File name: Pandora166s1_PhiladelphiaPA_20241023_L2Fit_fout2c5d20220925p1-8.txt File generation date: 20241024T054207.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 166 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora166_OF_v5d20210217.txt Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt Level 1 file used: Pandora166s1_PhiladelphiaPA_20241023_L1_smca1c5d20220925p1-8.txt Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE Short location name: PhiladelphiaPA Country of location: United States Location latitude [deg]: 39.9919 Location longitude [deg]: -75.0811 Location altitude [m]: 6 Local noon date: 20241023 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: HCHO modification of session 4 "Field cal based on session3" First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0654 305.2061 305.3468 305.4875 305.6282 305.7689 305.9096 306.0503 306.1910 306.3316 306.4722 306.6129 306.7535 306.8941 307.0347 307.1753 307.3158 307.4564 307.5969 307.7375 307.8780 308.0185 308.1590 308.2995 308.4400 308.5805 308.7209 308.8614 309.0018 309.1422 309.2827 309.4231 309.5635 309.7038 309.8442 309.9846 310.1249 310.2652 310.4056 310.5459 310.6862 310.8265 310.9668 311.1070 311.2473 311.3875 311.5278 311.6680 311.8082 311.9484 312.0886 312.2288 312.3690 312.5091 312.6493 312.7894 312.9295 313.0696 313.2097 313.3498 313.4899 313.6300 313.7700 313.9101 314.0501 314.1901 314.3301 314.4701 314.6101 314.7501 314.8901 315.0300 315.1700 315.3099 315.4498 315.5897 315.7296 315.8695 316.0094 316.1493 316.2891 316.4290 316.5688 316.7086 316.8484 316.9882 317.1280 317.2678 317.4076 317.5473 317.6871 317.8268 317.9665 318.1062 318.2459 318.3856 318.5253 318.6650 318.8046 318.9443 319.0839 319.2235 319.3631 319.5027 319.6423 319.7819 319.9215 320.0610 320.2006 320.3401 320.4796 320.6191 320.7586 320.8981 321.0376 321.1770 321.3165 321.4559 321.5954 321.7348 321.8742 322.0136 322.1530 322.2923 322.4317 322.5711 322.7104 322.8497 322.9891 323.1284 323.2677 323.4069 323.5462 323.6855 323.8247 323.9640 324.1032 324.2424 324.3816 324.5208 324.6600 324.7992 324.9383 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241023T122823.2Z 9062.519713 276 1 50.83 2 78.57 116.05 29.20 252.26 0.00 1 0.00 1 0 17 1.772e-01 5.451e-03 7.288e-02 1.982e-03 5.677728e-01 1.034204e-03 6.313291e-03 -6.000000e+00 1.011537e-01 225.32 -2.00 3.49 -2.00 320.87 0.00e+00 2.449348e-03 3.660755e-04 4.750420e-04 -6.000000e+00 4.096166e-03 283.93 -2.00 20.00 -2.00 320.55 0.00e+00 4.879 0.002 302.00 328.00 3 5.7693e-01 3.0042e-03 5.6715e-02 -6.0000e+00 2.5185e-01 4.9387e-02 3.9296e-03 2.9782e-02 -6.0000e+00 2.7452e-01 -3.2351e-02 4.4171e-03 1.6392e-02 -6.0000e+00 1.6169e-01 2.7547e-03 2.2701e-03 5.4352e-03 -6.0000e+00 6.7964e-02 1.2609e-03 -2.1404e-04 5.8953e-05 6.1907e-05 -6.0000e+00 4.8675e-03 -2.7956e-02 5.6219e-05 11 1 0 11 8 0 73.50 19.56 0.20 -0.02796 -0.02956 211 38 1 5 0 240.860 26.41 19.98 19.56 20.94 27.3 968.38 -94967 -41692 -41769 -30584 -74705 -63321 -87090 -42214 -40481 -9470 -39502 -55746 -19544 -35410 21889 -14528 -9886 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10 -73 189 -152 394 1432 619 375 129 -998 -584 494 -841 -2100 -1105 -1424 -139 507 809 389 224 191 -368 526 316 252 124 11 -914 58 1046 123 831 -135 -304 1270 697 417 -520 -578 -357 -4 -434 -613 -651 928 427 -208 -84 -401 370 SS 20241023T123338.3Z 9062.523360 279 1 50.85 2 77.67 116.99 30.15 253.57 0.00 1 0.00 1 0 25 1.527e-01 5.759e-03 4.546e-02 1.497e-03 5.305096e-01 7.719048e-04 5.950283e-03 -6.000000e+00 8.712933e-02 225.32 -2.00 3.49 -2.00 320.64 0.00e+00 2.574905e-03 2.591334e-04 4.025359e-04 -6.000000e+00 3.528294e-03 283.93 -2.00 20.00 -2.00 320.32 0.00e+00 4.549 0.002 302.00 328.00 3 4.8540e-01 2.2286e-03 5.2869e-02 -6.0000e+00 2.1693e-01 4.3559e-02 2.8119e-03 2.7608e-02 -6.0000e+00 2.3646e-01 -2.6683e-02 3.0020e-03 1.4867e-02 -6.0000e+00 1.3928e-01 -2.3747e-04 1.5612e-03 4.8232e-03 -6.0000e+00 5.8541e-02 1.9666e-03 -1.5786e-04 4.4551e-05 5.4346e-05 -6.0000e+00 4.1928e-03 -2.7937e-02 4.9163e-05 11 1 0 11 8 0 24.97 19.56 0.21 -0.02794 -0.02912 282 51 1 5 0 180.280 26.51 20.02 19.56 21.44 27.3 972.85 -77202 -3589 -45495 9674 -61813 -83970 -29930 -67375 -9035 -57851 -25322 -28482 -31428 -8919 -23211 -2544 -8220 -2997 -5425 1885 228 -13607 -1332 -4041 1380 -6919 -6431 -9104 -6941 -5122 5373 2359 115 -721 -4789 -3417 -3947 -1952 977 -1817 -58 -2438 209 -214 697 1041 -991 3144 558 1385 2005 3021 2003 2255 2002 552 697 -847 336 50 -362 1667 1923 3092 651 475 -47 -735 944 628 1119 1026 437 227 -6 -719 -1388 -1401 -1012 -749 -1223 -1002 -2174 -1990 -883 -726 209 231 974 786 883 680 -232 193 83 191 351 1221 502 37 1 -840 -650 -40 -769 -1626 -1021 -1077 -407 502 373 335 156 217 -183 232 539 317 207 -225 -521 -52 420 222 364 155 -317 1253 576 47 -80 -391 -212 5 -262 -349 -246 477 122 -85 -42 -107 76 -911 -26 -504 67 -737 -1205 -290 -984 -91 -950 -314 -398 -551 -157 -542 -58 -222 -84 -170 58 7 -512 -46 -154 54 -311 -295 -420 -305 -229 247 122 7 -48 -325 -223 -280 -159 94 -217 -7 -335 30 -31 103 156 -154 478 90 231 363 601 440 535 506 147 191 -238 91 13 -100 488 630 1119 255 183 -18 -277 375 286 567 550 237 118 -3 -316 -562 -555 -429 -367 -702 -653 -1578 -1531 -672 -591 178 204 862 679 714 545 -177 145 68 165 348 1366 621 46 1 -927 -655 -40 -820 -1866 -1224 -1372 -554 746 573 545 255 342 -290 345 789 483 335 -363 -856 -83 688 352 553 226 -447 1750 886 81 -142 -739 -418 10 -578 -772 -561 