File name: Pandora187s1_PittsburghPA_20211230_L2Fit_fwvt1c2d20210902p1-8.txt File generation date: 20231128T200142.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v2d20210902.txt Level 1 file used: Pandora187s1_PittsburghPA_20211230_L1_smca1c2d20210902p1-8.txt.bz2 Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20211230 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1607 1755 Nominal wavelengths inside fitting window [nm]: 492.1177 492.2395 492.3614 492.4832 492.6050 492.7267 492.8485 492.9702 493.0920 493.2137 493.3354 493.4570 493.5787 493.7003 493.8219 493.9435 494.0651 494.1867 494.3083 494.4298 494.5513 494.6728 494.7943 494.9158 495.0372 495.1587 495.2801 495.4015 495.5229 495.6442 495.7656 495.8869 496.0083 496.1296 496.2508 496.3721 496.4934 496.6146 496.7358 496.8570 496.9782 497.0994 497.2205 497.3416 497.4628 497.5839 497.7049 497.8260 497.9470 498.0681 498.1891 498.3101 498.4311 498.5520 498.6730 498.7939 498.9148 499.0357 499.1566 499.2775 499.3983 499.5191 499.6399 499.7607 499.8815 500.0023 500.1230 500.2437 500.3644 500.4851 500.6058 500.7265 500.8471 500.9677 501.0883 501.2089 501.3295 501.4500 501.5706 501.6911 501.8116 501.9321 502.0525 502.1730 502.2934 502.4139 502.5343 502.6546 502.7750 502.8953 503.0157 503.1360 503.2563 503.3766 503.4968 503.6171 503.7373 503.8575 503.9777 504.0979 504.2181 504.3382 504.4583 504.5784 504.6985 504.8186 504.9387 505.0587 505.1787 505.2987 505.4187 505.5387 505.6586 505.7786 505.8985 506.0184 506.1383 506.2581 506.3780 506.4978 506.6176 506.7374 506.8572 506.9770 507.0967 507.2165 507.3362 507.4559 507.5756 507.6952 507.8149 507.9345 508.0541 508.1737 508.2933 508.4128 508.5324 508.6519 508.7714 508.8909 509.0103 509.1298 509.2492 509.3686 509.4880 509.6074 509.7268 509.8461 509.9655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211230T180629.3Z 8034.754505 334 1 7.95 2 64.40 191.19 80.29 233.14 0.00 1 0.00 1 0 15 3.537e-03 3.518e-03 4.375e-03 4.367e-03 1.892338e+03 2.949800e+02 1.216218e+02 -6.000000e+00 2.246008e+02 275.09 -2.00 20.00 -2.00 505.26 0.00e+00 7.909449e-04 1.272477e-04 4.610673e-05 -6.000000e+00 1.054304e-04 275.09 -2.00 20.00 -2.00 500.45 0.00e+00 1.032910e-01 9.404332e-02 2.048207e-02 -6.000000e+00 7.651197e-02 223.21 -2.00 3.49 -2.00 502.05 0.00e+00 2.300 0.000 489.00 513.00 1 7.0518e+00 7.2748e-03 3.7676e-03 -6.0000e+00 5.9265e-03 1.4555e-02 1.7734e-03 4.5677e-04 -6.0000e+00 1.4506e-03 1.2107e-03 3.1848e-04 7.0926e-04 3.0636e-05 -6.0000e+00 5.9459e-04 -1.2942e-02 -3.0351e-05 2 1 1 12 1 1 999.00 18.62 0.65 -0.01294 -0.01073 1 4 1 4 0 3887.690 21.98 15.00 18.62 19.28 13.9 1000.75 -76 57 -73 -330 