File name: Pandora166s1_PhiladelphiaPA_20250108_L2Fit_fwvt1c5d20220925p1-8.txt File generation date: 20250109T052538.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 166 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora166_OF_v5d20210217.txt Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt Level 1 file used: Pandora166s1_PhiladelphiaPA_20250108_L1_smca1c5d20220925p1-8.txt Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE Short location name: PhiladelphiaPA Country of location: United States Location latitude [deg]: 39.9919 Location longitude [deg]: -75.0811 Location altitude [m]: 6 Local noon date: 20250108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: HCHO modification of session 4 "Field cal based on session3" First and last pixel inside fitting window: 1645 1794 Nominal wavelengths inside fitting window [nm]: 492.1120 492.2329 492.3538 492.4746 492.5954 492.7162 492.8370 492.9578 493.0786 493.1993 493.3201 493.4408 493.5615 493.6821 493.8028 493.9234 494.0441 494.1647 494.2853 494.4058 494.5264 494.6469 494.7674 494.8880 495.0084 495.1289 495.2494 495.3698 495.4902 495.6106 495.7310 495.8514 495.9717 496.0921 496.2124 496.3327 496.4530 496.5732 496.6935 496.8137 496.9339 497.0541 497.1743 497.2945 497.4146 497.5348 497.6549 497.7750 497.8951 498.0151 498.1352 498.2552 498.3752 498.4952 498.6152 498.7351 498.8551 498.9750 499.0949 499.2148 499.3347 499.4545 499.5744 499.6942 499.8140 499.9338 500.0536 500.1733 500.2930 500.4128 500.5325 500.6521 500.7718 500.8915 501.0111 501.1307 501.2503 501.3699 501.4895 501.6090 501.7285 501.8480 501.9675 502.0870 502.2065 502.3259 502.4454 502.5648 502.6842 502.8035 502.9229 503.0422 503.1615 503.2809 503.4001 503.5194 503.6387 503.7579 503.8771 503.9963 504.1155 504.2347 504.3538 504.4729 504.5921 504.7112 504.8302 504.9493 505.0683 505.1874 505.3064 505.4254 505.5444 505.6633 505.7823 505.9012 506.0201 506.1390 506.2578 506.3767 506.4955 506.6143 506.7331 506.8519 506.9707 507.0894 507.2082 507.3269 507.4456 507.5643 507.6829 507.8016 507.9202 508.0388 508.1574 508.2760 508.3945 508.5131 508.6316 508.7501 508.8686 508.9870 509.1055 509.2239 509.3423 509.4607 509.5791 509.6975 509.8158 509.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250108T131740.3Z 9139.553938 130 1 5.96 2 81.94 128.02 121.22 19.13 0.00 1 0.00 1 0 15 3.698e-03 3.671e-03 1.962e-03 1.960e-03 1.325825e+03 1.091808e+02 9.854592e+01 -6.000000e+00 1.980509e+02 276.52 -2.00 20.00 -2.00 505.27 0.00e+00 1.769133e-03 5.285224e-05 9.589270e-05 -6.000000e+00 1.017378e-04 276.52 -2.00 20.00 -2.00 500.51 0.00e+00 7.730520e-01 3.832963e-02 1.828275e-02 -6.000000e+00 7.305970e-02 223.64 -2.00 3.49 -2.00 502.09 0.00e+00 6.682 0.005 489.00 513.00 1 5.4936e+00 2.9286e-03 9.9697e-03 -6.0000e+00 5.5813e-03 1.7309e-02 7.6442e-04 6.0456e-04 -6.0000e+00 1.4643e-03 2.8655e-03 -2.4283e-04 1.8745e-04 3.5827e-05 -6.0000e+00 3.6114e-04 -2.6187e-02 -5.8247e-05 12 1 1 12 1 1 999.00 19.64 1.51 -0.02619 -0.02787 2 5 1 4 0 1985.350 26.51 20.00 19.64 2.74 25.8 892.51 -658 -1096 -205 7 265 154 365 593 618 209 268 203 -314 -329 -43 -336 -33 -48 535 124 -213 74 254 236 371 657 436 -146 -226 -361 -577 -171 -117 100 -10 209 205 157 -396 -194 12 -133 291 311 312 456 582 74 44 -101 -776 -581 -886 -388 -317 -49 68 123 -6 46 647 97 432 212 225 55 196 -111 -9 -322 -570 -295 -247 32 42 -217 -139 -413 44 -423 -537 -281 -513 34 38 -303 -37 -104 -439 -98 -282 -138 749 356 539 279 159 -133 -645 -270 -850 -631 -261 -148 180 -585 -34 -133 187 -383 -361 -128 426 484 767 646 75 539 243 581 451 48 236 384 285 321 292 466 510 19 -176 -26 -546 -164 -733 127 -54 -289 -23 314 112 91 190 179 70 214 -30 -389 -460 -636 -638 -1058 -203 7 270 156 377 616 640 214 270 207 -317 -328 -42 -335 -33 -48 550 129 -224 77 266 242 382 676 447 -152 -230 -365 -575 -171 -117 102 -11 217 211 163 -410 -199 12 -138 296 321 325 474 602 76 45 -101 -764 -572 -865 -381 -311 -50 69 125 -6 47 654 99 442 217 228 55 197 -111 -9 -314 -552 -286 -242 31 42 -216 -135 -397 43 -413 -513 -270 -498 33 37 -302 -36 -103 -438 -97 -277 -137 751 360 540 276 154 -130 -615 -258 -814 -596 -253 -145 179 -589 -34 -130 180 -373 -357 -128 423 485 773 656 77 550 247 580 444 48 234 382 279 315 287 456 498 19 -172 -26 -530 -156 -703 122 -53 -284 -23 315 113 92 189 179 70 213 -30 -381 -453 -624 SQ 20250108T133212.5Z 9139.564034 133 1 5.89 2 79.79 130.64 120.21 22.81 0.00 1 0.00 1 0 15 2.802e-03 2.782e-03 1.379e-04 1.377e-04 1.155753e+03 7.615233e+00 8.673374e+01 -6.000000e+00 1.500630e+02 276.52 -2.00 20.00 -2.00 505.28 0.00e+00 1.220081e-03 3.716645e-06 6.780727e-05 -6.000000e+00 7.708685e-05 276.52 -2.00 20.00 -2.00 500.54 0.00e+00 5.703695e-01 2.690877e-03 1.402317e-02 -6.000000e+00 5.535676e-02 223.64 -2.00 3.49 -2.00 502.12 0.00e+00 5.410 0.003 489.00 513.00 1 7.0328e-01 2.0556e-04 7.9992e-03 -6.0000e+00 4.2289e-03 2.9536e-03 5.3686e-05 4.9178e-04 -6.0000e+00 1.1095e-03 4.2303e-01 -1.9816e-04 1.3203e-05 2.6569e-05 -6.0000e+00 2.7362e-04 -2.0536e-02 -9.2130e-05 10 0 0 10 0 0 78.67 19.63 1.59 -0.02054 -0.02191 525 95 1 4 0 11.220 26.51 20.00 19.63 3.51 26.3 900.26 -561 -455 -156 13 148 440 535 494 436 309 275 109 -168 -212 -251 -241 -92 117 152 29 139 200 147 261 304 287 304 150 -264 -424 -417 -455 -214 174 57 -33 105 23 -148 -153 -62 -31 102 233 290 338 309 209 120 -227 -470 -624 -721 -572 -323 -172 -93 28 59 150 202 282 276 299 237 121 59 -25 -173 -362 -263 -196 -181 62 65 -156 -186 -164 -231 -346 -311 -348 -386 -171 -83 -157 -179 -120 -146 -147 -24 199 315 219 276 308 98 -155 -281 -542 -589 -485 -256 -31 -145 -159 -118 -261 -209 -130 -131 -18 156 262 313 521 569 521 370 331 230 132 202 271 110 198 274 171 254 285 26 -113 -135 -345 -363 -103 -111 -182 8 159 127 187 336 299 303 130 -118 -332 -414 -467 -535 -441 -150 13 151 442 546 509 448 314 275 112 -170 -212 -249 -241 -93 117 156 30 145 208 153 273 320 301 318 155 -267 -431 -416 -457 -212 178 60 -34 110 23 -152 -156 -64 -32 106 245 297 346 315 218 123 -227 -458 -616 -705 -564 -316 -173 -96 28 59 155 202 283 278 302 237 124 59 -25 -169 -351 -253 -189 -177 61 65 -155 -181 -158 -219 -328 -296 -335 -374 -167 -82 -157 -178 -120 -145 -147 -23 197 315 221 276 304 98 -151 -269 -509 -552 -461 -251 -30 -145 -159 -117 -254 -202 -127 -129 -18 158 270 314 524 574 526 372 339 232 132 200 269 111 198 274 172 254 285 26 -111 -130 -329 -346 -99 -109 -183 8 158 127 188 338 303 308 131 -117 -333 -407 -458 SQ 20250108T133218.6Z 9139.564104 133 2 5.90 2 79.78 130.65 120.20 22.83 0.00 1 0.00 1 0 15 2.727e-03 2.706e-03 1.444e-04 1.442e-04 1.153662e+03 7.964253e+00 8.733809e+01 -6.000000e+00 1.460477e+02 276.52 -2.00 20.00 -2.00 505.29 0.00e+00 1.227631e-03 3.891905e-06 6.817284e-05 -6.000000e+00 7.502491e-05 276.52 -2.00 20.00 -2.00 500.54 0.00e+00 5.711242e-01 2.815995e-03 1.394179e-02 -6.000000e+00 5.387878e-02 223.64 -2.00 3.49 -2.00 