1100 285 -195 -98 -232 159 SS 20241023T123922.6Z 9062.527345 282 1 50.83 2 76.70 118.03 31.19 254.94 0.00 1 0.00 1 0 25 9.181e-02 5.370e-03 2.772e-02 1.183e-03 4.995473e-01 6.102390e-04 5.696986e-03 -6.000000e+00 5.240042e-02 225.32 -2.00 3.49 -2.00 320.37 0.00e+00 2.047979e-03 1.892588e-04 3.321424e-04 -6.000000e+00 2.121931e-03 283.93 -2.00 20.00 -2.00 320.05 0.00e+00 4.239 0.001 302.00 328.00 3 4.5776e-01 1.7442e-03 4.9402e-02 -6.0000e+00 1.3046e-01 4.2120e-02 2.1239e-03 2.5893e-02 -6.0000e+00 1.4221e-01 -1.9337e-02 2.1300e-03 1.3693e-02 -6.0000e+00 8.3762e-02 -4.3076e-03 1.1239e-03 4.3502e-03 -6.0000e+00 3.5208e-02 2.8038e-03 -2.0152e-04 3.5356e-05 5.0389e-05 -6.0000e+00 2.5216e-03 -2.8239e-02 4.1769e-05 11 1 0 11 8 0 57.28 19.55 0.19 -0.02824 -0.02975 333 60 1 5 0 152.640 26.41 20.01 19.55 22.06 27.1 976.41 -44548 -27573 -14586 -34725 -25058 -42563 -38144 -24369 -19629 -20390 -20042 -13340 -26334 -11153 -14097 -8846 -1865 -696 2234 -4580 2271 -5160 -4530 -707 -3724 -2012 -6919 -2520 -6958 -1375 -76 3 1735 -3154 -3316 -5253 -1655 -2202 -21 528 -10 -872 -1050 -414 -555 548 -1008 584 175 281 2828 390 1578 1176 585 806 69 47 -524 226 78 1509 2212 2742 1176 464 274 -542 1394 1186 780 930 219 685 -394 -280 -976 -1983 -756 -917 -1001 -1405 -2006 -1837 -893 -866 -115 585 757 958 493 705 143 324 310 -101 401 1135 471 -106 -98 -752 -392 236 -881 -1499 -1059 -964 -380 377 349 252 293 21 -37 147 395 200 311 -39 -554 56 257 240 421 35 -173 1038 649 133 62 -503 -251 -31 -175 -300 -219 547 53 -82 -44 -165 24 -570 -350 -176 -506 -305 -594 -540 -340 -296 -310 -316 -213 -575 -261 -385 -272 -60 -24 81 -188 90 -222 -199 -32 -189 -106 -394 -134 -374 -72 -4 0 132 -253 -260 -409 -134 -209 -2 71 -2 -146 -186 -75 -102 101 -191 111 34 57 606 95 413 333 177 252 22 15 -169 71 25 518 844 1080 495 191 109 -216 585 568 419 527 126 376 -203 -130 -446 -890 -358 -468 -593 -950 -1498 -1453 -745 -775 -108 566 738 907 439 579 111 248 254 -94 425 1272 582 -134 -117 -828 -420 249 -1006 -1723 -1273 -1228 -516 558 564 405 472 35 -56 214 565 297 489 -65 -947 94 414 373 626 50 -238 1416 968 222 113 -915 -474 -61 -369 -669 -503 1275 118 -189 -97 -346 48 SS 20241023T124952.4Z 9062.534634 285 1 50.82 2 74.94 119.96 33.10 257.29 0.00 1 0.00 1 0 17 5.208e-02 5.494e-03 1.336e-02 8.058e-04 4.502773e-01 4.080786e-04 5.180816e-03 -6.000000e+00 2.972593e-02 225.32 -2.00 3.49 -2.00 319.91 0.00e+00 1.506431e-03 1.112302e-04 2.407432e-04 -6.000000e+00 1.203726e-03 283.93 -2.00 20.00 -2.00 319.59 0.00e+00 3.775 0.001 302.00 328.00 3 3.2685e-01 1.1352e-03 4.4038e-02 -6.0000e+00 7.4010e-02 3.4977e-02 1.3386e-03 2.3038e-02 -6.0000e+00 8.0672e-02 -1.5289e-02 1.2254e-03 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