247 166 304 17 -275 367 68 48 67 -77 -436 -546 231 38 597 -98 298 -244 137 122 77 166 432 509 45 -760 -393 90 516 -166 100 -72 -521 -271 298 122 -77 -16 279 490 -152 -8 -22 142 698 -338 -622 -818 -381 316 255 -458 356 -222 146 -197 852 172 145 85 -319 -199 18 291 -324 -549 -635 104 154 -154 -343 243 82 -267 -181 -106 -227 -510 495 155 -124 -454 -316 -256 95 151 190 -87 -230 -332 337 170 -273 -149 -363 294 -35 -274 -176 -835 -229 -443 509 467 58 -468 62 -208 458 -344 104 -124 742 266 629 -3 453 974 633 782 151 129 -122 682 -166 -316 -438 -429 -422 97 725 -158 281 95 -180 -9 174 -466 48 24 -177 -66 -204 -343 -28 -75 57 -74 -342 251 172 317 18 -289 380 70 49 68 -79 -438 -553 235 39 622 -103 316 -261 146 131 82 176 452 524 46 -772 -397 91 527 -173 102 -73 -534 -285 310 127 -81 -17 293 500 -156 -8 -23 146 701 -337 -611 -799 -371 308 253 -465 363 -229 146 -198 878 172 150 87 -326 -201 18 286 -318 -536 -620 101 150 -150 -335 235 78 -255 -173 -101 -218 -493 477 151 -122 -450 -314 -255 95 152 192 -85 -226 -336 335 167 -264 -142 -343 276 -34 -265 -173 -837 -230 -431 506 464 57 -460 61 -207 458 -349 105 -126 746 267 624 -3 442 941 613 755 146 125 -118 654 -160 -302 -430 -418 -410 93 703 -151 271 92 -178 -9 174 -469 48 24 -175 -64 -197 -329 -26 SQ 20211230T181736.0Z 8034.762222 343 1 7.34 2 64.86 193.97 81.97 235.06 0.00 1 0.00 1 0 15 1.714e-03 1.714e-03 2.346e-04 2.343e-04 1.892967e+03 1.571235e+01 1.315977e+02 -6.000000e+00 1.088035e+02 275.09 -2.00 20.00 -2.00 505.26 0.00e+00 6.609705e-04 6.824088e-06 3.803109e-05 -6.000000e+00 5.107434e-05 275.09 -2.00 20.00 -2.00 500.49 0.00e+00 3.035563e-02 5.024753e-03 1.801780e-02 -6.000000e+00 3.706847e-02 223.21 -2.00 3.49 -2.00 502.07 0.00e+00 2.339 0.000 489.00 513.00 1 1.8278e+00 3.8873e-04 3.6850e-03 -6.0000e+00 2.8712e-03 8.8469e-03 9.4881e-05 4.3260e-04 -6.0000e+00 7.0293e-04 2.2524e-01 1.0135e-03 3.8157e-05 2.4545e-05 -6.0000e+00 2.8804e-04 -8.3602e-03 -7.1530e-05 2 1 1 12 1 1 99.87 18.62 0.74 -0.00836 -0.00133 350 169 1 4 0 19.720 21.98 15.00 18.62 20.39 13.9 1007.82 -43 74 104 -5 -58 60 196 221 141 107 110 51 -5 -123 -124 -117 13 76 6 -52 -38 75 254 336 296 234 168 37 -81 -125 -27 107 210 151 -97 -336 -347 -168 -42 66 96 91 101 146 113 29 -19 -58 -131 -272 -369 -395 -264 -161 -103 -191 -173 -217 -104 57 178 229 178 148 70 22 38 12 -64 -78 -86 31 7 8 -143 -239 -261 -155 -68 6 -87 -191 -187 -147 -107 -151 -155 -120 -12 105 178 236 162 1 -117 -93 -110 -145 -225 -250 -231 -116 -135 -178 -385 -428 -329 -101 73 175 127 119 112 115 210 314 328 243 227 198 228 321 373 348 187 82 135 142 184 97 -17 -84 -77 10 63 75 -42 -95 -55 -28 -7 91 95 42 -27 -140 -241 -179 -40 -43 74 106 -5 -60 63 201 228 144 109 114 53 -5 -125 -126 -119 14 78 6 -54 -40 79 266 352 310 244 173 38 -81 -124 -27 107 211 155 -101 -350 -360 -174 -43 67 98 94 104 152 118 30 -20 -59 -131 -267 -368 -390 -261 -161 -101 -191 -175 -221 -106 59 183 235 182 150 71 22 37 12 -63 -77 -85 31 7 8 -142 -236 -256 -151 -66 6 -85 -187 -179 -142 -104 -148 -153 -119 -12 105 179 237 163 1 -115 -91 -105 -141 -218 -242 -219 -111 -132 -177 -384 -428 -328 -101 73 176 125 118 112 116 213 318 331 243 226 195 223 312 361 337 181 79 130 136 181 95 -16 -81 -74 10 62 72 -40 -94 -55 -28 -7 91 95 42 -26 -136 -233 -172 -38 SQ 20211230T182226.5Z 8034.765584 345 1 5.19 2 65.09 195.17 82.71 235.88 0.00 1 0.00 1 0 15 1.714e-03 1.715e-03 1.244e-04 1.243e-04 1.862070e+03 8.312278e+00 1.307176e+02 -6.000000e+00 1.088094e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 6.222243e-04 3.629322e-06 3.619507e-05 -6.000000e+00 5.107502e-05 275.09 -2.00 20.00 -2.00 500.53 0.00e+00 3.229273e-02 2.664986e-03 1.762569e-02 -6.000000e+00 3.706161e-02 223.21 -2.00 3.49 -2.00 502.12 0.00e+00 2.359 0.000 489.00 513.00 1 2.3607e-01 2.0620e-04 3.6865e-03 -6.0000e+00 2.8708e-03 4.6672e-03 5.0248e-05 4.2798e-04 -6.0000e+00 7.0251e-04 1.1040e+00 3.8838e-04 2.0238e-05 2.3368e-05 -6.0000e+00 2.8802e-04 -1.1980e-02 -1.9523e-05 0 0 0 10 0 0 -52.67 18.62 0.79 -0.01198 -0.00929 1074 330 1 4 0 4.590 21.88 15.00 18.62 20.72 13.9 1009.78 -13 96 124 -13 -65 43 213 231 139 100 107 66 -12 -86 -100 -88 19 78 30 -48 -53 113 255 325 300 217 167 62 -107 -98 -35 98 212 167 -122 -345 -342 -180 -41 44 87 71 97 109 101 25 -21 -79 -138 -261 -372 -379 -296 -162 -113 -193 -223 -201 -95 59 180 199 186 134 62 27 42 48 -56 -112 -95 7 12 -11 -133 -264 -252 -126 -47 -10 -76 -163 -184 -147 -148 -170 -145 -97 -21 93 187 234 149 -10 -108 -103 -101 -155 -225 -257 -221 -150 -118 -221 -401 -464 -306 -102 97 199 146 125 103 112 204 278 317 259 219 199 206 264 363 332 209 133 128 163 205 119 -13 -86 -55 28 82 93 -32 -88 -57 -48 -8 54 84 42 -33 -135 -225 -166 -31 -12 94 124 -14 -66 44 222 242 145 103 110 67 -12 -86 -100 -89 19 81 32 -50 -55 117 265 338 311 225 171 62 -110 -99 -35 99 211 169 -125 -357 -353 -185 -42 45 89 72 100 113 104 26 -22 -79 -140 -261 -367 -371 -290 -160 -113 -192 -224 -203 -97 60 183 202 189 135 62 27 42 48 -55 -110 -93 7 11 -10 -131 -260 -245 -122 -45 -9 -73 -159 -181 -146 -148 -166 -142 -95 -21 93 186 235 149 -10 -106 -100 -99 -150 -216 -247 -215 -148 -115 -218 -400 -463 -305 -102 96 199 143 124 103 113 206 282 320 260 218 196 201 264 362 331 209 132 128 162 202 117 -12 -83 -53 27 80 91 -31 -87 -56 -48 -8 54 85 42 -33 -132 -218 -160 -31 