File name: Pandora166s1_PhiladelphiaPA_20240612_L2Fit_fout2c5d20220925p1-8.txt
File generation date: 20240613T051005.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora166_OF_v5d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20240612_L1_smca1c5d20220925p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20240612
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: HCHO modification of session 4 "Field cal based on session3"
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0654 305.2061 305.3468 305.4875 305.6282 305.7689 305.9096 306.0503 306.1910 306.3316 306.4722 306.6129 306.7535 306.8941 307.0347 307.1753 307.3158 307.4564 307.5969 307.7375 307.8780 308.0185 308.1590 308.2995 308.4400 308.5805 308.7209 308.8614 309.0018 309.1422 309.2827 309.4231 309.5635 309.7038 309.8442 309.9846 310.1249 310.2652 310.4056 310.5459 310.6862 310.8265 310.9668 311.1070 311.2473 311.3875 311.5278 311.6680 311.8082 311.9484 312.0886 312.2288 312.3690 312.5091 312.6493 312.7894 312.9295 313.0696 313.2097 313.3498 313.4899 313.6300 313.7700 313.9101 314.0501 314.1901 314.3301 314.4701 314.6101 314.7501 314.8901 315.0300 315.1700 315.3099 315.4498 315.5897 315.7296 315.8695 316.0094 316.1493 316.2891 316.4290 316.5688 316.7086 316.8484 316.9882 317.1280 317.2678 317.4076 317.5473 317.6871 317.8268 317.9665 318.1062 318.2459 318.3856 318.5253 318.6650 318.8046 318.9443 319.0839 319.2235 319.3631 319.5027 319.6423 319.7819 319.9215 320.0610 320.2006 320.3401 320.4796 320.6191 320.7586 320.8981 321.0376 321.1770 321.3165 321.4559 321.5954 321.7348 321.8742 322.0136 322.1530 322.2923 322.4317 322.5711 322.7104 322.8497 322.9891 323.1284 323.2677 323.4069 323.5462 323.6855 323.8247 323.9640 324.1032 324.2424 324.3816 324.5208 324.6600 324.7992 324.9383
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240612T120100.6Z 8929.500701 129 1 50.81 2 64.06 80.58 120.56 34.26 0.00 1 0.00 1 0 17 1.583e-02 6.022e-03 1.775e-03 2.932e-04 3.529570e-01 1.506400e-04 4.125697e-03 -6.000000e+00 9.277223e-03 232.79 -2.00 3.49 -2.00 318.46 0.00e+00 8.308513e-04 2.662628e-05 1.113416e-04 -6.000000e+00 3.655994e-04 287.07 -2.00 20.00 -2.00 318.14 0.00e+00 2.272 0.000 302.00 328.00 3 1.6975e-01 4.0737e-04 2.9522e-02 -6.0000e+00 2.3508e-02 2.7333e-02 4.5700e-04 1.8399e-02 -6.0000e+00 2.5491e-02 -1.6635e-02 3.1517e-04 9.0867e-03 -6.0000e+00 1.4928e-02 5.3817e-04 1.6546e-04 2.5931e-03 -6.0000e+00 6.1716e-03 2.8792e-02 -1.8641e-04 8.6157e-06 2.8045e-05 -6.0000e+00 4.3554e-04 -2.2786e-02 -6.0089e-06 10 0 0 10 0 0 80.93 19.54 0.22 -0.02279 -0.02419 1102 199 1 5 0 46.100 26.41 20.00 19.54 25.42 25.9 1041.52 -2585 -1611 -2249 -4481 -6175 -5637 -4544 -3462 -2716 -4822 -5744 -5006 -2674 -2066 -821 -816 -892 -35 497 1082 76 -343 693 238 -214 -601 -956 -2195 -1866 -706 734 1150 1690 -794 -3402 -2544 -2683 -1411 -511 -849 -943 -1109 -483 -617 17 -69 -425 -211 -755 28 924 1003 1226 1581 937 1110 563 -52 159 369 1177 1749 2038 2119 305 -268 -185 -463 1132 964 441 623 278 473 -2 -305 -400 -781 -213 -626 -1123 -1156 -2263 -1808 -1057 -818 -403 -3 262 389 458 453 238 736 565 237 400 923 87 -265 -328 -742 -352 275 -827 -1337 -947 -915 -325 225 233 87 99 49 6 445 597 308 412 101 -377 41 446 313 594 262 204 1340 748 262 -4 -376 -154 61 -53 -255 -191 371 -81 -200 -154 -396 -238 -125 -87 -128 -250 -317 -274 -229 -194 -170 -329 -400 -360 -214 -194 -82 -93 -109 -4 67 151 11 -50 102 37 -36 -105 -170 -379 -302 -112 124 214 346 -175 -739 -531 -603 -364 -158 -310 -357 -446 -200 -261 7 -29 -179 -88 -314 12 407 479 625 853 531 646 337 -32 94 214 695 1099 1401 1472 221 -185 -128 -314 795 716 365 543 245 400 -2 -219 -279 -519 -146 -455 -934 -1075 -2160 -1809 -1118 -926 -453 -4 305 440 513 466 241 715 541 252 479 1156 119 -364 -427 -890 -416 324 -998 -1728 -1277 -1296 -456 338 375 138 162 75 8 627 827 443 595 156 -601 64 678 459 876 370 274 1767 1059 383 -6 -616 -258 107 -92 -470 -363 717 -151 -384 -284 -701 -408
SS 20240612T120616.6Z 8929.504359 132 1 50.80 2 63.07 81.35 120.02 35.55 0.00 1 0.00 1 0 17 1.410e-02 6.057e-03 1.562e-03 2.710e-04 3.415844e-01 1.390587e-04 3.996526e-03 -6.000000e+00 8.267567e-03 232.79 -2.00 3.49 -2.00 318.36 0.00e+00 7.956064e-04 2.366569e-05 1.020520e-04 -6.000000e+00 3.258024e-04 287.07 -2.00 20.00 -2.00 318.03 0.00e+00 2.195 0.000 302.00 328.00 3 7.7558e-02 3.7519e-04 2.8531e-02 -6.0000e+00 2.0950e-02 2.6890e-02 4.1969e-04 1.7789e-02 -6.0000e+00 2.2716e-02 -1.5270e-02 2.8396e-04 8.7671e-03 -6.0000e+00 1.3303e-02 -1.8026e-04 1.4866e-04 2.4889e-03 -6.0000e+00 5.5004e-03 3.4592e-02 -6.8771e-05 7.9379e-06 2.6764e-05 -6.0000e+00 3.8808e-04 -2.3109e-02 1.2743e-05 10 0 0 10 0 0 13.95 19.55 0.21 -0.02311 -0.02363 1415 256 1 5 0 35.900 26.41 20.00 19.55 26.03 25.8 1046.44 -2129 -1440 -1808 -3816 -4692 -4964 -3144 -2647 -2151 -4820 -5280 -4276 -2816 -1122 -1000 -330 -865 498 379 885 257 -591 1059 154 -33 -377 -1053 -1928 -1878 -267 463 1226 1544 -619 -3391 -2569 -2151 -1571 -429 -740 -1053 -926 -587 -691 -38 51 -600 -184 -901 33 906 975 1344 1495 1070 1035 681 35 198 433 1017 1830 1902 2101 288 -298 -184 -505 1168 972 542 639 303 496 -18 -305 -465 -806 -224 -589 -1168 -1189 -2196 -1772 -1047 -830 -295 42 393 359 460 428 206 730 525 252 464 941 105 -334 -366 -773 -355 264 -833 -1309 -926 -908 -370 258 256 116 141 86 34 420 594 314 400 55 -317 54 445 323 568 252 189 1315 729 227 -28 -399 -160 88 -91 -249 -195 380 -79 -172 -155 -369 -235 -108 -82 -108 -223 -249 -251 -164 -154 -140 -343 -382 -317 -234 -108 -112 -42 -117 70 56 136 41 -95 170 26 -6 -72 -206 -363 -333 -46 85 248 342 -147 -795 -578 -518 -437 -132 -270 -429 -399 -261 -313 -17 23 -271 -82 -400 15 423 493 723 853 597 593 400 21 115 248 591 1130 1286 1533 219 -215 -124 -333 798 752 437 543 260 410 -15 -229 -315 -521 -149 -444 -1006 -1072 -2163 -1829 -1143 -913 -342 51 472 419 501 453 202 683 517 275 534 1205 138 -444 -486 -948 -403 299 -1029 -1732 -1278 -1242 -532 395 397 186 221 134 50 568 834 432 586 86 -513 86 688 483 804 362 258 1761 1046 336 -45 -660 -256 146 -160 -463 -356 703 -148 -317 -289 -660 -407
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