File name: Pandora187s1_PittsburghPA_20211231_L2Fit_fwvt1c2d20210902p1-8.txt File generation date: 20231128T200244.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v2d20210902.txt Level 1 file used: Pandora187s1_PittsburghPA_20211231_L1_smca1c2d20210902p1-8.txt.bz2 Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20211231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1607 1755 Nominal wavelengths inside fitting window [nm]: 492.1177 492.2395 492.3614 492.4832 492.6050 492.7267 492.8485 492.9702 493.0920 493.2137 493.3354 493.4570 493.5787 493.7003 493.8219 493.9435 494.0651 494.1867 494.3083 494.4298 494.5513 494.6728 494.7943 494.9158 495.0372 495.1587 495.2801 495.4015 495.5229 495.6442 495.7656 495.8869 496.0083 496.1296 496.2508 496.3721 496.4934 496.6146 496.7358 496.8570 496.9782 497.0994 497.2205 497.3416 497.4628 497.5839 497.7049 497.8260 497.9470 498.0681 498.1891 498.3101 498.4311 498.5520 498.6730 498.7939 498.9148 499.0357 499.1566 499.2775 499.3983 499.5191 499.6399 499.7607 499.8815 500.0023 500.1230 500.2437 500.3644 500.4851 500.6058 500.7265 500.8471 500.9677 501.0883 501.2089 501.3295 501.4500 501.5706 501.6911 501.8116 501.9321 502.0525 502.1730 502.2934 502.4139 502.5343 502.6546 502.7750 502.8953 503.0157 503.1360 503.2563 503.3766 503.4968 503.6171 503.7373 503.8575 503.9777 504.0979 504.2181 504.3382 504.4583 504.5784 504.6985 504.8186 504.9387 505.0587 505.1787 505.2987 505.4187 505.5387 505.6586 505.7786 505.8985 506.0184 506.1383 506.2581 506.3780 506.4978 506.6176 506.7374 506.8572 506.9770 507.0967 507.2165 507.3362 507.4559 507.5756 507.6952 507.8149 507.9345 508.0541 508.1737 508.2933 508.4128 508.5324 508.6519 508.7714 508.8909 509.0103 509.1298 509.2492 509.3686 509.4880 509.6074 509.7268 509.8461 509.9655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211231T150441.2Z 8035.628255 184 1 45.24 2 71.20 146.51 64.15 178.24 0.00 1 0.00 1 0 15 3.622e-03 3.616e-03 2.062e-03 2.058e-03 2.512239e+03 1.413521e+02 1.592057e+02 -6.000000e+00 2.298960e+02 275.04 -2.00 20.00 -2.00 505.27 0.00e+00 5.827881e-04 6.031641e-05 3.612811e-05 -6.000000e+00 1.079217e-04 275.04 -2.00 20.00 -2.00 500.47 0.00e+00 2.182139e-01 4.435104e-02 2.671857e-02 -6.000000e+00 7.829737e-02 223.24 -2.00 3.49 -2.00 502.06 0.00e+00 3.066 0.000 489.00 513.00 1 7.7115e+00 3.4384e-03 4.8571e-03 -6.0000e+00 6.0654e-03 1.4368e-02 8.3381e-04 6.1125e-04 -6.0000e+00 1.4832e-03 5.5942e-04 -1.0432e-03 3.3232e-04 2.3190e-05 -6.0000e+00 6.0851e-04 -1.2991e-02 3.3926e-05 0 0 0 10 0 0 99.83 18.62 0.73 -0.01299 -0.02023 13 4 1 4 0 3479.090 21.98 15.01 18.62 17.52 13.8 987.22 -66 35 231 -355 82 4 374 -186 -218 412 157 267 -182 -278 -506 -674 337 288 423 -82 12 37 179 730 559 -36 55 553 -175 -515 -282 135 718 -136 -315 -72 178 -126 -168 249 305 342 95 142 -184 -375 -67 -163 308 -336 -439 -383 -670 175 45 -477 119 111 52 263 530 109 75 6 71 93 371 314 23 -174 -362 -353 91 -239 -357 -238 -1122 -43 124 -38 -242 -1049 253 439 -257 -582 -601 -321 57 178 550 747 -253 -142 -224 99 -261 -362 -541 -121 -412 -272 -158 -489 -77 -591 -202 208 -119 53 274 -81 424 575 191 415 729 207 794 -82 -57 480 479 123 647 258 -466 551 360 739 -128 12 284 245 148 -288 308 -201 -420 -36 249 -103 -166 -427 -73 147 -310 -384 -510 -63 34 229 -362 85 4 397 -200 -233 435 165 275 -187 -285 -518 -698 350 303 451 -85 13 38 187 757 579 -38 56 582 -183 -533 -290 140 713 -138 -324 -75 182 -129 -171 253 309 348 98 147 -191 -388 -69 -164 303 -342 -440 -380 -668 175 44 -472 119 112 52 265 534 111 76 6 70 91 376 314 23 -173 -360 -352 91 -239 -356 -236 -1114 -42 121 -37 -237 -1040 250 435 -246 -564 -584 -312 55 174 540 734 -251 -139 -217 95 -246 -351 -522 -116 -400 -256 -151 -477 -75 -582 -197 203 -117 53 272 -82 428 584 196 424 741 210 794 -82 -56 470 469 121 631 252 -458 534 347 706 -122 11 267 232 141 -280 301 -200 -422 -37 251 -100 -161 -414 -73 146 -304 -374 -496 SQ 20211231T155920.7Z 8035.666212 213 1 1.81 2 66.43 158.99 65.16 191.66 0.00 1 0.00 1 0 15 1.940e-03 1.938e-03 1.706e-03 1.704e-03 2.337105e+03 1.161046e+02 1.631383e+02 -6.000000e+00 1.231603e+02 275.04 -2.00 20.00 -2.00 505.26 0.00e+00 4.318532e-04 4.975071e-05 2.798763e-05 -6.000000e+00 5.781454e-05 275.04 -2.00 20.00 -2.00 500.48 0.00e+00 1.312491e-02 3.667320e-02 2.125263e-02 -6.000000e+00 4.194206e-02 223.24 -2.00 3.49 -2.00 502.07 0.00e+00 2.483 0.000 489.00 513.00 1 4.1646e+00 2.8395e-03 3.9274e-03 -6.0000e+00 3.2492e-03 1.6566e-02 6.9080e-04 5.1680e-04 -6.0000e+00 7.9443e-04 2.1417e-02 -7.0810e-04 2.7460e-04 1.6754e-05 -6.0000e+00 3.2600e-04 -1.1182e-02 3.1575e-05 2 1 1 12 1 1 96.43 18.62 0.67 -0.01118 -0.01609 6 61 1 4 0 232.430 21.88 15.00 18.62 19.13 13.9 998.64 -8 71 35 -30 -66 32 206 383 39 91 3 119 149 2 -123 -253 -163 114 126 -80 -52 -105 325 346 148 195 139 169 40 -49 -37 125 201 153 -101 -314 -307 -47 -93 134 153 42 225 -5 17 -2 -177 14 -81 -285 -422 -501 -176 -250 -21 -280 -185 -215 -126 106 198 283 380 124 -91 17 125 75 -152 -242 -209 -3 57 -5 -92 -236 -412 -118 -128 -171 106 110 -109 -257 -50 14 259 -118 -170 -61 93 253 11 60 27 51 -430 -249 -89 -247 -166 -40 -161 -182 -469 -511 -299 -126 -30 204 125 143 130 65 152 143 532 205 207 144 184 263 304 370 44 255 158 289 103 272 -85 -175 49 95 112 213 -20 -26 -38 10 -121 -80 86 -161 63 -131 -250 -193 18 -8 70 36 -30 -68 34 217 404 41 95 3 122 151 2 -125 -258 -168 119 134 -83 -54 -110 339 361 154 203 143 176 41 -50 -38 128 208 156 -104 -325 -318 -48 -95 136 156 43 232 -5 18 -2 -181 14 -83 -286 -417 -492 -172 -247 -22 -286 -186 -217 -128 107 201 286 383 124 -94 18 125 75 -150 -237 -205 -3 56 -5 -90 -230 -401 -114 -123 -165 102 107 -106 -254 -50 14 258 -115 -166 -60 92 251 11 59 26 50 -419 -238 -85 -235 -159 -39 -160 -178 -463 -504 -294 -123 -30 201 125 144 132 64 151 142 542 209 209 144 182 258 298 363 43 250 155 282 100 261 -81 -166 46 89 107 205 -19 -26 -38 10 -119 -78 84 -158 63 -130 -244 -187 18 SQ 20211231T160309.4Z 8035.668859 216 1 4.97 2 66.18 159.91 65.31 192.57 0.00 1 0.00 1 0 15 1.749e-03 1.749e-03 1.218e-04 1.216e-04 2.114715e+03 8.247670e+00 1.464916e+02 -6.000000e+00 1.110458e+02 275.04 -2.00 20.00 -2.00 505.27 0.00e+00 4.688468e-04 3.555092e-06 2.903543e-05 -6.000000e+00 5.213005e-05 275.04 -2.00 20.00 -2.00 500.52 0.00e+00 4.242367e-02 2.613213e-03 1.961197e-02 -6.000000e+00 3.784112e-02 223.24 -2.00 3.49 -2.00 502.11 0.00e+00 2.458 0.000 489.00 513.00 1 1.3330e-01 2.0222e-04 3.8412e-03 -6.0000e+00 2.9310e-03 1.7884e-03 4.9155e-05 4.7713e-04 -6.0000e+00 7.1751e-04 1.2079e+00 9.6778e-04 1.9713e-05 1.7846e-05 -6.0000e+00 2.9404e-04 -8.0478e-03 -6.6303e-05 0 0 0 10 0 0 99.39 18.61 0.81 -0.00805 -0.00133 1294 398 1 4 0 3.670 21.98 15.00 18.61 19.54 14.0 1002.40 -48 73 119 -1 -40 66 235 222 157 122 114 62 -1 -110 -105 -93 11 76 31 -56 -31 131 275 317 294 218 136 37 -81 -137 -65 71 197 151 -119 -358 -327 -175 -41 82 92 77 108 114 108 49 -42 -84 -157 -279 -368 -368 -288 -173 -118 -171 -195 -189 -92 76 209 236 211 166 52 15 44 23 -65 -124 -104 -4 12 -20 -141 -252 -272 -152 -93 -40 -84 -199 -209 -132 -119 -157 -156 -123 -22 94 189 213 146 0 -89 -104 -113 -166 -234 -270 -216 -150 -133 -210 -399 -449 -339 -103 97 186 151 133 102 114 243 299 327 273 229 189 234 297 379 338 179 116 142 156 172 117 -20 -90 -71 7 90 76 -28 -93 -68 -41 26 80 106 56 -19 -140 -228 -187 -43 -47 73 117 -1 -41 69 241 228 161 124 119 63 -1 -111 -106 -94 11 77 32 -58 -33 138 289 333 308 227 141 38 -81 -137 -65 71 199 155 -124 -363 -341 -182 -43 84 95 80 113 116 110 50 -44 -86 -157 -274 -368 -365 -286 -168 -117 -171 -198 -194 -95 76 209 243 216 169 52 15 43 22 -63 -119 -100 -4 11 -19 -137 -243 -269 -149 -91 -39 -83 -191 -203 -128 -117 -155 -155 -122 -22 94 191 210 144 0 -89 -102 -109 -158 -221 -256 -207 -145 -131 -210 -392 -442 -333 -101 96 184 150 133 103 116 249 307 334 278 231 189 232 292 373 332 176 114 139 153 167 113 -19 -88 -70 7 87 74 -28 -92 -69 -41 26 80 105 55 -19 -139 -225 -183 -42 SQ 20211231T160315.5Z 8035.668929 216 2 5.00 2 66.17 159.93 65.32 192.60 0.00 1 0.00 1 0 15 1.756e-03 1.757e-03 1.126e-04 1.125e-04 2.117180e+03 7.602527e+00 1.467344e+02 -6.000000e+00 1.114760e+02 275.04 -2.00 20.00 -2.00 505.27 0.00e+00 4.692680e-04 3.283796e-06 2.910340e-05 -6.000000e+00 5.232945e-05 275.04 -2.00 20.00 -2.00 500.54 0.00e+00 3.866100e-02 2.416128e-03 1.979905e-02 -6.000000e+00 3.797480e-02 223.24 -2.00 3.49 -2.00 502.12 0.00e+00 2.457 0.000 489.00 513.00 1 -1.0247e-02 1.8698e-04 3.8468e-03 -6.0000e+00 2.9416e-03 1.4599e-03 4.5469e-05 4.8060e-04 -6.0000e+00 7.1964e-04 1.3949e+00 