File name: Pandora166s1_PhiladelphiaPA_20240903_L2Fit_fout2c6d20231015p1-8.txt
File generation date: 20241031T065654.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora166_OF_v5d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v6d20231015.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20240903_L1_smca1c6d20231015p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20240903
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0440 305.1847 305.3255 305.4662 305.6069 305.7476 305.8882 306.0289 306.1696 306.3102 306.4509 306.5915 306.7321 306.8727 307.0133 307.1539 307.2945 307.4350 307.5756 307.7161 307.8566 307.9972 308.1377 308.2781 308.4186 308.5591 308.6996 308.8400 308.9804 309.1209 309.2613 309.4017 309.5421 309.6825 309.8228 309.9632 310.1035 310.2439 310.3842 310.5245 310.6648 310.8051 310.9454 311.0857 311.2259 311.3662 311.5064 311.6466 311.7869 311.9271 312.0672 312.2074 312.3476 312.4878 312.6279 312.7680 312.9082 313.0483 313.1884 313.3285 313.4685 313.6086 313.7487 313.8887 314.0288 314.1688 314.3088 314.4488 314.5888 314.7288 314.8687 315.0087 315.1486 315.2886 315.4285 315.5684 315.7083 315.8482 315.9881 316.1279 316.2678 316.4076 316.5475 316.6873 316.8271 316.9669 317.1067 317.2465 317.3862 317.5260 317.6657 317.8055 317.9452 318.0849 318.2246 318.3643 318.5040 318.6436 318.7833 318.9229 319.0626 319.2022 319.3418 319.4814 319.6210 319.7606 319.9001 320.0397 320.1792 320.3188 320.4583 320.5978 320.7373 320.8768 321.0163 321.1557 321.2952 321.4346 321.5740 321.7135 321.8529 321.9923 322.1317 322.2710 322.4104 322.5497 322.6891 322.8284 322.9677 323.1070 323.2463 323.3856 323.5249 323.6642 323.8034 323.9426 324.0819 324.2211 324.3603 324.4995 324.6387 324.7778 324.9170
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240903T120334.5Z 9012.502483 87 1 46.66 2 73.10 94.74 77.88 91.52 0.00 1 0.00 1 0 17 5.810e-02 5.624e-03 1.082e-02 6.201e-04 4.707780e-01 3.199421e-04 5.403244e-03 -6.000000e+00 3.375571e-02 230.18 -2.00 3.49 -2.00 319.80 0.00e+00 1.246114e-03 8.460776e-05 2.466295e-04 -6.000000e+00 1.342629e-03 289.45 -2.00 20.00 -2.00 319.49 0.00e+00 3.386 0.001 302.00 328.00 3 4.2385e-01 8.9145e-04 4.1972e-02 -6.0000e+00 8.4995e-02 3.4122e-02 1.0436e-03 2.4606e-02 -6.0000e+00 9.2325e-02 -1.4195e-02 9.4475e-04 1.2580e-02 -6.0000e+00 5.4181e-02 -4.2490e-03 5.0590e-04 3.7921e-03 -6.0000e+00 2.2541e-02 6.5873e-03 -2.7868e-04 1.8100e-05 4.1536e-05 -6.0000e+00 1.5976e-03 -6.6205e-03 0.0000e+00 12 1 1 12 1 1 97.05 19.37 0.19 -0.00662 -0.00871 517 102 1 5 0 90.070 26.32 19.98 19.37 22.44 26.9 967.99 -21021 -11420 -15095 -16278 -21238 -29241 -18226 -20567 -14338 -17464 -20011 -14310 -9975 -6078 -4955 -935 -3766 -1974 -696 1095 -976 -397 -869 -1174 -2937 -2361 -2816 -4501 -3921 -2056 -26 -42 1142 -422 -3471 -3115 -3338 -1757 -1409 -978 -1290 -1622 -586 -755 -423 268 -648 -383 -732 287 1151 1057 1233 1439 854 900 618 21 82 151 714 1672 1996 2524 777 -138 65 -447 1088 1020 594 853 284 537 -69 -347 -620 -933 -265 -566 -974 -1032 -2102 -1819 -1079 -718 -197 138 480 654 