File name: Pandora166s1_PhiladelphiaPA_20250208_L2Fit_fwvt1c6d20231015p1-8.txt
File generation date: 20250209T054333.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.70
Instrument operation file used: Pandora166_OF_v5d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v6d20231015.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20250208_L1_smca1c6d20231015p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20250208
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1645 1794
Nominal wavelengths inside fitting window [nm]: 492.0825 492.2034 492.3243 492.4451 492.5659 492.6867 492.8075 492.9283 493.0490 493.1698 493.2905 493.4112 493.5319 493.6525 493.7732 493.8938 494.0144 494.1350 494.2556 494.3762 494.4967 494.6173 494.7378 494.8583 494.9788 495.0992 495.2197 495.3401 495.4605 495.5809 495.7013 495.8217 495.9420 496.0623 496.1826 496.3029 496.4232 496.5435 496.6637 496.7839 496.9041 497.0243 497.1445 497.2647 497.3848 497.5049 497.6250 497.7451 497.8652 497.9852 498.1053 498.2253 498.3453 498.4653 498.5853 498.7052 498.8251 498.9451 499.0650 499.1848 499.3047 499.4246 499.5444 499.6642 499.7840 499.9038 500.0235 500.1433 500.2630 500.3827 500.5024 500.6221 500.7418 500.8614 500.9810 501.1006 501.2202 501.3398 501.4593 501.5789 501.6984 501.8179 501.9374 502.0569 502.1763 502.2958 502.4152 502.5346 502.6540 502.7733 502.8927 503.0120 503.1313 503.2506 503.3699 503.4892 503.6084 503.7276 503.8468 503.9660 504.0852 504.2044 504.3235 504.4426 504.5617 504.6808 504.7999 504.9190 505.0380 505.1570 505.2760 505.3950 505.5140 505.6329 505.7518 505.8708 505.9897 506.1085 506.2274 506.3462 506.4651 506.5839 506.7027 506.8214 506.9402 507.0589 507.1777 507.2964 507.4151 507.5337 507.6524 507.7710 507.8896 508.0082 508.1268 508.2454 508.3639 508.4825 508.6010 508.7195 508.8379 508.9564 509.0748 509.1933 509.3117 509.4301 509.5484 509.6668 509.7851 509.9034
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250208T130740.3Z 9170.546994 218 1 50.42 2 79.23 119.94 111.61 350.11 0.00 1 0.00 1 0 15 2.793e-03 2.778e-03 6.160e-04 6.151e-04 2.097474e+03 3.527226e+01 1.523660e+02 -6.000000e+00 1.492887e+02 276.00 -2.00 20.00 -2.00 505.29 0.00e+00 1.242699e-03 1.657133e-05 6.819107e-05 -6.000000e+00 7.672604e-05 276.00 -2.00 20.00 -2.00 500.53 0.00e+00 5.187241e-01 1.206912e-02 1.984769e-02 -6.000000e+00 5.528866e-02 224.70 -2.00 3.49 -2.00 502.11 0.00e+00 5.154 0.002 489.00 513.00 1 5.8799e+00 9.2031e-04 7.7341e-03 -6.0000e+00 4.2219e-03 4.6327e-03 2.4018e-04 5.7961e-04 -6.0000e+00 1.1087e-03 2.4815e-03 -4.1773e-06 5.8756e-05 3.1167e-05 -6.0000e+00 2.7290e-04 -5.0016e-03 -3.2004e-05 10 0 0 10 0 0 99.45 19.26 1.53 -0.00500 -0.00503 31 6 1 4 0 1626.150 26.21 20.00 19.26 6.27 26.3 945.64 -567 -581 -79 -2 61 373 477 346 368 192 187 73 -199 -209 -357 -255 -83 153 129 68 67 119 186 346 381 272 268 292 -176 -382 -432 -266 -217 212 75 -74 145 121 -255 -190 -94 -13 79 218 397 284 303 229 180 -203 -425 -551 -717 -539 -262 -186 -101 30 108 150 266 307 320 270 202 107 180 1 -282 -256 -315 -239 -140 -36 78 -104 -187 -154 -147 -337 -299 -298 -397 -232 -112 -178 -181 -232 -125 -90 64 215 335 247 264 303 101 -147 -294 -468 -682 -537 -167 -10 -56 -191 -187 -315 -223 -29 -176 -20 191 317 350 526 665 467 433 283 294 82 132 388 115 137 256 326 166 159 -88 -97 -100 -302 -508 -115 -7 -196 -71 154 5 183 182 337 212 -10 -34 -185 -359 -515 -545 -569 -75 -2 62 387 502 368 391 201 193 75 -200 -208 -354 -254 -84 158 136 69 69 122 191 356 394 282 275 296 -183 -386 -429 -265 -221 212 77 -77 149 124 -258 -190 -94 -13 80 225 413 296 314 234 181 -200 -427 -540 -697 -528 -263 -183 -102 30 110 152 270 313 328 276 205 107 178 1 -272 -255 -312 -237 -134 -35 76 -101 -179 -152 -144 -328 -292 -294 -377 -222 -108 -174 -177 -227 -122 -88 63 215 339 251 267 301 98 -140 -273 -448 -651 -496 -159 -9 -57 -194 -187 -311 -218 -28 -175 -20 196 314 349 527 669 471 434 280 299 83 132 389 116 138 259 329 167 160 -89 -96 -98 -290 -490 -112 -7 -190 -69 153 5 184 184 341 215 -10 -33 -179 -357 -509
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SQ 20250208T132105.0Z 9170.556308 227 1 6.44 2 77.03 122.37 111.97 353.11 0.00 1 0.00 1 0 15 2.912e-03 2.895e-03 1.104e-03 1.103e-03 1.829833e+03 6.239640e+01 1.318588e+02 -6.000000e+00 1.556445e+02 276.00 -2.00 20.00 -2.00 505.27 0.00e+00 1.270186e-03 2.967119e-05 7.003356e-05 -6.000000e+00 7.998916e-05 276.00 -2.00 20.00 -2.00 500.50 0.00e+00 3.634167e-01 2.166037e-02 1.846890e-02 -6.000000e+00 5.762434e-02 224.70 -2.00 3.49 -2.00 502.08 0.00e+00 4.341 0.001 489.00 513.00 1 5.2304e+00 1.6530e-03 6.6099e-03 -6.0000e+00 4.4006e-03 8.7493e-03 4.3209e-04 5.0346e-04 -6.0000e+00 1.1551e-03 5.3966e-03 -4.3746e-04 1.0513e-04 3.0518e-05 -6.0000e+00 2.8440e-04 -1.0520e-02 2.7244e-05 12 1 1 12 1 1 92.43 19.27 1.60 -0.01052 -0.01355 6 10 1 4 0 919.020 26.32 19.99 19.27 6.42 26.2 946.75 -498 -746 -250 -136 158 322 498 484 495 363 172 198 -126 -117 -204 -220 -230 243 144 -65 81 180 153 369 351 91 183 182 -232 -196 -422 -413 -222 257 45 -147 193 46 56 -108 -177 -242 124 49 314 237 454 392 21 -48 -536 -588 -755 -286 -305 -183 -39 138 227 -9 203 78 428 238 187 237 62 -295 -104 -304 -404 -59 32 59 47 -99 -125 -330 -431 -210 -286 -88 -528 -303 114 -292 -345 11 -298 -137 44 173 354 412 308 176 -40 -230 -246 -258 -640 -580 -260 95 50 -335 -147 -284 -202 -105 -67 48 313 246 453 383 500 409 486 155 139 84 357 217 243 193 223 222 168 358 -65 75 -81 -428 -480 -136 -118 -282 80 270 62 355 270 311 132 77 -224 -510 -335 -372 -486 -724 -249 -137 159 331 520 498 519 377 176 199 -129 -117 -204 -221 -230 248 147 -67 84 186 158 383 366 95 191 187 -238 -195 -424 -407 -223 260 47 -155 201 48 57 -109 -179 -247 128 52 322 244 474 404 22 -48 -530 -581 -739 -282 -302 -183 -40 141 233 -9 207 81 441 246 192 238 62 -290 -103 -299 -393 -57 31 59 46 -97 -123 -320 -414 -201 -274 -85 -516 -298 111 -286 -339 10 -294 -135 43 174 352 412 306 176 -40 -226 -236 -242 -600 -552 -254 93 49 -333 -144 -282 -198 -103 -65 48 315 250 453 386 505 414 487 157 138 83 348 213 240 191 221 220 166 352 -64 72 -79 -413 -461 -132 -114 -279 80 267 62 354 271 313 134 77 -221 -504 -324 -358
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