1.8322e-04 1.8243e-05 1.7962e-05 -6.0000e+00 2.9510e-04 -1.1693e-02 -2.7055e-06 0 0 0 10 0 0 77.70 18.61 0.81 -0.01169 -0.01042 1294 398 1 4 0 3.670 21.88 15.00 18.61 19.54 14.1 1002.40 -43 82 114 -9 -55 59 237 243 150 118 118 67 -9 -90 -93 -102 9 77 36 -48 -44 125 273 317 307 211 162 60 -102 -133 -68 60 196 145 -123 -330 -336 -188 -34 60 83 75 104 129 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513.00 1 -1.5511e-01 1.7605e-04 3.6293e-03 -6.0000e+00 2.8959e-03 1.8539e-03 4.2837e-05 4.4915e-04 -6.0000e+00 7.0850e-04 1.6437e+00 1.8472e-04 1.7210e-05 1.5461e-05 -6.0000e+00 2.9051e-04 -1.1280e-02 -9.0347e-06 0 0 0 10 0 0 94.60 18.61 0.80 -0.01128 -0.01000 1533 471 1 4 0 2.970 21.88 15.00 18.61 21.42 14.0 1013.57 -45 65 105 -16 -69 54 229 247 159 123 111 75 -13 -105 -105 -90 18 87 48 -52 -40 111 261 313 298 210 148 51 -104 -117 -63 71 191 147 -121 -326 -310 -170 -41 66 99 73 101 133 101 35 -29 -72 -147 -279 -388 -372 -300 -153 -102 -177 -208 -195 -93 72 196 238 203 147 52 4 46 39 -60 -125 -83 -24 14 -12 -133 -266 -256 -141 -80 -35 -81 -177 -204 -145 -114 -151 -157 -114 -20 88 194 221 155 -13 -113 -94 -105 -153 -253 -263 -205 -142 -123 -194 -374 -462 -335 -119 105 194 161 127 93 113 233 305 311 272 218 196 235 280 352 333 193 131 121 152 189 123 -29 -91 -57 8 88 90 -14 -96 -92 -48 10 77 102 60 -24 -159 -225 -168 -51 -45 65 104 -16 -70 56 238 257 165 127 113 75 -14 -107 -107 -90 18 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2.332 0.000 489.00 513.00 1 7.7794e-01 3.0073e-04 3.6211e-03 -6.0000e+00 2.9770e-03 3.1331e-03 7.3088e-05 4.4171e-04 -6.0000e+00 7.2859e-04 6.4649e-01 6.0088e-04 2.9258e-05 1.6049e-05 -6.0000e+00 2.9866e-04 -9.2334e-03 -4.1524e-05 0 0 0 10 0 0 99.70 18.61 0.81 -0.00923 -0.00507 1533 471 1 4 0 2.970 21.88 15.00 18.61 21.42 14.0 1013.57 -86 47 95 -12 -55 69 238 244 179 111 121 74 -5 -98 -101 -78 43 114 47 -45 -40 98 269 317 275 216 140 34 -154 -181 -123 39 170 140 -88 -299 -302 -169 -32 62 111 53 129 137 133 62 -14 -73 -141 -244 -387 -391 -314 -177 -117 -199 -202 -181 -65 99 217 247 251 178 55 -4 37 13 -76 -144 -122 -14 6 -32 -147 -273 -283 -179 -119 -56 -109 -213 -197 -166 -96 -142 -137 -100 -33 97 184 228 156 -15 -97 -90 -108 -156 -251 -281 -222 -147 -120 -217 -390 -453 -330 -131 120 209 148 149 136 150 221 314 352 269 230 197 198 290 350 325 182 131 119 151 192 111 -3 -115 -65 -5 103 77 -1 -101 -85 -39 23 92 128 60 -39 -157 -231 -208 -52 -83 46 95 -12 -57 70 245 252 185 113 122 77 -5 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-2.00 502.09 0.00e+00 2.331 0.000 489.00 513.00 1 1.3726e+00 4.3801e-04 3.6397e-03 -6.0000e+00 2.8220e-03 5.5503e-03 1.0658e-04 4.5287e-04 -6.0000e+00 6.9029e-04 3.5657e-01 5.5026e-05 4.2652e-05 1.5502e-05 -6.0000e+00 2.8311e-04 -1.2570e-02 1.1026e-05 0 0 0 10 0 0 92.98 18.61 0.78 -0.01257 -0.01219 1533 471 1 4 0 2.970 