735 996 595 725 619 237 459 954 298 -209 -198 -686 -420 288 -820 -1458 -1102 -990 -492 196 162 9 11 -2 -40 424 667 340 295 -57 -512 -21 281 170 474 237 125 1338 787 208 -28 -391 -123 53 -104 -238 -235 414 -66 -155 -106 -231 -29 -315 -181 -266 -285 -359 -514 -305 -399 -297 -406 -494 -358 -282 -203 -199 -39 -179 -100 -37 61 -57 -23 -53 -77 -211 -179 -219 -345 -286 -150 -2 -4 117 -47 -390 -339 -393 -238 -231 -192 -266 -361 -135 -179 -101 64 -158 -94 -183 74 315 319 403 505 319 348 247 8 33 59 282 705 933 1296 424 -74 33 -226 579 618 376 569 192 348 -42 -204 -332 -484 -145 -355 -662 -794 -1788 -1634 -1025 -683 -197 143 498 660 740 923 517 616 563 243 501 1172 378 -271 -259 -822 -461 311 -961 -1835 -1448 -1294 -683 294 265 14 18 -3 -61 609 942 499 459 -95 -869 -34 450 263 698 336 179 1901 1145 336 -49 -687 -223 100 -210 -481 -490 877 -142 -326 -211 -464 -55
SS 20240903T120900.3Z 9012.506254 90 1 50.81 2 72.06 95.64 76.87 92.40 0.00 1 0.00 1 0 25 4.562e-02 5.507e-03 7.095e-03 4.797e-04 4.477895e-01 2.469846e-04 5.154168e-03 -6.000000e+00 2.650372e-02 230.18 -2.00 3.49 -2.00 319.65 0.00e+00 1.364181e-03 6.217721e-05 2.184120e-04 -6.000000e+00 1.054198e-03 289.45 -2.00 20.00 -2.00 319.34 0.00e+00 3.203 0.001 302.00 328.00 3 1.5736e-01 6.8259e-04 3.9748e-02 -6.0000e+00 6.6735e-02 3.4361e-02 7.9228e-04 2.3320e-02 -6.0000e+00 7.2491e-02 -1.2750e-02 6.9093e-04 1.1896e-02 -6.0000e+00 4.2541e-02 -4.9512e-03 3.7130e-04 3.5814e-03 -6.0000e+00 1.7698e-02 1.0532e-02 -2.6432e-04 1.4098e-05 3.8811e-05 -6.0000e+00 1.2544e-03 -6.4100e-03 0.0000e+00 10 0 0 10 0 0 8.38 19.37 0.19 -0.00641 -0.00840 927 167 1 5 0 54.800 26.32 19.98 19.37 22.84 26.8 971.06 -16724 -10307 -12613 -14858 -16372 -15771 -17005 -11677 -15178 -14071 -15545 -12675 -8807 -7456 -2441 -1214 -1454 162 -52 43 -710 -299 26 -409 -1483 -1709 -2720 -3218 -4419 -2179 320 191 1308 -949 -3477 -2919 -3172 -1840 -1144 -822 -1516 -1304 -794 -809 1 -69 -421 -362 -949 -126 1090 1173 1380 1683 1022 1108 564 64 -106 155 785 1574 2252 2438 863 -50 -22 -518 1008 1177 502 830 286 551 16 -528 -688 -1217 -538 -678 -1172 -1066 -2045 -1722 -995 -635 -156 248 520 582 533 507 114 546 493 165 507 1018 312 -126 -187 -760 -366 252 -863 -1371 -988 -915 -354 294 303 90 159 122 -47 357 499 224 280 -55 -517 -46 405 247 455 145 37 1233 706 183 -28 -434 -221 -37 -144 -266 -201 465 51 -121 -51 -248 -50 -302 -202 -271 -320 -327 -300 -347 -255 -389 -386 -447 -377 -296 -278 -105 -60 -79 9 -3 3 -48 -20 2 -31 -121 -147 -242 -278 -370 -181 29 20 149 -119 -433 -352 -412 -276 -207 -164 -344 -316 -201 -209 0 -18 -111 -96 -256 -35 320 378 480 627 404 452 238 27 -44 64 328 701 1106 1315 493 -28 -12 -272 554 734 327 571 199 368 10 -320 -380 -650 -301 -434 -812 -832 -1761 -1563 -955 -651 -158 259 547 595 544 477 100 467 449 169 551 1242 418 -171 -241 -904 -399 272 -1008 -1715 -1292 -1262 -487 437 488 152 267 196 -71 500 731 320 426 -89 -857 -75 635 374 697 214 53 1713 1063 287 -48 -781 -410 -67 -280 -548 -426 947 105 -259 -104 -483 -94
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