305.7476 305.8882 306.0289 306.1696 306.3102 306.4509 306.5915 306.7321 306.8727 307.0133 307.1539 307.2945 307.4350 307.5756 307.7161 307.8566 307.9972 308.1377 308.2781 308.4186 308.5591 308.6996 308.8400 308.9804 309.1209 309.2613 309.4017 309.5421 309.6825 309.8228 309.9632 310.1035 310.2439 310.3842 310.5245 310.6648 310.8051 310.9454 311.0857 311.2259 311.3662 311.5064 311.6466 311.7869 311.9271 312.0672 312.2074 312.3476 312.4878 312.6279 312.7680 312.9082 313.0483 313.1884 313.3285 313.4685 313.6086 313.7487 313.8887 314.0288 314.1688 314.3088 314.4488 314.5888 314.7288 314.8687 315.0087 315.1486 315.2886 315.4285 315.5684 315.7083 315.8482 315.9881 316.1279 316.2678 316.4076 316.5475 316.6873 316.8271 316.9669 317.1067 317.2465 317.3862 317.5260 317.6657 317.8055 317.9452 318.0849 318.2246 318.3643 318.5040 318.6436 318.7833 318.9229 319.0626 319.2022 319.3418 319.4814 319.6210 319.7606 319.9001 320.0397 320.1792 320.3188 320.4583 320.5978 320.7373 320.8768 321.0163 321.1557 321.2952 321.4346 321.5740 321.7135 321.8529 321.9923 322.1317 322.2710 322.4104 322.5497 322.6891 322.8284 322.9677 323.1070 323.2463 323.3856 323.5249 323.6642 323.8034 323.9426 324.0819 324.2211 324.3603 324.4995 324.6387 324.7778 324.9170
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240323T211317.8Z 8848.884234 577 1 50.87 2 67.66 252.05 98.06 74.90 0.00 1 0.00 1 0 17 2.221e-02 5.410e-03 1.061e-02 1.018e-03 3.997580e-01 5.162945e-04 4.638391e-03 -6.000000e+00 1.274789e-02 227.00 -2.00 3.49 -2.00 319.32 0.00e+00 1.041823e-03 1.179884e-04 1.697911e-04 -6.000000e+00 5.131044e-04 278.72 -2.00 20.00 -2.00 319.01 0.00e+00 2.608 0.000 302.00 328.00 3 1.9690e+00 1.4097e-03 3.3198e-02 -6.0000e+00 3.1859e-02 4.3708e-02 1.6156e-03 2.0347e-02 -6.0000e+00 3.4693e-02 1.9974e-03 1.2962e-03 1.0382e-02 -6.0000e+00 2.0409e-02 -1.1238e-02 6.9830e-04 3.1250e-03 -6.0000e+00 8.5429e-03 3.2024e-03 -1.3062e-05 3.0246e-05 3.4343e-05 -6.0000e+00 6.1024e-04 -3.7929e-03 0.0000e+00 10 0 0 10 0 0 99.99 19.37 0.13 -0.00379 -0.00389 452 82 1 5 0 112.520 26.21 20.01 19.37 14.84 24.4 995.15 -1593 -4642 -3145 -9421 -3487 -14792 958 -5881 -4252 -3916 -8187 -2210 -5692 -1147 -1124 3173 -1948 1780 81 842 1727 -942 2058 162 -40 -1169 -1828 -136 -3590 674 1264 1867 2070 -437 -2722 -2709 -2497 -1464 -543 -1718 -1255 -1488 -1336 -998 -878 184 -1204 -427 -1082 -578 1077 314 1332 1366 971 1099 658 -149 -227 584 789 1610 2027 2509 345 -695 -149 -862 1194 778 756 900 506 752 5 -293 -760 -760 -559 -550 -908 -1170 -2073 -1742 -823 -668 -226 268 504 550 496 373 -142 404 391 26 580 1065 440 -133 -92 -789 -420 230 -795 -1208 -931 -864 -314 354 355 125 177 27 -79 203 371 146 276 -6 -352 140 392 360 387 141 -109 1039 595 -24 -94 -517 -231 -66 -108 -255 -149 528 43 -50 -68 -217 -112 -41 -141 -100 -309 -98 -444 26 -192 -148 -146 -326 -87 -270 -60 -70 217 -153 143 7 73 153 -86 186 16 -4 -131 -210 -15 -383 72 141 233 288 -66 -406 -392 -388 -262 -117 -426 -348 -440 -411 -312 -276 58 -382 -134 -342 -186 364 117 528 577 432 503 310 -71 -106 266 367 797 1102 1482 207 -418 -84 -481 692 513 532 667 378 539 4 -185 -437 -418 -322 -359 -656 -952 -1849 -1632 -813 -680 -242 296 559 592 516 357 -127 348 357 26 642 1315 592 -182 -118 -937 -475 258 -935 -1519 -1222 -1194 -458 535 577 212 296 43 -117 291 521 212 426 -10 -573 224 606 555 568 198 -147 1427 850 -38 -153 -886 -406 -121 -202 -505 -305 1092 90 -103 -133 -420 -209
SS 20240323T224148.9Z 8848.945705 620 1 51.26 2 84.28 267.16 81.98 89.07 0.00 1 0.00 1 0 25 9.478e-01 9.633e-02 5.403e-01 6.212e-02 1.133566e+00 3.917640e-02 1.223204e-02 -6.000000e+00 5.828548e-01 227.00 -2.00 3.49 -2.00 322.23 0.00e+00 -1.339752e-02 1.367428e-02 1.140971e-03 -6.000000e+00 2.757679e-02 278.72 -2.00 20.00 -2.00 321.82 0.00e+00 8.875 0.013 302.00 328.00 3 4.8674e-01 1.2446e-01 1.0691e-01 -6.0000e+00 1.4573e+00 2.3898e+00 1.4071e-01 5.7610e-02 -6.0000e+00 1.5965e+00 -2.5429e+00 1.0194e-01 3.0631e-02 -6.0000e+00 9.3994e-01 8.8581e-01 5.9476e-02 1.0359e-02 -6.0000e+00 3.9808e-01 1.0299e-05 -4.6646e-04 1.6982e-03 1.4648e-04 -6.0000e+00 2.8945e-02 -1.9159e-04 0.0000e+00 12 8 8 10 0 0 73.38 19.36 0.80 -0.00019 -0.00370 24 4 1 5 0 2135.590 26.21 20.00 19.36 12.84 24.4 979.40 900000 186443 900000 900000 56328 900000 -55900 900000 108643 900000 900000 78925 187581 -10312 900000 25454 900000 77048 900000 214211 -36396 109932 142033 900000 23226 900000 27257 -42231 900000 -52785 900000 -62278 900000 184133 93180 900000 -20509 900000 -61842 900000 55707 40472 274112 39303 129565 -40334 900000 -70546 67011 212232 -15747 109709 -515 307286 -56788 245292 5305 160782 338365 32932 900000 -60088 900000 37260 69315 67952 58772 156653 -29511 89389 -836 56289 62297 97354 437716 -22853 128132 -71016 126328 -42341 98921 4394 12345 27290 -19743 25152 -12819 42861 1107 31817 74940 44844 35667 -3250 20496 -6688 54542 -1340 7643 13319 -7277 10552 -18171 37188 -4271 7284 8202 234 9396 -12993 17761 4253 -5862 -1633 -9153 437 -8497 9891 -8369 4332 5050 5238 6671 -14446 9343 -3324 3476 -2614 7198 -2879 -8778 6081 -2443 4344 -2295 2215 3045 11 2348 -4989 3052 -4553 3131 900000 11244 900000 900000 3397 900000 -7883 900000 6552 900000 900000 4760 11313 -1298 900000 2709 900000 5103 900000 12919 -5543 6630 8566 900000 2039 900000 2119 -5377 900000 -6293 900000 -10322 900000 11105 5620 900000 -2113 900000 -12104 900000 4620 3934 16531 3478 7814 -6351 900000 -14001 4041 12799 -2253 6616 -76 18532 -15682 14793 862 9697 20406 3259 900000 -13584 900000 4288 6347 6321 6003 9448 -7854 8975 -208 8474 8529 8751 26398 -4738 7728 -21885 7619 -13544 10197 1250 3640 7450 -8700 7614 -5638 11387 423 8731 12945 9702 8419 -1180 6909 -3439 18734 -900 5261 8938 -5624 6171 -12253 14285 -2521 4076 4802 160 6672 -13366 15927 4867 -7842 -2132 -12631 538 -11460 11623 -12282 5754 6453 6269 7467 -19224 9652 -3784 3641 -3074 9059 -4762 -17707 11858 -5640 10204 -6228 6095 8492 32 6580 -14287 7419 -10874 6527