21.88 15.00 18.61 21.42 14.0 1013.57 -53 83 101 -8 -51 57 205 257 140 96 100 60 -9 -80 -97 -110 -11 92 27 -44 -71 106 248 315 295 212 150 57 -84 -127 -57 74 208 122 -135 -332 -327 -154 -15 74 64 114 86 132 106 46 -2 -72 -157 -251 -356 -361 -283 -161 -98 -136 -206 -201 -92 61 203 235 206 140 48 21 30 18 -46 -147 -80 -9 3 6 -151 -247 -280 -142 -69 -4 -65 -205 -202 -145 -152 -159 -171 -100 -5 93 205 216 153 -20 -100 -75 -162 -179 -226 -251 -237 -124 -125 -211 -345 -436 -320 -138 103 183 158 158 122 96 225 281 306 225 200 188 203 294 336 289 175 115 102 168 169 135 -9 -71 -65 8 74 68 -35 -112 -101 -26 18 89 96 54 -29 -129 -213 -158 -31 -51 81 100 -8 -53 60 218 274 149 101 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502.07 0.00e+00 2.331 0.000 489.00 513.00 1 2.5596e+00 1.0577e-03 3.6429e-03 -6.0000e+00 2.8871e-03 1.1001e-02 2.5596e-04 4.5922e-04 -6.0000e+00 7.0616e-04 1.0887e-01 -1.6217e-04 1.0264e-04 1.4715e-05 -6.0000e+00 2.8964e-04 -1.2971e-02 1.8169e-05 0 0 0 10 0 0 95.03 18.61 0.73 -0.01297 -0.01410 1533 471 1 4 0 2.970 21.98 15.00 18.61 21.42 14.1 1013.57 -21 78 131 -35 -115 23 176 222 145 118 122 55 19 -63 -125 -93 27 74 90 -104 -17 42 269 368 293 175 148 80 -84 -145 -91 80 195 147 -117 -306 -308 -157 -38 26 99 54 126 99 71 5 -31 -161 -123 -293 -385 -338 -262 -146 -71 -138 -197 -227 -115 46 162 279 234 181 46 35 46 -2 -117 -206 -84 -7 14 -82 -148 -199 -284 -84 -52 -78 -95 -186 -193 -87 -92 -172 -176 -84 -49 125 191 211 95 8 -138 -77 -118 -148 -232 -316 -192 -127 -126 -236 -360 -529 -281 -106 114 157 167 141 91 88 223 313 297 244 197 198 189 304 326 290 207 157 96 166 216 161 -23 -122 -51 23 86 82 -16 -118 -93 -24 56 64 81 30 -44 -105 -239 -190 -28 -20 78 132 -36 -121 25 191 242 158 128 131 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502.00 0.00e+00 2.331 0.000 489.00 513.00 1 2.6150e+00 1.1111e-03 3.6393e-03 -6.0000e+00 2.8387e-03 9.9919e-03 2.6889e-04 4.5572e-04 -6.0000e+00 6.9442e-04 1.0298e-01 1.0037e-04 1.0658e-04 1.5481e-05 -6.0000e+00 2.8478e-04 -1.3080e-02 1.0238e-05 0 0 0 10 0 0 75.35 18.61 0.72 -0.01308 -0.01238 1533 471 1 4 0 2.970 21.98 15.00 18.61 21.42 14.1 1013.57 -88 116 117 -35 -90 26 122 229 193 103 130 93 9 -101 -89 -126 -13 41 -12 -77 -29 92 235 383 294 199 171 28 -140 -114 -136 53 174 164 -94 -339 -314 -213 -64 90 123 125 158 126 156 31 -71 -64 -123 -201 -382 -390 -265 -148 -94 -192 -170 -195 -66 52 176 182 196 140 63 -53 60 46 -16 -102 -115 12 46 -55 -118 -273 -269 -141 -65 -64 -20 -146 -195 -111 -131 -180 -157 -39 -82 90 173 221 156 -75 -83 -134 -121 -102 -238 -270 -200 -93 -110 -192 -386 -457 -314 -93 82 166 182 85 20 155 198 286 317 277 222 196 220 284 305 244 165 100 105 161 200 118 -28 -108 -41 10 103 91 -5 -77 -82 24 19 112 74 1 -55 -180 -260 -141 -21 -86 113 117 -36 -94 28 131 247 208 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