SQ 20211230T182232.6Z 8034.765655 345 2 5.21 2 65.09 195.20 82.72 235.90 0.00 1 0.00 1 0 15 1.708e-03 1.709e-03 1.193e-04 1.192e-04 1.857994e+03 7.965851e+00 1.299857e+02 -6.000000e+00 1.084592e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 6.158815e-04 3.475519e-06 3.587115e-05 -6.000000e+00 5.091054e-05 275.09 -2.00 20.00 -2.00 500.53 0.00e+00 3.562827e-02 2.552628e-03 1.765465e-02 -6.000000e+00 3.694191e-02 223.21 -2.00 3.49 -2.00 502.11 0.00e+00 2.359 0.000 489.00 513.00 1 1.5753e-01 1.9748e-04 3.6859e-03 -6.0000e+00 2.8616e-03 4.4517e-03 4.8146e-05 4.2820e-04 -6.0000e+00 7.0023e-04 1.1939e+00 3.4012e-04 1.9402e-05 2.3195e-05 -6.0000e+00 2.8709e-04 -1.1515e-02 -2.1020e-05 0 0 0 10 0 0 -17.28 18.62 0.79 -0.01152 -0.00916 1074 330 1 4 0 4.590 21.88 15.00 18.62 20.72 14.0 1010.36 4 84 132 -19 -57 38 220 216 155 101 121 64 -14 -105 -118 -88 17 78 14 -52 -56 103 268 322 292 232 155 60 -105 -106 -44 113 219 168 -108 -350 -321 -198 -47 34 89 70 105 109 107 47 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247 285 363 316 188 117 121 126 174 91 -6 -82 -39 29 119 114 -17 -88 -70 -38 19 84 73 32 -51 -154 -227 -157 -25 SQ 20211230T182736.4Z 8034.769171 348 6 4.93 2 65.35 196.45 83.51 236.75 0.00 1 0.00 1 0 15 1.705e-03 1.705e-03 1.135e-04 1.133e-04 1.888613e+03 7.635834e+00 1.306232e+02 -6.000000e+00 1.082701e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 6.163402e-04 3.313738e-06 3.620735e-05 -6.000000e+00 5.082195e-05 275.09 -2.00 20.00 -2.00 500.52 0.00e+00 3.207193e-02 2.434580e-03 1.822630e-02 -6.000000e+00 3.687823e-02 223.21 -2.00 3.49 -2.00 502.10 0.00e+00 2.382 0.000 489.00 513.00 1 -6.3004e-03 1.8846e-04 3.7339e-03 -6.0000e+00 2.8566e-03 4.2361e-03 4.5844e-05 4.3764e-04 -6.0000e+00 6.9904e-04 1.4023e+00 4.2675e-04 1.8428e-05 2.3243e-05 -6.0000e+00 2.8660e-04 -1.1503e-02 -2.3291e-05 0 0 0 10 0 0 -115.52 18.62 0.79 -0.01150 -0.00854 1370 421 1 4 0 3.420 21.98 15.00 18.62 21.37 14.1 1016.37 -11 90 129 -1 -55 30 219 222 148 111 120 54 -23 -104 -106 -104 8 66 6 -65 -52 117 252 307 292 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307 249 219 197 227 296 350 335 177 93 121 154 187 123 6 -78 -53 28 103 97 -10 -91 -96 -45 -2 69 73 30 -50 -149 -211 -141 -11 SQ 20211230T182748.4Z 8034.769310 348 8 4.90 2 65.36 196.50 83.54 236.78 0.00 1 0.00 1 0 15 1.708e-03 1.707e-03 1.138e-04 1.137e-04 1.870697e+03 7.622347e+00 1.307721e+02 -6.000000e+00 1.084746e+02 275.09 -2.00 20.00 -2.00 505.26 0.00e+00 6.192159e-04 3.320860e-06 3.602608e-05 -6.000000e+00 5.091783e-05 275.09 -2.00 20.00 -2.00 500.52 0.00e+00 3.812985e-02 2.443296e-03 1.771038e-02 -6.000000e+00 3.694733e-02 223.21 -2.00 3.49 -2.00 502.10 0.00e+00 2.383 0.000 489.00 513.00 1 3.0931e-03 1.8912e-04 3.7183e-03 -6.0000e+00 2.8620e-03 4.1806e-03 4.6038e-05 4.2991e-04 -6.0000e+00 7.0033e-04 1.3883e+00 4.1515e-04 1.8514e-05 2.3270e-05 -6.0000e+00 2.8713e-04 -1.1715e-02 -2.0169e-05 0 0 0 10 0 0 -137.13 18.62 0.79 -0.01172 -0.00884 1370 421 1 4 0 3.420 21.98 15.00 18.62 21.37 14.1 1016.37 -19 97 124 -9 -63 44 219 216 154 110 95 80 0 -96 -98 -95 12 85 8 -55 -46 98 245 318 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233 192 225 288 343 328 189 97 116 155 182 137 -9 -84 -53 29 105 98 -4 -93 -80 -46 -1 76 82 20 -25 -149 -219 -150 -18 SQ 20211230T182754.2Z 8034.769378 348 9 4.89 2 65.37 196.52 83.55 236.80 0.00 1 0.00 1 0 15 1.707e-03 1.708e-03 1.140e-04 1.139e-04 1.885203e+03 7.631383e+00 1.316116e+02 -6.000000e+00 1.083560e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 6.189543e-04 3.319558e-06 3.600495e-05 -6.000000e+00 5.086213e-05 275.09 -2.00 20.00 -2.00 500.53 0.00e+00 3.291652e-02 2.438936e-03 1.790395e-02 -6.000000e+00 3.690681e-02 223.21 -2.00 3.49 -2.00 502.11 0.00e+00 2.384 0.000 489.00 513.00 1 7.8851e-03 1.8871e-04 3.7251e-03 -6.0000e+00 2.8588e-03 4.2029e-03 4.5988e-05 4.3412e-04 -6.0000e+00 6.9956e-04 1.3821e+00 3.8028e-04 1.8552e-05 2.3138e-05 -6.0000e+00 2.8682e-04 -1.1845e-02 -1.8984e-05 0 0 0 10 0 0 -134.96 18.62 0.80 -0.01184 -0.00921 1370 421 1 4 0 3.420 21.98 15.00 18.62 21.37 14.1 1016.37 5 96 142 -19 -64 35 190 222 128 106 110 85 9 -87 -109 -91 3 93 23 -59 -47 93 242 313 300 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315 266 217 190 209 305 356 327 204 133 113 145 173 109 -19 -59 -36 43 109 93 -22 -100 -102 -47 15 64 84 29 -43 -158 -199 -161 -18 SQ 20211230T183212.8Z 8034.772370 351 1 8.15 2 65.61 197.58 84.23 237.51 0.00 1 0.00 1 0 15 1.680e-03 1.680e-03 4.236e-04 4.231e-04 1.925284e+03 2.843936e+01 1.344539e+02 -6.000000e+00 1.066342e+02 275.09 -2.00 20.00 -2.00 505.26 0.00e+00 6.994496e-04 1.234845e-05 4.016816e-05 -6.000000e+00 5.005345e-05 275.09 -2.00 20.00 -2.00 500.48 0.00e+00 4.606123e-02 9.096526e-03 1.837437e-02 -6.000000e+00 3.631783e-02 223.21 -2.00 3.49 -2.00 502.07 0.00e+00 2.405 0.000 489.00 513.00 1 3.1301e+00 7.0416e-04 3.7907e-03 -6.0000e+00 2.8133e-03 1.3225e-02 1.7153e-04 4.4118e-04 -6.0000e+00 6.8832e-04 6.0574e-02 1.8642e-04 6.8809e-05 2.5953e-05 -6.0000e+00 2.8224e-04 -1.1667e-02 -1.1648e-05 2 1 1 12 1 1 92.85 18.62 0.69 -0.01167 -0.01037 93 165 1 4 0 84.730 21.98 15.00 18.62 21.86 14.0 1018.45 -20 65 69 -70 -122 33 224 200 155 116 130 84 -15 -131 -101 -94 13 47 73 -34 -27 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258 313 330 