502.12 0.00e+00 5.403 0.003 489.00 513.00 1 7.8492e-01 2.1519e-04 7.9905e-03 -6.0000e+00 4.1159e-03 2.8014e-03 5.6179e-05 4.9033e-04 -6.0000e+00 1.0799e-03 3.9019e-01 -1.1075e-04 1.3835e-05 2.6853e-05 -6.0000e+00 2.6631e-04 -1.9935e-02 -1.0010e-04 10 0 0 10 0 0 94.99 19.63 1.59 -0.01993 -0.02070 525 95 1 4 0 11.220 26.51 20.00 19.63 3.51 26.3 900.26 -551 -448 -142 47 136 439 520 473 436 292 275 116 -136 -186 -233 -229 -117 98 143 38 102 200 132 257 316 294 301 159 -260 -431 -379 -439 -216 149 63 -16 73 23 -151 -151 -94 -22 80 218 257 295 303 210 98 -207 -495 -613 -715 -558 -312 -182 -90 7 81 133 245 288 270 272 229 123 55 -14 -174 -345 -286 -222 -172 41 81 -139 -164 -173 -242 -330 -302 -344 -368 -154 -42 -168 -165 -101 -140 -150 -12 215 274 209 272 295 70 -142 -278 -493 -596 -494 -245 -12 -141 -173 -97 -268 -225 -118 -111 -34 155 256 340 487 575 503 360 303 200 143 170 303 80 172 253 176 220 291 32 -53 -99 -322 -361 -89 -106 -174 30 163 113 165 339 282 273 110 -127 -316 -391 -447 -529 -438 -138 47 140 444 534 490 450 298 276 115 -138 -187 -233 -231 -116 99 148 39 107 209 138 270 333 311 317 165 -264 -424 -381 -428 -215 154 65 -17 74 24 -156 -155 -97 -23 83 222 264 304 311 212 101 -208 -485 -587 -704 -534 -307 -184 -90 7 81 133 246 290 274 275 230 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2.6419e-05 -6.0000e+00 2.8038e-04 -2.1971e-02 -8.5498e-05 10 0 0 10 0 0 60.21 19.63 1.59 -0.02197 -0.02295 525 95 1 4 0 11.220 26.51 20.00 19.63 3.51 26.3 900.26 -604 -514 -187 -5 116 450 532 476 458 313 264 86 -166 -231 -271 -288 -115 117 126 42 154 208 146 278 349 300 327 134 -248 -414 -411 -453 -222 183 89 -10 114 45 -176 -150 -68 -11 82 244 297 329 315 237 113 -223 -506 -623 -729 -574 -296 -198 -79 64 66 138 221 285 285 296 226 126 69 -25 -177 -335 -306 -228 -171 64 53 -147 -183 -179 -273 -362 -303 -325 -375 -150 -62 -161 -207 -130 -151 -147 -20 214 298 239 285 329 71 -160 -300 -559 -603 -513 -240 -13 -134 -173 -118 -273 -195 -136 -136 -44 186 302 351 540 577 535 367 327 216 147 192 293 130 193 292 204 244 282 14 -131 -131 -361 -385 -126 -147 -173 -1 165 110 177 336 301 280 114 -116 -349 -411 -487 -571 -494 -186 -5 118 465 541 487 468 316 272 87 -167 -229 -268 -286 -116 121 128 43 160 215 151 289 364 313 339 138 -249 -417 -408 -452 -226 186 93 -11 118 47 -180 -152 -69 -11 84 255 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20250108T203938.3Z 9139.860859 367 5 5.92 2 79.38 228.91 53.00 96.36 0.00 1 0.00 1 0 15 2.841e-03 2.822e-03 9.303e-05 9.291e-05 9.362748e+02 5.097773e+00 6.982520e+01 -6.000000e+00 1.521204e+02 276.50 -2.00 20.00 -2.00 505.28 0.00e+00 1.100713e-03 2.506162e-06 6.081045e-05 -6.000000e+00 7.815081e-05 276.50 -2.00 20.00 -2.00 500.51 0.00e+00 6.436961e-01 1.815431e-03 1.237051e-02 -6.000000e+00 5.613847e-02 223.65 -2.00 3.49 -2.00 502.10 0.00e+00 5.218 0.002 489.00 513.00 1 -4.7083e-02 1.3870e-04 7.6782e-03 -6.0000e+00 4.2883e-03 4.1080e-03 3.6259e-05 4.6132e-04 -6.0000e+00 1.1255e-03 9.1769e-01 -1.7244e-04 8.8985e-06 2.3343e-05 -6.0000e+00 2.7753e-04 -2.3920e-02 -9.2958e-05 10 0 0 10 0 0 19.66 19.51 1.63 -0.02392 -0.02512 1034 187 1 4 0 5.690 26.41 20.00 19.51 7.13 26.3 927.57 -600 -482 -221 -17 109 432 530 479 434 301 271 97 -169 -239 -270 -300 -118 97 143 53 127 222 155 267 325 302 312 165 -246 -430 -402 -425 -222 193 96 -24 103 59 -145 -168 -86 -24 114 239 286 314 336 239 115 -188 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