271 207 189 241 334 358 345 205 156 130 178 200 102 -50 -79 -72 39 80 119 -1 -127 -114 -42 -27 61 81 47 -32 -133 -203 -164 -105 SQ 20211230T184037.4Z 8034.778211 357 1 5.30 2 66.12 199.62 85.56 238.89 0.00 1 0.00 1 0 15 1.710e-03 1.707e-03 1.380e-04 1.378e-04 1.995065e+03 9.283041e+00 1.395172e+02 -6.000000e+00 1.085579e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 6.739358e-04 4.024673e-06 3.930766e-05 -6.000000e+00 5.095851e-05 275.09 -2.00 20.00 -2.00 500.50 0.00e+00 3.375619e-02 2.959295e-03 1.884738e-02 -6.000000e+00 3.698096e-02 223.21 -2.00 3.49 -2.00 502.09 0.00e+00 2.453 0.000 489.00 513.00 1 4.3220e-01 2.2907e-04 3.8602e-03 -6.0000e+00 2.8645e-03 4.1295e-03 5.5732e-05 4.5462e-04 -6.0000e+00 7.0112e-04 8.9466e-01 6.9578e-04 2.2351e-05 2.5570e-05 -6.0000e+00 2.8738e-04 -8.8595e-03 -5.3094e-05 0 0 0 10 0 0 98.68 18.62 0.80 -0.00886 -0.00403 980 301 1 4 0 5.110 21.98 15.00 18.62 21.89 14.0 1017.80 -13 99 125 -5 -57 52 218 233 158 121 110 82 5 -81 -97 -74 16 74 32 -54 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323 249 212 205 223 317 369 332 181 121 120 164 178 114 -11 -86 -36 32 86 90 -17 -92 -72 -31 1 87 98 51 -54 -160 -224 -147 -45 SQ 20211230T184047.5Z 8034.778327 357 3 1.34 2 66.13 199.66 85.58 238.92 0.00 1 0.00 1 0 15 1.782e-03 1.782e-03 2.539e-04 2.537e-04 1.994337e+03 1.707099e+01 1.398517e+02 -6.000000e+00 1.131242e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 6.754710e-04 7.413614e-06 3.923682e-05 -6.000000e+00 5.310058e-05 275.09 -2.00 20.00 -2.00 500.52 0.00e+00 3.181577e-02 5.442641e-03 1.880666e-02 -6.000000e+00 3.853205e-02 223.21 -2.00 3.49 -2.00 502.11 0.00e+00 2.454 0.000 489.00 513.00 1 1.5372e-01 4.2132e-04 3.8600e-03 -6.0000e+00 2.9847e-03 3.6670e-03 1.0249e-04 4.5470e-04 -6.0000e+00 7.3040e-04 1.1820e+00 3.7646e-04 4.1236e-05 2.5431e-05 -6.0000e+00 2.9945e-04 -1.1235e-02 -2.5971e-05 2 1 1 12 1 1 -123.76 18.62 0.80 -0.01124 -0.00862 215 301 1 4 0 5.110 21.98 15.00 18.62 21.89 14.1 1018.14 -28 82 145 23 -63 40 253 237 147 110 126 25 -26 -97 -122 -113 -13 73 26 -62 -22 111 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311 352 280 192 177 238 310 346 314 193 141 128 151 139 115 7 -79 -58 28 79 94 -35 -113 -68 -21 -21 95 104 15 -5 -124 -191 -166 -67 SQ 20211230T185834.4Z 8034.790676 364 1 4.13 2 67.38 203.90 88.45 241.76 0.00 1 0.00 1 0 15 1.670e-03 1.674e-03 5.378e-04 5.371e-04 2.068217e+03 3.628394e+01 1.466390e+02 -6.000000e+00 1.060420e+02 275.09 -2.00 20.00 -2.00 505.26 0.00e+00 7.468098e-04 1.566076e-05 4.288221e-05 -6.000000e+00 4.977847e-05 275.09 -2.00 20.00 -2.00 500.48 0.00e+00 8.327949e-02 1.154394e-02 1.900289e-02 -6.000000e+00 3.612953e-02 223.21 -2.00 3.49 -2.00 502.06 0.00e+00 2.580 0.000 489.00 513.00 1 2.8717e+00 8.9330e-04 4.0437e-03 -6.0000e+00 2.7984e-03 1.3879e-02 2.1777e-04 4.6413e-04 -6.0000e+00 6.8517e-04 7.6284e-02 1.1880e-03 8.7380e-05 2.7833e-05 -6.0000e+00 2.8073e-04 -8.6457e-03 -7.5348e-05 2 1 1 12 1 1 99.47 18.62 0.71 -0.00865 -0.00041 63 225 1 4 0 61.690 21.98 15.00 18.62 21.66 14.0 1015.10 -69 71 121 49 -87 31 220 251 136 139 150 67 -9 -49 -136 -68 -9 125 17 -84 -65 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220 172 195 279 303 359 207 69 116 115 151 167 0 -113 4 12 47 67 -56 -87 -65 -2 72 38 82 16 5 -63 -191 -161 -92 SQ 20211230T190210.8Z 8034.793181 367 1 5.42 2 67.67 204.74 89.04 242.33 0.00 1 0.00 1 0 15 2.042e-03 2.045e-03 1.711e-03 1.708e-03 2.117954e+03 1.157744e+02 1.464948e+02 -6.000000e+00 1.296411e+02 275.09 -2.00 20.00 -2.00 505.26 0.00e+00 8.303661e-04 4.994558e-05 4.734045e-05 -6.000000e+00 6.085303e-05 275.09 -2.00 20.00 -2.00 500.46 0.00e+00 1.036619e-01 3.679561e-02 2.054152e-02 -6.000000e+00 4.415434e-02 223.21 -2.00 3.49 -2.00 502.05 0.00e+00 2.610 0.000 489.00 513.00 1 5.3016e+00 2.8503e-03 4.1555e-03 -6.0000e+00 3.4203e-03 1.8473e-02 6.9352e-04 4.8616e-04 -6.0000e+00 8.3686e-04 6.6702e-03 2.4095e-04 2.7632e-04 3.0654e-05 -6.0000e+00 3.4314e-04 -6.8125e-03 -4.2122e-05 2 1 1 12 1 1 91.33 18.62 0.63 -0.00681 -0.00514 6 19 1 4 0 749.360 21.98 15.00 18.62 21.65 14.0 1014.75 -34 95 55 -104 -106 -11 199 222 78 162 100 27 69 -61 -168 -266 -34 -13 170 46 92 142 389 335 518 63 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275 -69 246 355 230 240 293 99 76 118 210 177 -18 -22 78 66 131 -103 53 22 -193 258 39 -16 -58 14 -187 -55 -305 -112 -118 SQ 20211230T190628.9Z 8034.796168 370 1 45.80 2 68.01 205.74 89.75 243.00 0.00 1 0.00 1 0 15 2.263e-03 2.256e-03 1.244e-03 1.242e-03 2.285884e+03 8.517632e+01 1.576998e+02 -6.000000e+00 1.436803e+02 275.09 -2.00 20.00 -2.00 505.27 0.00e+00 8.224241e-04 3.615552e-05 4.608300e-05 -6.000000e+00 6.744512e-05 275.09 -2.00 20.00 -2.00 500.44 0.00e+00 8.049217e-02 2.677850e-02 2.155802e-02 -6.000000e+00 4.894475e-02 223.21 -2.00 3.49 -2.00 502.04 0.00e+00 2.648 0.000 489.00 513.00 1 6.8597e+00 2.0680e-03 4.2308e-03 -6.0000e+00 3.7912e-03 1.7411e-02 5.0494e-04 5.1207e-04 -6.0000e+00 9.2791e-04 1.3989e-03 8.1233e-04 2.0124e-04 2.9399e-05 -6.0000e+00 3.8036e-04 -1.0778e-02 -3.8948e-05 0 0 0 10 0 0 99.87 18.62 0.67 -0.01078 -0.00514 25 8 1 4 0 1831.640 21.98 15.00 18.62 21.30 14.0 1012.47 -204 146 18 -162 -26 10 303 195 50 80 106 -82 86 -121 -205 -319 7 186 119 -58 3 222 311 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